Water quality data for Fall Creek,New York,USA: 1972–1995

The 33 086 ha mixed land use Fall Creek watershed in upstate New York is part of the Great Lakes drainage system. Results from more than 3500 water samples are available in a data set that compiles flow data and measurements of various water quality analytes collected between 1972 and 1995 in all seasons and under all flow regimes in Fall Creek and its tributaries. Data is freely accessible at https://ecommons.cornell.edu/handle/1813/8148 and includes measurements of suspended solids, pH, alkalinity, calcium, magnesium, potassium, sodium, chloride, nitrate nitrogen (NO3-N), sulphate sulphur (SO4-S), phosphorus (P) fractions molybdate reactive P (MRP) and total dissolved P (TDP), percent P in sediment, and ammonium nitrogen (NH4-N). Methods, sub-watershed areas, and coordinates for sampling sites are also included. The work represented in this data set has made important scientific contributions to understanding of hydrological and biogeochemical processes that influence loading in mixed use watersheds and that have an impact on algal productivity in receiving water bodies. In addition, the work has been foundational for important regulatory and management decisions in the region.     

Probing the physics of interacting galaxies

The morphological and velocity structures in the gaseous (HI and CO) and stellar components of two interacting systems are examined. Both Arp 140 and Arp 104 reveal extended tidal tails in the HI. The Hα and FIR fluxes of Arp 140 yield similar SFR of ∼ 0.8 M_⊙ yr^-1. In contrast the Hα flux of Arp 104 yields a SFR of ∼ 0.05 M_⊙ yr^-1, ∼ 20 times smaller than that obtained from the FIR flux. Spectra were used to examine the changing velocity of atomic and molecular gas in NGC 5218 (Arp 104). The atomic and molecular gas were found to be dynamically similar with comparable velocities and velocity widths across the galaxy; consistent with the two phases responding similarly to the interaction, or enhanced HI to CO conversion in the centre of the galaxy. This revised version was published online in August 2006 with corrections to the Cover Date.     

Sulfide-driven arsenic mobilization from arsenopyrite and black shale pyrite

We examined the hypothesis that sulfide drives arsenic mobilization from pyritic black shale by a sulfide-arsenide exchange and oxidation reaction in which sulfide replaces arsenic in arsenopyrite forming pyrite, and arsenide (As−1) is concurrently oxidized to soluble arsenite (As+3). This hypothesis was tested in a series of sulfide-arsenide exchange experiments with arsenopyrite (FeAsS), homogenized black shale from the Newark Basin (Lockatong formation), and pyrite isolated from Newark Basin black shale incubated under oxic (21% O₂), hypoxic (2% O₂, 98% N₂), and anoxic (5% H₂, 95% N₂) conditions. The oxidation state of arsenic in Newark Basin black shale pyrite was determined using X-ray absorption-near edge structure spectroscopy (XANES). Incubation results show that sulfide (1 mM initial concentration) increases arsenic mobilization to the dissolved phase from all three solids under oxic and hypoxic, but not anoxic conditions. Indeed under oxic and hypoxic conditions, the presence of sulfide resulted in the mobilization in 48 h of 13-16 times more arsenic from arsenopyrite and 6-11 times more arsenic from isolated black shale pyrite than in sulfide-free controls. XANES results show that arsenic in Newark Basin black shale pyrite has the same oxidation state as that in FeAsS (−1) and thus extend the sulfide-arsenide exchange mechanism of arsenic mobilization to sedimentary rock, black shale pyrite. Biologically active incubations of whole black shale and its resident microorganisms under sulfate reducing conditions resulted in sevenfold higher mobilization of soluble arsenic than sterile controls. Taken together, our results indicate that sulfide-driven arsenic mobilization would be most important under conditions of redox disequilibrium, such as when sulfate-reducing bacteria release sulfide into oxic groundwater, and that microbial sulfide production is expected to enhance arsenic mobilization in sedimentary rock aquifers with major pyrite-bearing, black shale formations.     

Thermodynamic characterization of the partitioning of iron between soluble and colloidal species in the Atlantic Ocean

Recent electrochemical measurements have shown that iron (Fe) speciation in seawater is dominated by complexation with strong organic ligands throughout the water column and have provided important thermodynamic information about these compounds. Independent work has shown that iron exists in both soluble and colloidal fractions in the Atlantic Ocean. Here we have combined these approaches in samples collected from a variety of regimes within the Atlantic Ocean. We measured the partitioning of Fe between soluble (< 0.02 μm) and colloidal (0.02 to 0.4 μm) size classes and characterized the concentrations and conditional stability constants of Fe ligands within these size classes. Results suggest that equilibrium partitioning of Fe between soluble and colloidal ligands is partially responsible for the distribution of Fe between soluble and colloidal size classes. However, a significant fraction of the colloidal Fe was inert to ligand exchange as soluble Fe concentrations were generally lower than values predicted by a simple equilibrium partitioning model.In surface waters, strong ligands with conditional stability constants of 10¹³ relative to total inorganic Fe appeared to dominate speciation in both the soluble and colloidal fractions. In deep waters these ligands were absent, and instead we found ligands with stability constants 12–15 fold smaller that were predominantly in the soluble pool. Nevertheless, significant levels of colloidal Fe were found in these samples, which we inferred must be inert to coordination exchange.     

Impact of the North Atlantic Oscillation on Middle Eastern Climate and Streamflow

Interannual to decadal variations in Middle Eastern temperature, precipitationand streamflow reflect the far-field influence of the North Atlantic Oscillation (NAO), a dominant mode of Atlantic sector climate variability. Using a new sea surface temperature (SST) based index of the NAO and availablestreamflow data from five Middle Eastern rivers, we show that the first principal component of December through March streamflow variability reflects changes in the NAO. However, Middle East rivers have two primary flooding periods.The first is rainfall-driven runoff from December through March, regulated on interannual to decadal timescales by the NAO as reflected in local precipitation and temperature.The second period, from April through June, reflects spring snowmelt and contributes in excess of 50% of annual runoff.This period, known locally as the khamsin, displays no significantNAO connections and a less direct relationship with local climatic factors, suggesting that streamflow variability during this period reflects land-cover change, possibly related to agriculture and hydropower generation, and snowmelt.     

A comparison of three image-object methods for the multiscale analysis of landscape structure

Within the conceptual framework of Complex Systems, we discuss the importance and challenges in extracting and linking multiscale objects from high-resolution remote sensing imagery to improve the monitoring, modeling and management of complex landscapes. In particular, we emphasize that remote sensing data are a particular case of the modifiable areal unit problem (MAUP) and describe how image-objects provide a way to reduce this problem. We then hypothesize that multiscale analysis should be guided by the intrinsic scale of the dominant landscape objects composing a scene and describe three different multiscale image-processing techniques with the potential to achieve this. Each of these techniques, i.e., Fractal Net Evolution Approach (FNEA), Linear Scale-Space and Blob-Feature Detection (SS), and Multiscale Object-Specific Analysis (MOSA), facilitates the multiscale pattern analysis, exploration and hierarchical linking of image-objects based on methods that derive spatially explicit multiscale contextual information from a single resolution of remote sensing imagery. We then outline the weaknesses and strengths of each technique and provide strategies for their improvement.     

PCA and SVM as geo-computational methods for geological mapping in the southern of Tunisia,using ASTER remote sensing data set

The purpose of this study was to examine the efficiency of Advanced Space Borne Thermal Emission and Reflection Radiometer (ASTER) data in the discrimination of geological formations and the generation of geological map in the northern margin of the Tunisian desert. The nine ASTER bands covering the visible (VIS), near-infrared (NIR) and short-wave infrared (SWIR) spectral regions (wavelength range of 400–2500 nm) have been treated and analyzed. As a first step of data processing, crosstalk correction, resampling, orthorectification, atmospheric correction, and radiometric normalization have been applied to the ASTER radiance data. Then, to decrease the redundancy information in highly correlated bands, the principal component analysis (PCA) has been applied on the nine ASTER bands. The results of PCA allow the validation and the rectification of the lithological boundaries already published on the geologic map, and gives a new information for identifying new lithological units corresponding to superficial formations previously undiscovered. The application of a supervised classification on the principal components image using a support vector machine (SVM) algorithm shows good correlation with the reference geologic map. The overall classification accuracy is 73 % and the kappa coefficient equals to 0.71. The processing of ASTER remote sensing data set by PCA and SVM can be employed as an effective tool for geological mapping in arid regions.     

Ecotoxicological evaluation of dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro State,Brazil) using bioassays with earthworms and collembolans

The toxicity and metal bioavailability were studied in dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro, RJ, Brazil) using acute and avoidance tests with Eisenia andrei, and reproduction tests with Folsomia candida. The sediment was mixed with an artificial soil, and two natural soils (ferralsol and chernosol—representative Brazilian tropical soils) to obtain the following doses: 1, 3, 6, 12, 18, 24 and 30%. Total metal concentrations were determined in the sediment to support the interpretation of ecotoxicological data. Metal concentrations in the mixtures were in agreement with the threshold limits established by Brazilian law. However, significant avoidance responses were found on doses ≥?3% and were the most sensitive endpoint. Earthworm mortality found in artificial soil mixtures (LC50?=?3.9) suggests higher toxicity levels than those obtained in ferralsol (LC50?=?7.6%) and chernosol (11.0%) treatments. Earthworm mortality, avoidance responses and collembolan reproduction levels found in ferralsol mixtures (LC50?=?9.2; avoidance EC50?=?2.3%; reproduction EC50?=?2.8%) were higher compared to chernosol treatments (LC50?=?11.0%; avoidance EC50?=?4.3%; reproduction EC50?=?4.9%). The reduction of toxicity levels in chernosol mixtures is probably due to the abundance of expansive clay minerals in chernosols with capacity of adsorbing metals and other xenobiotic substances from soil pore water, decreasing metal bioavailability. Finally, threshold limits defined by Brazilian legislation for soil quality and land disposal of dredged sediments are not sufficient to prevent noxious effects on soil fauna and should be complemented with a preliminary ecotoxicological evaluation.     

Geochemical comparison between minettes and kersantites from the Western European Hercynian orogen: trace element and PbSrNd isotope constraints on their origin

Trace element and isotopic characteristics of late Carboniferous to early Permian minettes and kersantites have been determined. These lamprophyres have been sampled throughout the Western European Hercynian orogen, from Brittany to the west to Schwarzwald to the east. In spite of sharp petrological differences reflected by mineralogy and major element geochemistry, minettes and kersantites exhibit close identity with respect to trace element and isotopic features. These features comprise enrichment in incompatible elements, highCs/Rb and lowCe/Pb ratios, Ta and Ti relative depletion, high abundance in transition elements and highNi/Mg ratios. Pb isotope ratios are undistinguishable from those measured on Hercynian continental crust. Initial¹⁴³Nd/¹⁴⁴Nd ratios are between0.5120 (ε_i −5) and0.5122 (ε_i −1) for minettes and kersantites whereas initial⁸⁷Sr/⁸⁶Sr ratios vary between 0.7055–0.710 for minettes and 0.707–0.708 for kersantites. No simple mixing relations are visible on RbSr and SmNd isochron diagrams. The exceptional homogeneity of these geochemical characteristics along a 1000 km traverse does not allow for an hypothesis of enrichment through upper level assimilation and thus leads to propose that these rocks originated through melting of a mantle enriched by recycling of crustal material.