Modeling hydrodynamics and aquaculture waste transport in coastal maine

Net-pen aquaculture results in the introduction of excess fish food and fecal matter in coastal waters. These wastes may modify the benthic environment. Mathematical models are developed in this study to simulate tidal and wind-driven currents, waves, and the resulting dispersion of fish food and fecal matter in coastal Maine, a region where limited modelling studies have been performed. Cobscook Bay and Toothacher Bay in Maine are studied in detail through the use of mathematical models and field data. We find that a systematic, site-specific, step-by-step modeling strategy involving the use of numerical models to simulate the overall hydrodynamic environment in combination with a waste-particle transport model can be an extremely powerful method of determining a priori whether aquaculture operations will cause high rates of net-pen waste accumulation at a particular site.     

Governance and technology transfer in the Clean Development Mechanism in India

Despite significant technological advances in emerging economies, the further development of clean energy technologies in developing countries remains crucial to reducing the greenhouse gas emissions associated with economic development. In this paper we address two significant gaps in the growing body of literature that has assessed the role of the Clean Development Mechanism in promoting the transfer of clean technologies to developing countries. First, we present a qualitative analysis of the governance of the Clean Development Mechanism in India. This provides a basis for understanding the extent to which and the ways in which governance may impact upon the likelihood that projects promote technology transfer. Second, we provide a novel quantification of the level and nature of technology transfer that has occurred in Indian Clean Development Mechanism projects, based on insights from literature on technological capability building. We find that the Clean Development Mechanism in India has produced a negligible number of projects that promote technology transfer if technology transfer is understood as a process of learning about technology. Together these qualitative and quantitative analyses show how politics and governance have contributed to the current form of the Clean Development Mechanism market in India, in which processes of building indigenous technological capabilities have been neglected.     

Influence of the vertical motion field on ozone concentration in the stratosphere

Computations of the mean meridional motion field in the stratosphere are applied to ozone distributions to evaluate the associated ozone concentration changes. These changes are compared with those produced by photochemical and quasi-horizontal eddy processes. For the period January–April 1964 there is a cooperative action between the mean and eddy motions with mean subsidence in middle latitudes supplying ozone to be carried polawards and equatorwards by quasi-horizontal eddy processes. At low latitudes mean horizontal motions offset the eddy transport while at high latitudes mean rising motion is the offsetting term. The mean ozone flux through 50 mb, 3.5×10²⁹ molecules sec^–1, is comparable with the fluxes evaluated by other techniques.The spring maximum is thought to be due to a modulation of the energy supply to the stratospheric eddies which, in turn, force the mean motions. Longer-term changes are to be expected; for example during Ice Ages when increased tropospheric eddy activity is anticipated there should be higher total ozone.     

MAROS: a decision support system for optimizing monitoring plans

The Monitoring and Remediation Optimization System (MAROS), a decision-support software, was developed to assist in formulating cost-effective ground water long-term monitoring plans. MAROS optimizes an existing ground water monitoring program using both temporal and spatial data analyses to determine the general monitoring system category and the locations and frequency of sampling for future compliance monitoring at the site. The objective of the MAROS optimization is to minimize monitoring locations in the sampling network and reduce sampling frequency without significant loss of information, ensuring adequate future characterization of the contaminant plume. The interpretive trend analysis approach recommends the general monitoring system category for a site based on plume stability and site-specific hydrogeologic information. Plume stability is characterized using primary lines of evidence (i.e., Mann-Kendall analysis and linear regression analysis) based on concentration trends, and secondary lines of evidence based on modeling results and empirical data. The sampling optimization approach, consisting of a two-dimensional spatial sampling reduction method (Delaunay method) and a temporal sampling analysis method (Modified CES method), provides detailed sampling location and frequency results. The Delaunay method is designed to identify and eliminate redundant sampling locations without causing significant information loss in characterizing the plume. The Modified CES method determines the optimal sampling frequency for a sampling location based on the direction, magnitude, and uncertainty in its concentration trend. MAROS addresses a variety of ground water contaminants (fuels, solvents, and metals), allows import of various data formats, and is designed for continual modification of long-term monitoring plans as the plume or site conditions change over time.     

Long-term global sea surface temperature fluctuations and their possible influence on atmospheric CO2 concentrations

Changes of atmospheric CO₂ concentration since 1958 are shown to be related to sea surface temperature changes. The largest contribution to changes arises from the Pacific equatorial upwelling region, with the Indian Ocean and Atlantic contributing only small fractions to the variance. It is hypothesized that the observed relationship is related to the nutrients that are brought up by upwelling cold water, with photosynthesis contributing to a lowering of the partial pressure of CO₂ in the sea and thus to a greater tendency for a flux from the air to the sea.Possible longer term variations of sea temperature and CO₂ are discussed.     

Landscape for change? International climate policy and energy transitions: evidence from sub-Saharan Africa

What is the role of the climate regime in facilitating rapid decarbonization of the world’s energy systems? We examine how core assumptions concerning the roles of the nation state, carbon markets and finance and technology in international climate policy are being challenged by the realities of how transitions in the energy systems are unfolding. Drawing on the critical region of sub-Saharan Africa, we examine the potential for international climate policy to foster new trajectories towards decarbonization.

Policy relevance

The international regime for climate policy has been in place for some twenty years. Despite significant changes in the landscape of energy systems and drivers of global GHG emissions over this time, the core principles and tools remain relatively stable – national governments, carbon markets, project-based climate finance and the transfer of technological hardware. Given the diversity of actors and drivers and the limited direct reach and influence of international climate policy, however, there is an urgent need to consider how the climate regime can best support the embryonic transitions that are slowly taking form around the world. To do this effectively requires a more nuanced understanding of the role of the state in governing these transitions beyond the notion of a cohesive state serving as rule-enforcer and transition manager. It also requires a broader view of technology, not just as hardware that is transferred, but as a set of practices and networks of expertise and enabling actors. Likewise, though markets have an important role to play as vehicles for achieving broader ends, they are not an end in themselves. Finally on finance, while acknowledging the important role of climate aid, often as a multiplier or facilitator of more ambitious private flows, it is critical to differentiate between the types of finance required for different transitions, many of which will not be counted under, or directed by, the climate regime. In sum, the (low-) carbon economy is being built in ways and in numerous sites that the climate regime needs to be cognizant of and engage with productively, and this may require fundamental reconsideration of the building blocks of the international climate regime.     

The Geochemistry of Lake Joyce, McMurdo Dry Valleys, Antarctica

Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3O4). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters.     

Nickel, Copper, Zinc and Cadmium Cycling with Manganese in Lake Vanda (Wright Valley, Antarctica)

Lake Vanda is a closed-basin, permanently ice-covered lake located in the Wright Valley of Antarctica. The lakes more important geochemical features include the fact that it is fed by a single glacial melt water stream for only 6–8weeks out of the year; that it has remained stratified for more than a millennium; and that, like other lakes in the region, it is remote from anthropogenic influence. These, together with the fact that it is among the least biologically productive lakes in the world, make it an ideal system for examining the transport, cycling and fate of trace metals in the aquatic environment. Like others before us, we view this lake as a natural geochemical laboratory, a flask in the desert. This paper presents the first set of closely spaced, vertical, profiles for dissolved and particulate Mn, Fe, Ni, Cu, Zn and Cd in the water column. Despite the absence of an outflow, metals in the fresh upper waters of the lake have extremely low concentrations, in the pico-molar to nano-molar range, and are partitioned largely into dissolved rather than particulate phases. Efficient metal scavenging by particles from these oxygen-rich waters is indicated. Significant increases in metal concentrations begin to appear at depth, between 57 and 60m, and these increases coincide with the onset of manganese oxide dissolution in oxic, but lower pH waters. Vertical profiles suggest that the entire suite of trace metals (Ni, Cu, Zn, and Cd) is being released from manganese oxide carrier phases. Thermodynamic analysis indicates that Mn3O4 (i.e., the mineral hausmannite) may be important in metal sequestration and recycling in the deeper waters of Lake Vanda. Manganese-reducing organisms reported by Bratina etal. (1998) are active in the zone of metal release and these could also contribute to the observed cycling.