Analysis of Karst Tufa from Guangxi, China

The paper presents an analysis of characteristic karst tufa from Guangxi, China, which has not been studied before. A comparison with tufa from Dinaric Karst of Croatia is discussed in view of the C-type climate. The major mineral is calcite. Minor minerals are quartz and dolomite, depending on location. The content of calcium carbonate varies from 65% to 92%, and that of magnesium carbonate from 0.03% to 1.77%. Among other elements, the most abundant are Fe, from 0.02% to 1.50%, and Ti, from 0.15% to 0.27%. Many other trace elements (V, Cr, Mn, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Y, Zr, Hg and Pb) are also present. Specific activity of radionuclides 40K, 232Th, 137Cs, 226Ra and 238U varies from sample to sample. Concentration of U in tufa is close to that reported for sedimentary carbonate. Low concentration of 137Cs indicates that this part of the world was not exposed to nuclear explosions. The concentration of 226Ra is the highest in Mashan County. The ratio 238U/226Ra (0.21-0.71) in tufa from Mashan Co     

Assessment of pollution sources in the southeastern of the Riyadh and its impact on the population/Saudi Arabia

The rapid growth of Riyadh—capital of Saudi Arabia—is pushing the area to more pollution and incentive for reorganization. The aim of this research is to assess air pollutants in southeast of Riyadh and detect opinion of the population about their environment. The assessment was done by analyzing 405 questionnaires, evaluating thermal band of Landsat 8, and spatial analyzing of particular matter and chemicals in 19 air samples by geostatistical tool in the ArcMap. Most of the inhabitants stated that they are suffering from bad odor, sewage leakage, and dust mainly from a cement factory. The thermal band of Landsat clarified the location of the pollution sources mainly the 1st industrial city, Yammama Cement Factory, and power plant in Farouq area. The ordinary kriging maps showed that the highest concentration of PM₁₀ (>403 μg/m³) lied to the northern and western side of the study area and caused a health issue to most inhabitants.     

Isotopic characteristics of precipitation in Slovenia and Croatia: Comparison of continental and maritime stations

The stable isotopic composition of hydrogen and oxygen (δ²H and δ¹⁸O) and tritium activity (³H) were monitored in monthly precipitation at two continental stations (Ljubljana, Zagreb) and six stations along the eastern Adriatic coasts of Slovenia and Croatia in the period 2001–2003. Mean air temperatures and amount of precipitation were also recorded.

Distinct differences in both meteorological and isotopic data between the continental and maritime stations were observed. Seasonal variations in δ¹⁸O are smaller at the maritime stations than at the continental ones due to smaller seasonal temperature variations. A good correlation between δ¹⁸O and δ²H was obtained for each station, and the local meteoric water lines are close to the Global Meteoric Water Line, with a decreasing trend of slope for the south-Adriatic stations. Good correlations between δ¹⁸O in monthly precipitation and mean monthly air temperature were observed at all stations. The slope of δ¹⁸O vs. T varied between 0.37‰ °C⁻¹ and 0.15‰ °C⁻¹. Mean ³H activity and seasonal variation of ³H activity are smaller at maritime stations than at continental ones. Additionally, ³H activity decreases in the NW–SE direction of the Adriatic coast.

The study of spatial variations over this relatively small area rich in geographical and climatic diversities showed the complexity of the isotopic composition of precipitation and the isotopic data obtained for eight stations, most of them in the karstic area along the Adriatic coast, and gave valuable information for regional hydrological investigations and modelling of isotope variability over the Mediterranean basin.     

Intraurban variability of PM10 and PM2.5 in an Eastern Mediterranean city

The results of the first large scale chemical characterization of PM10 and PM2.5 at three different sites in the urban city of Beirut, Lebanon, are presented. Between May 2009 and April 2010 a total of 304 PM10 and PM2.5 samples were collected by sampling every sixth day at three different sites in Beirut. Observed mass concentrations varied between 19.7 and 521.2 μg m^? 3 for PM10 and between 8.4 and 72.2 μg m^? 3 for PM2.5, respectively. Inorganic concentrations accounted for 29.7–35.6 μg m^? 3 and 46.0–53.5 μg m^? 3 of the total mass of PM10 and PM2.5, respectively. Intra-city temporal and spatial variations were assessed based on the study of three factors: correlation coefficients (R) for PM and chemical components, coefficient of divergence (CODs), and source apportionment using positive matrix factorization (PMF). Based on R and COD of PM concentrations, the three sites appear homogeneous. However, when individual elements were compared, heterogeneity among sites was found. This latter was attributed to the variability in the percent contribution of biogenic and local anthropogenic source factors such as traffic related sources and dust resuspension. Other factors included the proximity to the Mediterranean sea, the population density and the topographical structure of the city. Hence, despite its small size (20.8 km²), one PM monitoring site does not reflect an accurate PM level in Beirut.     

An ab-initio Hartree-Fock study of α-quartz and stishovite

-quartz and stishovite have been studied using a periodic ab-initio Hartree-Fock method in order to characterize the chemical nature of the Si-O bond and the way in which it changes with the coordination number of Si. Structural properties, including unit cell volume and c/a ratio have been optimized in order to evaluate the reliability of the method and the effect of the basis set. Density of states and electron charge density maps have been taken into account to investigate the electronic properties of the two systems and the rôle played by different orbitals. We also present comparisons with experimental X-ray emission data. The importance of d orbitals is stressed by our calculations, and a possible interpretation of the Si-O bond proposed. Quartz is found to be more covalent than stishovite.     

Clay minerals in fluvial shaley sandstone of upper Triassic reservoir (TAGS)—Toual field SE Algeria: identification from wireline logs and core data

The creep property of rock under cyclic loading is very important in civil engineering. In order to establish a novel constitutive equation for rock under cyclic loading, a fractional-order viscoplastic body under cyclic loading was constructed based on fractional-order viscous element. A fractional-order visco-elastoplastic model (FVEPM) for rock was established by connecting constructed fractional-order viscoplastic body with Burgers model. The model was a Burgers model when the maximum value of cyclic loading was less than the critical strength of rock; otherwise, it was a FVEPM which can be used to reflect the transient, steady-state, and tertiary creep phases of rock. The cyclic loading was decomposed into a static load and a cyclic loading with a zero average stress. According to rheological mechanics theory, the rheology constitutive equation of rock under the static load can be derived. According to viscoelastic mechanics theory, the constitutive equation under cyclic loading with a zero average stress was established by introducing the variation parameters of energy storage and energy dissipation compliance caused by rock damage and fracture. Finally, a new dynamic constitutive equation of rock cyclic loading can be obtained by superimposing the constitutive equation under static load and cyclic loading with a zero average stress. Compared with existing test results of rock under cyclic loading, the proposed constitutive model can be used to describe the creep characteristics of rock under cyclic loading and reflect the presented fluctuation of strain curve of rock under cyclic loading.     

Meteoric phreatic speleothems and the development of cave stratigraphy: An example from Tounj Cave, Dinarides, Croatia

Speleothems occurring in some caves of the carbonate Dinarides line all channel surfaces, and have been deposited from meteoric waters under phreatic conditions. Such phreatic speleothemic deposition modifies common experience (l) that meteoric phreatic conditions cause dissolutional widening of cave voids, and (2) that speleothems imply vadose conditions. The phreatic speleothems described here postdate an early polygenetic evolution of the cave voids, and predate the last, vadose stage. They were likely produced during the late/postglacial warming period, when dissolved carbonate was amply supplied, and when there was much water available for saturation of underground voids. Phreatic speleothems may be used as a tool for time correlation of internal deposits, both within one cave and within a karst region. They indicate an important stage in the history of the ground-water regime of an area. In general, phreatic speleothems help in better understanding of the development of subterranean voids and related karst/palaeokarst.