Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field

Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid,     

A New Progress of the Proterozoic Chronostratigraphical Division

The Precambrian, an informal chronostratigraphical unit, represents the period of Earth history from the start of the Cambrian at ca. 541 Ma back to the formation of the planet at 4567 Ma. It was originally conceptualized as a "Cryptozoic Eon" that was contrasted with the Phanerozoic Eon from the Cambrian to the Quaternary, which is now known as the Precambrian and can be subdivided into three eons, i.e., the Hadean, the Archean and the Proterozoic. The Precambrian is currently divided chronometrically into convenient boundaries, including for the establishment of the Proterozoic periods that were chosen to reflect large-scale tectonic or sedimentary features(except for the Ediacaran Period). This chronometric arrangement might represent the second progress on the study of chronostratigraphy of the Precambrian after its separation from the Phanerozoic. Upon further study of the evolutionary history of the Precambrian Earth, applying new geodynamic and geobiological knowledge and information, a revised division of Precambrian time has led to the third conceptual progress on the study of Precambrian chronostratigraphy. In the current scheme, the Proterozoic Eon began at 2500 Ma, which is the approximate time by which most granite-greenstone crust had formed, and can be subdivided into ten periods of typically 200 Ma duration grouped into three eras(except for the Ediacaran Period). Within this current scheme, the Ediacaran Period was ratified in 2004, the first period-level addition to the geologic time scale in more than a century, an important advancement in stratigraphy. There are two main problems in the current scheme of Proterozoic chronostratigraphical division:(1) the definition of the Archean–Proterozoic boundary at 2500 Ma, which does not reflect a unique time of synchronous global change in tectonic style and does not correspond with a major change in lithology;(2) the round number subdivision of the Proterozoic into several periods based on broad orogenic characteristics, which has not met with requests on the concept of modern stratigraphy, except for the Ediacaran Period. In the revised chronostratigraphic scheme for the Proterozoic, the Archean–Proterozoic boundary is placed at the major change from a reducing early Earth to a cooler, more modern Earth characterized by the supercontinent cycle, a major change that occurred at ca. 2420 Ma. Thus, a revised Proterozoic Eon(2420–542 Ma) is envisaged to extend from the Archean–Proterozoic boundary at ca. 2420 Ma to the end of the Ediacaran Period, i.e., a period marked by the progressive rise in atmospheric oxygen, supercontinent cyclicity, and the evolution of more complex(eukaryotic) life. As with the current Proterozoic Eon, a revised Proterozoic Eon based on chronostratigraphy is envisaged to consist of three eras(Paleoproterozoic, Mesoproterozoic, and Neoproterozoic), but the boundary ages for these divisions differ from their current ages and their subdivisions into periods would also differ from current practice. A scheme is proposed for the chronostratigraphic division of the Proterozoic, based principally on geodynamic and geobiological events and their expressions in the stratigraphic record. Importantly, this revision of the Proterozoic time scale will be of significant benefit to the community as a whole and will help to drive new research that will unveil new information about the history of our planet, since the Proterozoic is a significant connecting link between the preceding Precambrian and the following Phanerozoic.     

上扬子区寒武系娄山关群白云岩层序地层格架及其古地理背景

上扬子区特别是贵州及其邻区的寒武系娄山关群发育一套化石贫乏的浅水台地相白云岩,横跨中、上寒武统,厚度上千米,自北西向南东随着沉积环境水体的加深逐渐相变为开阔海台地相灰岩、陆棚相泥页岩等。由于化石贫乏难以进行详尽的年代地层划分,但是发育石盐假晶泥晶白云岩所反映的沉积环境水体变浅以及发育颗粒白云岩所反映的水体加深,表明可以应用从岩相序列到沉积相序列的方法对该套白云岩进行层序地层划分,成为在“海平面变化的框架内探讨沉积相迁移”的典型代表。巨厚的贫乏化石的娄山关群白云岩与下伏厚度较小、产三叶虫化石的陡坡寺组白云质细粒混合岩系形成了鲜明的对照,它们组成了1个二级层序,并可以划分为7个三级层序。陡坡寺组细粒混合岩系代表了二级海侵作用所造成的水体加深,而娄山关群白云岩自北西向南东进积尖灭则代表了二级海退过程所造成的水体变浅。该二级层序本身即是1个总体向上变浅的沉积相序列,其相序组构与三级层序相似,三级层序的相序组构与那些由岩相序列所组成的若干环潮坪型米级旋回也具有相似性。因此研究区娄山关群白云岩构成了1个复杂而有规律的、独特的层序地层格架,并由此反映了沉积物的时间演变序列和沉积相的空间展布特征具有一定的规律性,代表了其古地理演变过程既受制于海侵加深和海退变浅的时间过程,同时又受控于沉积环境水体自北西向南东由浅变深的空间变化过程。娄山关群白云岩的层序地层研究表明：层序地层学研究的核心是沉积物的时间演变序列以及沉积相的空间展布形式所代表的规律性,并根据这种规律性进行地层划分和对比。     

独立参数降雹条件概率法识别雹云之探讨

利用江苏盐城和福建雷达回波资料，探空资料，天气实况，对独立参数降雹条件概率法识别雹云的应用范围，零度层高度对识别准确率的影响以及如何选取区分水平高的参数等问题进行了探讨，得出一些有意义的结论，有一定的实用价值。     

Regularity and estimation of methane emission from marshland in the Sanjiang Plain

ＲＥＧＵＬＡＲＩＴＹＡＮＤＥＳＴＩＭＡＴＩＯＮＯＦＭＥＴＨＡＮＥＥＭＩＳＳＩＯＮＦＲＯＭＭＡＲＳＨＬＡＮＤＩＮＴＨＥＳＡＮＪＩＡＮＧＰＬＡＩＮ①ＣｕｉＢａｏｓｈａｎ（崔保山）ＭａＸｕｅｈｕｉ（马学慧）ＣｈａｎｇｃｈｕｎＩｎｓｔｉｔｕｔｅｏｆＧｅｏｇｒ...     

Sedimentary Features and Their Implications of Microdigital Stromatolites from the Mesoproterozoic Wumishan Formation at the Jixian Section in North China

<正>The Mesoproterozoic Wumishan Formation at the Jixian section in Tianjin is a set of more than 3000-m-thick stromatolitic carbonate succession.In this succession,several lithofacies units,that is,the subtidal stromatolitic biostrome,the thrombolitic bioherm,tidal-flat micritic dolomite and lagoon dolomitic shale,make up many meter-scale cycles of the peritidal carbonate type that have been nominated as the Wumishan cycles.Importantly,many microdigital stromatolites make up the stromatolitic biostrome unit of the Wumishan cycles in the lower part of the Wumishan Formation. These microdigital stromatolites have been grouped as a stromatolitic assemblage by paleontologists, that is,"Pseudogymnosolen mopanyuensis-Scuphus-Yangzhuang columnaris"assemblage.These microdigital stromatolites had also been interpreted as the aragonite(tufa) sea-floor precipitates by sedimentologists,and has further been thought as the special products of the transitional period from the sea-floor aragonite precipitates of the Archean to the clastic and muddy carbonates of the Neoproterozoic.Although there are some restrictions for the stratigraphic meaning of the concept of the stromatolitic assemblage,detailed studies on classification by paleontologists provide an important clue to understand the sedimentological meaning of the microdigital stromatolites.Furthermore,an important and obvious horizon for the end of the microdigital stromatolites was recorded in the Mesoproterozoic Wumishan Formation at the Jixian section,which provides useful information to understand the stromatolite decline occurred at c.1250 Ma and the evolving carbonate world of the Precambrian.     

云南哈播斑岩型铜（ 钼 金）矿床地质与成矿背景研究

哈播斑岩铜(-钼-金)矿床位于哀牢山-红河新生代成矿带南端西侧,是近年来新发现的一个斑岩型矿床.矿区内出露的哈播侵入体具有多期侵入的特征,花岗岩依次侵入的序列为坪山花岗岩、三道班花岗岩、阿树花岗岩、哈播南山花岗岩(37.3 Ma),随后有4期斑岩侵入到哈播南山花岗岩中,依次为黑云母钾长石斑岩、石英钾长石斑岩、石英二长斑岩和晚期黑云母钾长石斑岩岩脉.采用LA-ICP-MS锆石U-Pb年龄法测定黑云母钾长石斑岩和石英二长斑岩的加权平均年龄分别为36.20±0.20 Ma和36.19±0.22 Ma,哈播南山花岗岩和4期斑岩具有相似的岩石地球化学特征,都有富钾、高氧化态和类似岛弧花岗岩的岩石地球化学特征,可能具有相同的来源.辉钼矿Re-Os年龄显示,哈播矿床的成矿年龄为35.47±0.16 Ma.相似的成岩-成矿年龄暗示哈播矿床成岩和成矿作用是一个连续的岩浆-热液过程,与玉龙斑岩铜矿相似.基于哈播矿床的岩石学、地球化学特点,结合前人关于青藏高原东部斑岩铜矿的研究成果,我们认为哈播斑岩矿床可能为藏东富碱斑岩带向东南的延伸,与玉龙斑岩铜矿带具有相似的成因,为哀牢山-红河新生代成矿带的重要组成部分,是晚碰撞构造转换背景下的重要产物.     

Maritime network dynamics before and after international events

Investigating the influence of international events on global maritime networks is a challenging task that must comprehensively incorporate geographical, political, and maritime sciences. Understanding global maritime network dynamics is an initial and critical step in this investigation. This study proposes an automatic identification system (AIS)-based approach to understanding maritime network dynamics before and after international events. In this approach, a spatiotemporal modeling method is introduced to measure the similarity in shipping trends before and after international events. Then, a spatiotemporal analytic framework is proposed to understand the maritime network dynamics by grouping similar situation, and assessing possible indirect effects within a network. Finally, three case studies of international events, military conflict, lifted economic sanctions, and government elections, were used to investigate the observed network dynamics possibly affected by international events. The results indicate that container, tanker, and bulk shipping between India and its connected countries all declined more than 69% after military conflicts between India and Pakistan in August 2015. Tanker shipping between Iran and the United Arab Emirates increased 51% after economic sanctions on Iran were lifted. Container shipping between Sri Lanka and Singapore, Malaysia, and India increased more than 74% after the general election in Sri Lanka. These investigations demonstrate the feasibility of the proposed approach in assessing the possible effects of international events on maritime network dynamics.     

中元古界非叠层石灰岩中的MISS:以北京延庆千沟剖面高于庄组第三段为例

前寒武纪碳酸盐岩多以叠层石碳酸盐岩序列为特征。燕山地区中元古界高于庄组,其中的第三段(张家裕亚组)则为一个以灰岩为主、贫乏叠层石的碳酸盐岩沉积序列,该序列被定义为前寒武纪非叠层石碳酸盐岩序列。该非叠层石碳酸盐岩沉积序列,尤其以燕山西部的延庆千沟剖面最为典型。根据沉积相序列及其所反映的旋回性,可以将该剖面的高于庄组第三段划分为3个三级层序。在这些三级层序的海侵体系域和早期高水位体系域中,中薄层隐晶质泥晶灰岩(均一石灰岩)和灰黑色薄层泥灰岩组成若干潮下型米级旋回;而在隐晶质泥晶灰岩层面上,普遍发育各种奇形怪状的沉积构造。这些沉积构造包括穹窿状构造、规则网状和杂乱的帐篷脊、变余波痕等,构成一个潮下相灰岩层面上的特别的微生物形成的沉积构造(Microbial Induced Sedimentary Structure,MISS)组合。因此,延庆千沟剖面的高于庄组第三段,特别的岩石类型和沉积构造成为前寒武纪碳酸盐岩沉积中非叠层石碳酸盐岩沉积序列的典型代表,尤其是那些奇形怪状的MISS所代表的沉积学特点表明:在前寒武纪,即使在叠层石生长的黄金时段,也发育非叠层石碳酸盐岩沉积序列。因此,这些现象将特别有助于对前寒武纪非叠层石生态系所造成的另一类席底生境的深入理解,也有助于复杂多变的碳酸盐岩世界。