Conditions of pocket formation in the Oktyabrskaya tourmaline-rich gem pegmatite (the Malkhan field, Central Transbaikalia, Russia)

Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl₂[AlSi₃O₁₀](OH,F)₂ series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H₃BO₃ contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B₂O₃, 3.64–5.20 wt.% Cs₂O, 0.54 wt.% Li₂O, 0.57 wt.% Ta₂O₅, 0.10 wt.% Nb₂O₅, 0.12 wt.% BeO. The H₂O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H₂O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.

Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H₂O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets.     

Some general relations of the development of complex molecular objects at early stages of biosphere formation as a consequence of the physical properties of condensed medium

We analyzed the character of molecular transformations under conditions of condensed media, in which intermolecular interactions always occur. It was shown that, instead of discrete transfer of external energy into the molecule, the energy characteristics of the condensed medium (appearance of zones) could result in gradual accumulation of internal energy in reaction centers owing to sequential thermal collisions with particles of the medium initiating the chemical reaction. This does not require high temperatures. The established physical properties related to the energy characteristics of condensed media could play an important role in molecular transformations and, consequently, formation of complex molecular objects at early stages of biosphere formation.     

Deficit of Large Aftershocks as an Indicator of Afterslip at the Sources of Earthquakes in Subduction Zones

Doklady Earth Sciences - A relative decrease in the fraction of large aftershocks in the first days after earthquakes in subduction zones is demonstrated, and a connection of this phenomenon with...     

Subpollen Particles as Atmospheric Cloud Condensation Nuclei

Izvestiya, Atmospheric and Oceanic Physics - Bioparticles constitute a significant fraction of atmospheric aerosol. Their size range varies from nanometers (macromolecules) to hundreds of...     

Testing the method for surface air temperature refinement based on a complex of models of the atmospheric boundary layer and local heat and water budgets

A method is considered for space-time refinement of surface air temperature obtained from the atmospheric general circulation model (GCM) of the Hydrometeorological Center of Russia over a limited area by means of use of a complex of the atmospheric boundary layer models and surface heat and water budget model. The latter describes all major processes of heat and water exchange at the underlying surface and within the soil and vegetation using 14 external parameters for different types of landscapes and soils. The side and upper boundary conditions for the local model are provided from the GCM model. Different statistical estimates of the modeling results show possibility and reliability of the refinement for time changes of the quantity under calculation as well as for development of averaged fields reflecting small-scale inhomogeneities of the landscape.     

Geodynamic models and their application in the combined interpretation of geological and geophysical data (a review)

The paper presents a review of investigations in the field of the theory and practice of the interpretation of geological and geophysical data with geodynamic models that were carried out mainly by researchers of the Institute of Physics of the Earth, Russian Academy of Sciences. Evolutionary models of platform structures, passive continental margins, rift zones, and orogens are examined. The review presents formulations of inverse problems and results of interpretation for various regions, including sedimentary basins of the East European Platform, Atlantic Ocean margins, the Caucasus, the South Urals, and others.     

Why the Sacramento Delta area differs from other parts of the great valley: Numerical modeling of thermal structure and thermal subsidence of forearc basins

Data on present-day heat flow, subsidence history, and paleotemperature for the Sacramento Delta region, California, have been employed to constrain a numerical model of tectonic subsidence and thermal evolution of forearc basins. The model assumes an oceanic basement with an initial thermal profile dependent on its age subjected to refrigeration caused by a subducting slab. Subsidence in the Sacramento Delta region appears to be close to that expected for a forearc basin underlain by normal oceanic lithosphere of age 150 Ma, demonstrating that effects from both the initial thermal profile and the subduction process are necessary and sufficient. Subsidence at the eastern and northern borders of the Sacramento Valley is considerably less, approximating subsidence expected from the dynamics of the subduction zone alone. These results, together with other geophysical data, show that Sacramento Delta lithosphere, being thinner and having undergone deeper subsidence, must differ from lithosphere of the transitional type under other parts of the Sacramento Valley. Thermal modeling allows evaluation of the rheological properties of the lithosphere. Strength diagrams based on our thermal model show that, even under relatively slow deformation (10⁻¹⁷ s⁻¹), the upper part of the delta crystalline crust (down to 20–22 km) can fail in brittle fashion, which is in agreement with deeper earthquake occurrence. Hypocentral depths of earthquakes under the Sacramento Delta region extend to nearly 20 km, whereas, in the Coast Ranges to the west, depths are typically less than 12–15 km. The greater width of the seismogenic zone in this area raises the possibility that, for fault segments of comparable length, earthquakes of somewhat greater magnitude might occur than in the Coast Ranges to the west. The text was submitted by the authors in English.     

Geomagnetic control of the foF2 long-term trends

Further development of the method proposed by Danilov and Mikhailov is presented. The method is applied to reveal the foF2 long-term trends on 30 Northern Hemisphere ionosonde stations. Most of them show significant foF2 trends. A pronounced dependence of trend magnitude on geomagnetic (invariant) latitude is confirmed. Periods of negative/positive foF2 trends corresponding to the periods of long-term increasing/decreasing geomagnetic activity are revealed for the first time. Pronounced diurnal variations of the foF2 trend magnitude are found. Strong positive foF2 trends in the post-midnight-early-morning LT sector and strong negative trends during daytime hours are found on the sub-auroral stations for the period with increasing geomagnetic activity. On the contrary middle and lower latitude stations demonstrate negative trends in the early-morning LT sector and small negative or positive trends during daytime hours for the same period. All the morphological features revealed of the foF2 trends may be explained in the framework of contemporary F2-region storm mechanisms. This newly proposed F2-layer geomagnetic storm concept casts serious doubts on the hypothesis relating the F2-layer parameter long-term trends to the thermosphere cooling due to the greenhouse effect.     

Regularities of hydrological processes in the Chesapeake Bay (USA): Case study of a classical estuary

The main regularities of hydrological and hydrological-environmental processes occurring within the complex estuary, the Chesapeake Bay and the mouths of its tributaries, are discussed. The peculiarities of the estuary morphological structure, including the structures of tidal and net currents, salinity and water turbidity fields and their variability, the environmental conditions, and their human-induced changes. Using the Chesapeake Bay as an example, it became possible to reveal the basic features of classical estuaries subject to a considerable impact of river runoff and featuring mixing of river and sea water and moderate stratification of the water mass. It is shown that the regularities of hydrological processes in the Chesapeake Bay are typical of many mouth water bodies of estuarine type (inlets, drowned river valleys, lagoons, and tidal estuaries proper).     

New definitions, regionalization, and typification of river mouth areas and estuaries as their parts

The problems of studying river mouth areas and their parts, namely, estuaries and deltas are discussed. The step is taken to combine the concept of river mouth area and mouth processes developed in our country with the concept for estuary and estuarine processes widely spread among foreign scientists. In this connection, the article offers new definitions of a river mouth area and estuary as well as new schemes of regionalization of river mouth areas and typification of estuaries. The types of river mouth areas and estuaries are illustrated by case studies.