Denudation,vertical crustal movements and sedimentary basin infill

Denudation and vertical crustal movements are linked through the isostatic equation for conservation of lithospheric mass. Recent empirical results from a wide range of sources are presented on the rates of these processes. Denudation alone can cause non-tectonic (isostatic) surface uplift of the right magnitude predicted by theory. A case is made, following Ahnert, for a single linear relationship (although with much scatter) between denudation rate and mean drainage basin relief for large basins. Some recent determinations of denudational time constants have neglected to include tectonic and isostatic terms which oppose the reduction of relief by denudation. Application of diffusional transport models to determine the rate of sediment deposition are severely limited by inherent one-dimensionality and neglect of suspended and washload contributions. Basin infill sequences may be used to determine past sediment transfer coefficients from a hinterland, but problems arise in the apportionment of the various hinterland fluxes that occur in »real-world« three dimensional basins. Sediment yields in smaller half-graben and growth fold basins must reflect the magnitude of drainage basins and the complex local controls upon sediment yields. Examples are given from extensional basins in the Western USA and Greece. The »length« of tectonic relief produced in tilt blocks and growth folds will control the area of drainage basin developed (through the fractal form of Hack's Law) and hence the magnitude of deposition in sedimentary basins adjoining tectonic uplands.

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Zusammenfassung Denudation und vertikale Krustenbewegungen sind verbunden durch das isostatische Gesetz über den Erhalt der lithosphärischen Masse. Neuerliche empirische Ergebnisse aus einem weiten Quellenbereich werden im Verhältnis zu diesen Prozessen präsentiert. Denudation allein, kann nicht tektonisch bedingte (isostatische) Oberflächenhebungen hervorrufen, die in der richtigen Größenordnung liegen, wie sie auch theoretisch ermittelt wurden. Es wird in Anlehnung an Ahnert ein Fall geschaffen, in der eine einfach lineare Beziehung (obgleich mit vielen Streuungen) zwischen der Denudationsrate und dem durchschnittlichen Abflußbeckenrelief für große Becken vorliegt. Einige neue Ermittlungen der Denudationszeitkonstanten wurden vernachlässigt, um tektonische und isostatische Begriffe einzufügen, welche sich der Verringerung des Reliefs durch Denudation widersetzen. Die Anwendung des Verbreitungstransportmodells zum Bestimmen der Sedimentationsrate sind streng begrenzt durch die ihm innewohnende Eindimensionalität, und der Vernachlässigung der Schwebe- und Schwämmfrachtbeteiligung. Bekkenfüllungssequenzen können benutzt werden um vergangene Sedimenttransferkoeffizienten aus dem Hinterland festzulegen; aber es treten auch Probleme bei der Verteilung der verschiedenen Hinterlandeinträge auf, die bei einem realen dreidimensionalen Becken vorhanden sind. Sedimenteinträge in kleineren Halbgräben und Growth-fold Becken müssen die Größe des Abflußbeckens widerspiegeln, sowie die komplexen lokalen Steuerungen auf die Sedimenteinträge. Beispiele von Dehnungsbecken aus dem Westen der USA und Griechenlands werden angesprochen. Die Länge des tektonischen Reliefs in verkippten Blöcken und Growth-Folds wird die Fläche des entwickelten Abflußbeckens kontrollieren (durch die fraktale Form des Gesetzes von Hack), und daher die Ablagerungsmenge von Sedimentbecken in der Nähe von tektonischen Hochlagen.

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Résumé L'érosion et les mouvements crustaux verticaux sont liés par l'équation isostatique de conservation de la masse lithosphérique. Des résultats empiriques récents provenant d'un large éventail de sources sont présentés en relation avec ces processus. L'érosion seule peut être la cause d'une montée non tectonique (isostatique) dont l'ampleur est prévue exactement par la théorie. Un cas est présenté, d'après Ahnert, qui montre, pour de grands bassins, une relation linéaire simple (mais avec une forte dispersion des points) entre le taux de dénudation et le relief moyen de l'aire de drainage. Certaines déterminations récentes des constantes de temps de dénudation ont omis de tenir compte des termes tectonique et isostatique qui s'opposent à la destruction du relief par érosion. L'utilisation de modèles de transport diffus en vue de déterminer le taux d'accumulation des sédiments est sévèrement limitée par le caractère unidimensionnel de tels modèles et par le fait qu'il ne tiennent pas compte de la fraction en suspension. Les séquences de comblement d'un bassin sédimentaire peuvent être utilisées pour déterminer les anciens cfficients de transfert à partir de l'hinterland; mais des difficultés surgissent à propos de la répartition des différents flux en provenance de l'hinterland dans le cas réel d'un bassin à 3 dimensions. Les apports sédimentaires dans les bassins de demi-graben et de »growth-fold« doivent traduire la grandeur des aires de drainage et les facteurs locaux complexes qui régissent ces apports. Des exemples sont présentés, relatifs à des bassins d'extension de l'ouest des USA et de Grèce. La »longueur« des reliefs tectoniques en relation avec les blocs basculés et les »growth-folds« déterminent, par la forme fractale de la loi de Hack, la surface des aires de drainage ainsi engendrées et, en conséquence, l'importance des dépôts dans les bassins sédimentaires voisins des reliefs tectoniques.

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Shock chemistry in the molecular clouds associated with SNR IC 443

Several interstellar molecules have been detected toward the highly perturbed B and G clouds associated with the supernova remnant IC 443 via their 3 mm transitions, including N2H+, SiO, SO, CN, HNC, and H13CO+. The (J, K) = (1, 1) and (2, 2) inversion lines of metastable ammonia have also been observed, as well as the J = 3-2 transition of HCO+ at 1.2 mm. Analysis of the (1, 1) and (2, 2) inversion lines of NH3 indicates minimum gas kinetic temperatures of TK = 70 K toward cloud B, and TK = 33 K in cloud G. Modeling of the J = 1-0 and J = 3-2 transitions of HCO+ implies densities greater than 10(5) cm-3 toward both positions. These data clearly show that hot and dense material is present in IC 443, and they suggest the presence of shocks in both regions. A careful analysis of the HCO+ lines indicates that the HCO+ abundance is at most enhanced by factors of a few over that found in cold, quiescent gas. This conclusion contradicts past claims of HCO+ abundance enhancements of several orders of magnitude in the perturbed regions. The N2H+ abundance was also found to be similar to that in cold gas, suggesting that there is no increase in ionization in the clouds. The abundances of SO and CS, as well as CN and NH3, do not appear to differ significantly from those found in cold dark clouds, although chemistry models predict sulfur-containing species to undergo high-temperature enhancements. SiO, however, is found to have an abundance in the perturbed gas 100 times larger than the upper limits observed in the dark cloud TMC 1, a result in agreement with high temperature chemistry models. In addition, the HNC/HCN ratio in both IC 443 B and G was found to be approximately 0.1--far from the ratio of 1 predicted by low-temperature ion-molecule chemistry, but similar to the values observed in clouds where elevated temperatures are present.     

Geochemistry of oceanic carbonatites compared with continental carbonatites: mantle recycling of oceanic crustal carbonate

Major and trace element and Sr-Nd-Pb-O-C isotopic compositions are presented for carbonatites from the Cape Verde (Brava, Fogo, Sáo Tiago, Maio and Sáo Vicente) and Canary (Fuerteventura) Islands. Carbonatites show pronounced enrichment in Ba, Th, REE, Sr and Pb in comparison to most silicate volcanic rocks and relative depletion in Ti, Zr, Hf, K and Rb. Calcio (calcitic)-carbonatites have primary (mantle-like) stable isotopic compositions and radiogenic isotopic compositions similar to HIMU-type ocean island basalts. Cape Verde carbonatites, however, have more radiogenic Pb isotope ratios (e.g. ²⁰⁶Pb/²⁰⁴Pb=19.3-20.4) than reported for silicate volcanic rocks from these islands (18.7-19.9; Gerlach et al. 1988; Kokfelt 1998). We interpret calcio-carbonatites to be derived from the melting of recycled carbonated oceanic crust (eclogite) with a recycling age of ~1.6 Ga. Because of the degree of recrystallization, replacement of calcite by secondary dolomite and elevated ‘¹³C and ‘¹⁸O, the major and trace element compositions of the magnesio (dolomitic)-carbonatites are likely to reflect secondary processes. Compared with Cape Verde calcio-carbonatites, the less radiogenic Nd and Pb isotopic ratios and the negative Ɨ/4 of the magnesio-carbonatites (also observed in silicate volcanic rocks from the Canary and Cape Verde Islands) cannot be explained through secondary processes or through the assimilation of Cape Verde crust. These isotopic characteristics require the involvement of a mantle component that has thus far only been found in the Smoky Butte lamproites from Montana, which are believed to be derived from subcontinental lithospheric sources. Continental carbonatites show much greater variation in radiogenic isotopic composition than oceanic carbonatites, requiring a HIMU-like component similar to that observed in the oceanic carbonatites and enriched components. We interpret the enriched components to be Phanerozoic through Proterozoic marine carbonate (e.g. limestone) recycled through shallow, subcontinental-lithospheric-mantle and deep, lower-mantle sources.     

Cluster gets to grips with the magnetosphere

On 9 November 2001 RAS hosted the first UK meeting to discuss results from Cluster, itself the first mission to explore the Earth's magnetosphere with four identically instrumented spacecraft – and thus fully resolve the complex spatial and temporal variations of the plasmas that fill space around the Earth. Mike Hapgood reports.     

Wide-angle seismic velocities in heterogeneous crust

Seismic velocities measured by wide-angle surveys are commonly used to constrain material composition in the deep crust. Therefore, it is important to understand how these velocities are affected by the presence of multiscale heterogeneities. The effects may be characterised by the scale of the heterogeneity relative to the dominant seismic wavelength (λ); what is clear is that heterogeneities of all scales and strengths bias wide-angle velocities to some degree. Waveform modelling was used to investigate the apparent wide-angle P -wave velocities of different heterogeneous lower crusts. A constant composition (50 per cent felsic and 50 per cent ultramafic) was formed into a variety of 1- and 2-D heterogeneous arrangements and the resulting wide-angle seismic velocity was estimated. Elastic, 1-D models produced the largest velocity shift relative to the true average velocity of the medium (which is the velocity of an isotropic mixture of the two components). Thick (width > λ) horizontal layers, as a result of Fermat's Principle, provided the largest increase in velocity; thin (width ≪λ) vertical layers produced the largest decrease in velocity. Acoustic 2-D algorithms were shown to be inadequate for modelling the kinematics of waves in bodies with multiscale heterogeneities. Elastic, 2-D modelling found velocity shifts (both positive and negative) that were of a smaller magnitude than those produced by 1-D models. The key to the magnitude of the velocity shift appears to be the connectivity of the fast (and/or slow) components. Thus, the models with the highest apparent levels of connectivity between the fast phases, the 1-D layers, produced the highest-magnitude velocity shifts. To understand the relationship between measured seismic velocities and petrology in the deep crust it is clear that high-resolution structural information (which describes such connectivity) must be included in any modelling.