An occurrence of ardennite in quartz veins in piemontite schist,Western Otago,New Zealand

Summary Ardennite of complex composition: (Mn²⁺ _3.488Ca_0.509Ba_0.002)₌₄(Mg_0.916916 Fe³⁺ _0.165 Mn³⁺ _0.099Cu_0.033Ni_0.009Zn_0.006 Ti_0.008Al_4.764)₌₆(As⁵⁺ _0.823V⁵⁺ _0.022P_0.005B_0.069Al_0.042Si_5.039)₌₆O_21.81(OH)_6.17 occurs in crack-seal quartz veins in quartz-albite-piemontite-spessartine-phengitehematite-chlorite-rutile-tourmaline ± calcite schist of the Haast Schist Group near Arrow Junction, western Otago, New Zealand. The Mn²⁺/Mn³⁺-ratio is sensitive to calculations and to accuracy of analyses. Boron is detected in ardennite for the first time. Other properties include = 1.734(3), = 1.735(3), = 1.751(3), 2V_Z = 30(2)°;a = 8.721(1),b = 5.816(1),c = 18.545(3) Å,V = 940.7(2) ų. Associated mineral phases are spessartine, hematite, piemontite containing 0.7% SrO and 0.06% PbO, and phengite. Later-stage vein minerals comprise chlorite, albite, and manganoan calcite which were deposited under less highly oxidizing conditions. Digenite with minor intergrown covellite occurs in small amount with manganoan calcite and quartz in a cross-cutting late-stage veina chalcopyrite and native copper occur in other late-stage veins. Arsenic and other components of the ardennite and associated minerals are derived from highly oxidized ferromanganese oxide- and hydroxide-bearing siliceous pelagic sediments that formed the protolith for the piemontite schist. The veins formed at a relatively early stage after metamorphism peaked in the chlorite zone of the greenschist facies under conditions that have been estimated at about 4.5 kbar, 390 °C.

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Vorkommen von Ardennit in Quarzgängen aus Piemontit-Schiefern, West-Otago, Neuseeland

Zusammenfassung Ardennit mit der Zusammensetzung (Mn²⁺ _3.488Ca_0.509Ba_0.002)₌₄(Mg_0.916Fe³⁺ _0.165Mn³⁺ _0.099Cu_0.033Ni_0.009Zn_0.006 Ti_0.008Al_4.764)₌₆(As⁵⁺ _0.823V⁵⁺ _0.022P_0.005B_0.069Al_0.042Si_5.039)₌₆O_21.81(OH)_6.17 tritt in Crack-seal-Quarzgängen in Quarz-Albit-Piemontit-Spessartin-Phengit-Hämatit-Chlorit-Rutil-Turmalin ± Calcit-Schiefern der Haast Schiefer-Gruppe nahe der Arrow Junction, West-Otago, Neuseeland, auf. Die Proportionen von Mn²⁺/Mn³⁺ hängen von der Kalkulation und der Genauigkeit der Analyse ab. Bor wird zum ersten Mal im Ardennit bestimmt. Andere Eigenschaften sind: = 1.734(3), = 1.735(3), = 1.751(3), 2Vz = 30(2)°; a = 8.721(1), b = 5.816(1), c = 18.545(3) Å, V = 940.7(2) Å3. Assoziierte Mineralphasen sind Spessartin, Hämatit, Piemontit, der 0.7% SrO und 0.06% PbO enthält und Phengit. Spät gebildete Gangmineralien, wie Chlorit, Albit und Mn-Calcit, sind unter geringer oxidierenden Bedingungen entstanden. Digenit mit etwas Covellin tritt in kleinen Mengen zusammen mit Mn-Calcit und Quartz in einem querschlägigen Gang auf, Chalcopyrit und gediegenes Kupfer kommen in anderen späten Gängen vor. Arsen und andere Komponenten des Ardennites and der assoziierten Minerale können von hochoxidierten, Fe-Mn-Oxid- und Hydroxyd-führenden, Sireichen, pelagischen Sedimenten hergeleitet werden, die das Ausgangsgestein für den Piemontit darstellen. Die Gänge wurden in einem relativ frühen Stadium, nach dem Metamorphosehöhepunkt, innerhalb der Chloritzone der Grünschiefer-Fazies, unter ungefähr 4.5 kbar und 390°C, gebildet.

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With 4 Figures     

Andradite and andradite-grossular solid solutions in very low-grade regionally metamorphosed rocks in Southern New Zealand

Almost pure andradite and intermediate members of the andradite-grossular series (gros_40–49, and _47–54, py_0–3, alm_0–3, spess_0–2, hydrogarnet_0–3), often framboidal in habit, are widespread in metabasites including lavas, minor intrusions, and volcanic sandstones and breccias metamorphosed under prehnite-pumpellyite and pumpellyite-actinolite facies conditions, possibly extending into the zeolite facies. Coexisting phases include iron-rich epidotes (100 Fe*/Fe*+Al=22–34), pumpellyite, prehnite, actinolite, and chlorite, electron microprobe analyses of which are given, as well as quartz, albite, and calcite. Zoisite (100 Fe*/Fe*+Al=1–5) and iron-poor epidote (100 Fe*/Fe*+Al=11–18) occur in 2 rocks in pseudomorphs after plagioclase together with more iron-rich epidote, but not in close association with the garnets. Coexisting pumpellyite is iron-rich (FeO* 9–14%) in the prehnite-pumpellyite facies and iron-poor (FeO* 5%) in the pumpellyiteactinolite facies. Chlorites and actinolites vary widely and sympathetically in FeO/MgO+FeO ratio. Andradite is also described from a stilpnomelane-actinolite-hematite-bearing andradite quartzite of the pumpellyite-actinolite facies. Conditions of formation involved temperatures of 300 to 400 ° or less, at pressures up to a few kilobars. A wide range of oxygen fugacities is possible, but in the fluid phase was low. Grandite and chlorite are incompatible in the pumpellyite-actinolite and greenschist facies in the presence of quartz but the 2 minerals occur together in some pumpellyite-actinolite facies assemblages as a result of incomplete reaction and/or local deficiency in silica. In the greenschist facies the association is replaced by epidote-actinolite±hematite and sodic amphibole. Whereas at medium to high grades of metamorphism andradite and grandite are characteristic of skarns irrespective of , at very low grades they are found in mafic volcanic rocks and volcanogenic sediments as well as in certain cherty rocks of unusual composition, rodingites, and serpentinites, where was very low.     

Nutricline shoaling in the eastern Pacific warm pool during the last two glacial maxima

Isoprenoid glycerol dialkyl glycerol tetraethers (GDGTs) and alkenones were analyzed in sediment samples retrieved from Ocean Drilling Program Site 1241 covering the last 150000 years to understand the hydrological evolution of the eastern Pacific warm pool (EPWP). GDGT and alkenone concentrations showed higher values in marine isotope stage (MIS)-2 and MIS-6, which suggests the enhancement of primary production at glacial maxima. $ {\text{TEX}}_{86}^{\text{H}} $ - and $ U_{ 3 7^\prime }^{\text{K}} $ -derived temperature depicted different temperature evolutions. $ U_{ 3 7^\prime }^{\text{K}} $ -derived temperature was marked by small variation during the glacial–interglacial cycles, whereas $ {\text{TEX}}_{86}^{\text{H}} $ -derived temperature showed pronounced glacial–interglacial variation that was similar to Mg/Ca-derived temperature records from nearby cores in the EPWP. Given that enhanced primary production during glacial maxima suggests nutricline shoaling, unchanged $ U_{ 3 7^\prime }^{\text{K}} $ over glacial–interglacial cycles can be interpreted as the shift of alkenone production depth. $ {\text{TEX}}_{86}^{\text{H}} $ seems not to be influenced by glacial–interglacial changes in nutricline depths, recording an integrated temperature in surface and thermocline water. The shallow nutricline in the EPWP during glacial maxima most likely reflected the intense formation of Antarctic intermediate water.     

Calibration and validation of the ocean color version-3 product from ADEOS OCTS

We present calibration and validation results of the OCTS’s ocean color version-3 product, which mainly consists of the chlorophyll-a concentration (Chl-a) and the normalized water-leaving radiance (_nL_w). First, OCTS was calibrated for the inter-detector sensitivity difference, offset, and absolute sensitivity using external calibration source. It was also vicariously calibrated using in-situ measurements for water (Chl-a and_nL_w) and atmosphere (optical thickness), which were acquired synchronously with OCTS under cloud-free conditions. Second, the product was validated using selected 17 in-situ Chl-a and 11 in-situ_nL_w measurements. We confirmed that Chl-a was estimated with an accuracy of 68% for Chl-a less than 2 mg/m³, and_nL_w from 94% (band 2) to 128% (band 4). Geometric accuracy was improved to 1.3 km. Stripes were significantly reduced by modifying the detector normalization factor as a function of input radiance.     

Hydrogeochemistry and groundwater salinization in an ephemeral coastal flood plain: Cap Bon,Tunisia

Abstract

The Wadi Al Ayn plain is a coastal system on the eastern coast of Cap Bon in northeastern Tunisia. The area is known for its intensive agriculture, which is based mainly on groundwater exploitation. The aim of this study is to identify the sources of groundwater salinization in the Wadi Al Ayn aquifer system and deduce the processes that drive the mineralization. Surface water and groundwater samples were taken and analysed for major ions and stable isotopes. The geochemical data were used to characterize and classify the water samples based on a variety of ion plots and diagrams. Stable isotopes are useful tools to help us understand recharge processes and to differentiate between salinity origins. The oilfield brines infiltrated from the sandy bed of Wadi Al Ayn comprise the main source of groundwater salinization in the central part of the plain, while seawater intrusion is mainly responsible for the increased salinity in the groundwater of the coastal part of the plain (at Daroufa).

Citation Chekirbane, A., Tsujimura, M., Kawachi, A., Isoda, H., Tarhouni, J., and Benalaya, A., 2013. Hydrogeochemistry and groundwater salinization in an ephemeral coastal flood plain: Cap Bon, Tunisia. Hydrological Sciences Journal, 58 (5), 1097–1110.     

Inflation along Kilauea's Southwest Rift Zone in 2006

We report on InSAR and GPS results showing the first crustal inflation along the southwest rift zone at Kilauea volcano in over 20 years. Two independent interferograms (May 2–August 2, 2006 and June 22–Nov 7, 2006) from the ALOS PALSAR instrument reveal domal uplift located southwest of the main caldera. The uplift is bounded on the northeast by the caldera and follows the southwest rift zone for about 12 km. It is approximately 8 km wide. We use data derived from permanent GPS stations to calibrate the InSAR displacement data and estimate uplift of 7.7 cm during the first interferogram and 8.9 cm during the second with line-of-sight volumes of 2.8 × 10⁶ m³ and 3.0 × 10⁶ m³ respectively. The earthquake record for the periods before, during, and after inflation shows that a swarm of shallow earthquakes (z < 5 km) signaled the beginning of the uplift and that elevated levels of shallow seismicity along the rift zones occurred throughout the uplift period. GPS data indicate that the inflation occurred steadily over nine months between mid-January and mid-October, 2006 making injection of a sill unlikely. We attribute the inflation to recharge of a shallow ductile area under the SWRZ.     

Stereology-based fabric analysis of microcracks in damaged granite

Crack-related fabric analyses were carried out in terms of crack tensors using Inada granite deformed inelastically in a triaxial vessel up to post-failure, focusing on the fabric changes during brittle failure. Complementarily, numerical simulation tests were conducted to determine the representative volume element (RVE) required for crack surveying. Numerical simulation tests show that the window size for crack surveying should be at least six times the mean trace length in order to obtain a statistically meaningful crack tensor. A larger window is needed to estimate the distribution of crack radii. In quartz, cracks grow preferentially parallel to the major loading axis. Crack tensors in quartz can provide a measure of damage reflecting inelastic deformation under differential stress in past geological events. During the first stage of inelastic deformation, the number density of cracks decreases with a rather sharp increase in crack diameters. This happens because pre-existing cracks in intact rock join together to make longer cracks. However, the density remains almost constant during the second stage of loading from 90% to 100% of the peak stress. The crack diameter gradually increases due to the stable propagation of cracks. When granite is further deformed beyond the peak stress, the number density decreases again while sharp increases in crack diameters appear as a result of the forking and coalescence of cracks. It is also suggested that load-normal grain boundary cracks are generated as a result of the rolling and sliding of disintegrated blocks in the post-failure stage.     

Marine reservoir correction for the Pacific coast of central Japan using C ages of marine mollusks uplifted during historical earthquakes

In this study we utilize marine shell samples from two levels of historically uplifted sessile mollusk assemblages and raised wave-cut benches to evaluate the marine reservoir correction (ΔR) for the Pacific coast of central Japan. Elevation measurements of the uplifted marine shells indicate that the lower assemblage emerged during the 1923 Taisho Kanto earthquake (M7.9), whereas uplift of the upper assemblage is most likely but less confidently ascribed to the 1703 Genroku Kanto earthquake (M8.2). Radiocarbon dating of carefully selected samples from the upper and lower assemblages yielded very similar ΔR values of 82 ± 33 and 77 ± 32 yr, respectively. We regard the former ΔR value as a representative and more reliable value given the uncertainty in correlation of the upper assemblage with the 1703 earthquake. This result is consistent with previously reported ΔR values for the Pacific coast of south-central Japan and areas around the Sea of Japan that are influenced by warm ocean currents. Radiocarbon dating of coseismically uplifted shells can aid in estimating marine reservoir ages in the tectonically active Japan Islands.     

The Iguaraçu H5 chondrite: a fall from Paraná State,Brazil

Abstract— The Iguaraçu meteorite, a single stone of 1200 g, fell in Paraná State, Brazil in October 1977. It is classified as an H5 ordinary chondrite with olivine of composition Fa 18.7.     

The optical reflector system for the CANGAROO-II imaging atmospheric Cherenkov telescope

A new imaging atmospheric Cherenkov telescope with a light-weight reflector has been constructed. Light, robust, and durable mirror facets of containing carbon fiber reinforced plastic laminates were developed for the telescope. The reflector has a parabolic shape (f/1.1) with a 30 m² surface area, which consists of 60 spherical mirror facets. The image size of each mirror facet is 0°.08 (FWHM) on average. The attitude of each facet can be adjusted by stepping motors. After the first in situ adjustment, a point image of about 0°.14 (FWHM) over 3° field of view was obtained. The effect of gravitational load on the optical system was confirmed to be negligible at the focal plane. The telescope has been in operation with an energy threshold for γ-rays of 300 GeV since May 1999.