The composition and distribution of saturated and aromatic hydrocarbons in nearshore sediments, river sediments, and coastal peat of the Alaskan Beaufort Sea: Implications for detecting anthropogenic hydrocarbon inputs

A 3-year program, to determine spatial and temporal trends in sediment concentrations of hydrocarbons and metals from oil and gas exploration and development activities, was conducted in the US Beaufort Sea. Concentrations of saturated and aromatic hydrocarbons in sediments from the Beaufort Sea were elevated in comparison to non-polluted shelf-sediments from other regions of the US coast. Potential natural sources for hydrocarbons that were examined included riverine sediments and coastal peat. Significant quantities of fossil hydrocarbons characterize the surface sediments from the entire region. Sediment inputs from river discharges appear to account for this observation. The use of source-diagnostic ratios has allowed the differentiation of various sources in an area with high naturally-occurring hydrocarbon concentrations where effects due to oil and gas exploration and development activities may be obscured.     

Short-Period Fluctuations in Coronal Mass Ejection Activity during Solar Cycle 23

We have constructed a time series of the number of coronal mass ejections (CMEs) observed by SOHO/LASCO during solar cycle 23. Using spectral analysis techniques (the maximum entropy method and wavelet analysis) we found short-period (< one year) semiperiodic activity. Among others, we found interesting periodicities at 193, 36, 28, and 25 days. We discuss the implications of such short-period activity in terms of the emergence and escape of magnetic flux from the convection zone, through the low solar atmosphere (where these periodicities have been found for numerous activity parameters), toward interplanetary space. This analysis shows that CMEs remove the magnetic flux in a quasiperiodic process in a way similar to that of magnetic flux emergence and other solar eruptive activity.     

Real-time envelope cross-correlation detector: application to induced seismicity in the Insheim and Landau deep geothermal reservoirs

We develop and test a real-time envelope cross-correlation detector for use in seismic response plans to mitigate hazard of induced seismicity. The incoming seismological data are cross-correlated in real-time with a set of previously recorded master events. For robustness against small changes in the earthquake source locations or in the focal mechanisms we cross-correlate the envelopes of the seismograms rather than the seismograms themselves. Two sequenced detection conditions are implemented: After passing a single trace cross-correlation condition, a network cross-correlation is calculated taking amplitude ratios between stations into account. Besides detecting the earthquake and assigning it to the respective reservoir, real-time magnitudes are important for seismic response plans. We estimate the magnitudes of induced microseismicity using the relative amplitudes between master event and detected event. The real-time detector is implemented as a SeisComP3 module. We carry out offline and online performance tests using seismic monitoring data of the Insheim and Landau geothermal power plants (Upper Rhine Graben, Germany), also including blasts from a nearby quarry. The comparison of the automatic real-time catalogue with a manually processed catalogue shows, that with the implemented parameters events are always correctly assigned to the respective reservoir (4 km distance between reservoirs) or the quarry (8 km and 10 km distance, respectively, from the reservoirs). The real-time catalogue achieves a magnitude of completeness around 0.0. Four per cent of the events assigned to the Insheim reservoir and zero per cent of the Landau events are misdetections. All wrong detections are local tectonic events, whereas none are caused by seismic noise.     

Interactive Visualization to Advance Earthquake Simulation

The geological sciences are challenged to manage and interpret increasing volumes of data as observations and simulations increase in size and complexity. For example, simulations of earthquake-related processes typically generate complex, time-varying data sets in two or more dimensions. To facilitate interpretation and analysis of these data sets, evaluate the underlying models, and to drive future calculations, we have developed methods of interactive visualization with a special focus on using immersive virtual reality (VR) environments to interact with models of Earth’s surface and interior. Virtual mapping tools allow virtual “field studies” in inaccessible regions. Interactive tools allow us to manipulate shapes in order to construct models of geological features for geodynamic models, while feature extraction tools support quantitative measurement of structures that emerge from numerical simulation or field observations, thereby enabling us to improve our interpretation of the dynamical processes that drive earthquakes. VR has traditionally been used primarily as a presentation tool, albeit with active navigation through data. Reaping the full intellectual benefits of immersive VR as a tool for scientific analysis requires building on the method’s strengths, that is, using both 3D perception and interaction with observed or simulated data. This approach also takes advantage of the specialized skills of geological scientists who are trained to interpret, the often limited, geological and geophysical data available from field observations.     

Analytic models for orogenic collapse

The temporal and spatial distribution of the aftershock sequences of the Ruwenzori (February 5, 1994, Mb (5.8)), Masisi (April 29, 1995, Mb (5.1)) and Kalehe (October 24, 2002, Mb (5.9)) earthquakes have been studied. It has been found that most of the aftershocks of the Ruwenzori earthquake are located on the eastern flank of the main escarpment and those of the Masisi earthquake are confined to the northwest of Lake Kivu margin where earthquake occurrence of swarm-type was normally observed. The Kalehe earthquake occurred in the central part of Lake Kivu and it was the largest earthquake observed in the Lake Kivu basin since 1900. The rate of decrease in aftershock activity with the time has shown that the p-value for Ruwenzori and Masisi earthquake equals 0.6, somehow smaller than that found in other geotectonic zones where p is close to 1. The p-value of the Kalehe earthquake is a normal value equal to 1.From an area delimited by spatial distribution of aftershocks, the linear dimension of the fault was estimated. The fault area determined in this study correlates well with those of previous studies which occurred in the Western Rift Valley of Africa including the Tanganyika and Upemba Rift.     

Interplanetary medium condition effects in the South Atlantic Magnetic Anomaly: A case study

One way to investigate the magnetosphere–ionosphere coupling is through the simultaneous observation of different parameters measured at different locations of the geospace environment and try to determine some relationships among them. The main objective of this work is to examine how the solar energetic particles and the interplanetary medium conditions may affect the space and time configuration of the ring current at low-latitudes and also to get a better understanding on how these particles interfere with the lower ionosphere in the South Atlantic Magnetic Anomaly region (SAMA). To accomplish this, the cosmic noise absorption (CNA) and the horizontal component of the Earth's magnetic field data measured from sites located in the SAMA region were compared with the proton and electron fluxes, interplanetary medium conditions (solar wind and the north–south component of the interplanetary magnetic field measured on board satellites), the SYM-H index and magnetometer data from Kakioka (KAK-Japan), located significantly outside the SAMA region. The time series analyzed correspond to the geomagnetic disturbance that occurred on August 25–30, 1998. The analysis was performed by implementing wavelet techniques, with particular attention to singularities detection, which highlights the presence of transient signals. The results are discussed in terms of the first three wavelet decomposition levels of the parameters. The magnitude of wavelet coefficients of the solar wind and proton flux at the two energy ranges analyzed is timely well correlated, indicating that these two signals are energetically linked. The larger wavelet coefficient amplitude of KAK and VSS magnetograms shows time delays that are compatible with an asymmetric configuration of the ring current, considering that at the storm time, VSS was at the dawn sector of the magnetosphere and KAK at the dusk side. The wavelet analysis of CNA signals reveals that the signal may be sensitive to the ionization produced by energetic electrons and protons as well. The time delays observed in wavelet coefficients may give an indication of the different accelerating process to which the particles are submitted when traveling along the magnetic field lines, from higher to lower latitudes, and the likely contribution of these particles to the ionization measured as an absorption of the cosmic noise in the lower ionosphere.     

Trace metals in sediments from the inner continental shelf of the western Beaufort Sea

Increased development and changing climate have enhanced global interest in the Arctic Ocean and adjacent seas. Using a large, 3-yr data base, we have determined the distribution of trace metals in sediments from the inner shelf of the western Beaufort Sea. Metal concentrations in these sediments reflect pristine conditions, consistent with those for most coastal areas in the Arctic and with predictions based on average continental crust. Geographic variations in metal values are primarily related to sediment grainsize distribution. However, grain-size patterns are a complex function of several variables including source areas, ice and water movement, as well as physical and chemical weathering. Future identification of any metal contamination in Beaufort Sea sediments will be simplified by understanding the predictable natural patterns.     

Surface water quality and sediment geochemistry in the Gualaxo do Norte basin,eastern Quadrilátero Ferrífero,Minas Gerais,Brazil

This paper describes the geochemistry of water and sediment samples downstream from two iron mines in the Gualaxo do Norte River basin, north of Mariana city, Minas Gerais state, Brazil. Electric conductivity, total dissolved solids, pH, E_h, Na, K, Ca, Mg and trace elements (Fe, Mn, Al, Cd, Ni, Cr, Zn, As, Pb, Co, Sb, Cu, Mo, Rb, Sr, Ti, V, Y, Zr and Ba) have been analysed in water and sediments. The observed Na anomalies are mainly associated with the iron mine processing plants. Enriched concentrations of iron and manganese were only observed in rudimentary gold exploitation areas (prospectors) and where supergenic alteration of the banded iron formation has occurred. Iron and manganese background values are in some places higher than the limits established by Brazilian legislation. Mn, As, Sb and Ba anomalies have been observed in sediments. Their main source is associated with the sulphide-rich mineral deposits in the spring of the Gualaxo do Norte River and not directly related to the present iron exploitation in the region. Background values are proposed for the studied region.     

Eclogite facies relics and a multistage breakdown in metabasites of the KTB pilot hole,NE Bavaria: implications for the Variscan tectonometamorphic evolution of the NW Bohemian Massif

Complex reaction textures in coronitic metagabbros and retrograded eclogites of the KTB pilot and an adjacent drilling provide evidence for a multistage metamorphic history in the Variscan basement of the NW Bohemian Massif. The eclogites show complete metamorphic recrystallization leaving no textural or mineral relics of their igneous precursors. In contrast, textural relics of the igneous protolith are still preserved in the metagabbros where the metamorphic overprint under high pressure conditions achieved only partial replacement of the initial assemblage plagioclase + augite + amphibole (+olivine or orthopyroxene?) + ilmenite to form the eclogite facies assemblage garnet + omphacite + kyanite + zoisite + quartz+rutile. The garnets in the metagabbros occur in the typical ‘necklace’ fashion at the borders between the original plagioclase and mafic phase domains. In the same rocks, omphacite formed by a topotactic reaction mechanism replacing igneous augite as well as in smaller grains at the margins of the texturally igneous clinopyroxene where it occurs without fixed orientation with respect to the relict phase. Both eclogites and metagabbros show a partial breakdown under high pressure granulite (transitional to high pressure amphibolite) facies conditions during which omphacite broke down to vermicular symplectites of diopside + plagioclase. A later pervasive medium pressure metamorphism under amphibolite facies conditions led to the development of assemblages dominated by hornblende + plagioclase+titanite: phases prevailing in the overwhelming majority of the surrounding metabasites. Subsequent vein-associated retrogression produced minerals typical of the greenschist to zeolite facies. All metamorphic stages may be represented in a single thin section but although the overall reaction sequence is apparent, the obvious disequilibrium in the rocks makes the use of conventional geothermobarometry difficult. However, calculations made by assuming an approach to domainal equilibrium show that both the eclogite facies and early breakdown occurred above 10 kb. As the metamorphic unit hosting these particular metabasites is generally characterized by pressures below 10 kb these results have important implications for understanding the tectonometamorphic evolution of the region. The relationship between the studied rocks and other units in the NW Bohemian Massif exhibiting a multistage metamorphic evolution is discussed and possible tectonic models evaluated.