Effects of water use on arsenic release to well water in a confined aquifer

Field-based experiments were designed to investigate the release of naturally occurring, low to moderate (< 50 microg/L) arsenic concentrations to well water in a confined sandstone aquifer in northeastern Wisconsin. Geologic, geochemical, and hydrogeologic data collected from a 115 m2 site demonstrate that arsenic concentrations in ground water are heterogeneous at the scale of the field site, and that the distribution of arsenic in ground water correlates to solid-phase arsenic in aquifer materials. Arsenic concentrations in a test well varied from 1.8 to 22 microg/L during experiments conducted under no, low, and high pumping rates. The quality of ground water consumed from wells under typical domestic water use patterns differs from that of ground water in the aquifer because of reactions that occur within the well. Redox conditions in the well can change rapidly in response to ground water withdrawals. The well borehole is an environment conducive to microbiological growth, and biogeochemical reactions also affect borehole chemistry. While oxidation of sulfide minerals appears to release arsenic to ground water in zones within the aquifer, reduction of arsenic-bearing iron (hydr)oxides is a likely mechanism of arsenic release to water having a long residence time in the well borehole.     

Effects of changing climate on ice cover in three morphometrically different lakes

A one‐dimensional hydrodynamic lake model (DYRESM‐WQ‐I) is employed to simulate ice cover and water temperatures over the period 1911–2014. The effects of climate changes (air temperature and wind speed) on ice cover (ice‐on, ice‐off, ice cover duration, and maximum ice thickness) are modeled and compared for the three different morphometry lakes: Fish Lake, Lake Wingra, and Lake Mendota, located in Madison, Wisconsin, USA. It is found that the ice cover period has decreased due to later ice‐on dates and earlier ice‐off dates, and the annual maximum ice cover thickness has decreased for the three lakes during the last century. Based upon simulated perturbations of daily mean air temperatures across the range of ?10°C to +10°C of historical values, Fish Lake has the most occurrences of no ice cover and Lake Wingra still remains ice covered under extreme conditions (+10°C). Overall, shallower lakes with larger surface areas appear more resilient to ice cover changes caused by climate changes.     

Trophic Resource Overlap Between Small Elasmobranchs and Sympatric Teleosts in Mid-Atlantic Bight Nearshore Habitats

Small, abundant elasmobranchs use shallow marine areas (<20 m depth) of the US Middle Atlantic coast as nurseries and adult foraging habitat, an area also used by a diverse assemblage of economically important juvenile and adult teleost species. Specimens of three small elasmobranch species (smooth dogfish Mustelus canis, clearnose skate Raja eglanteria, and bullnose ray Myliobatis freminvillii) were collected in August 2007 and 2008 from a study area of ∼150 km², extending 22 km south from Ocean City, Maryland, USA (38° 19′ N) and offshore from 5- to 20-m depth. Stomach contents indicated that fish were part of the diets of smooth dogfish and clearnose skate at a level comparable with sympatric piscivorous teleosts. However, stable isotope data suggest that piscivory is likely an opportunistic foraging behavior in this habitat. Studied elasmobranchs were secondary-tertiary consumers with diets composed primarily of decapod crustaceans, fish, and mollusks. There was significant overlap in diet composition, spatial distribution, and diel stomach fullness patterns between clearnose skate, southern kingfish Menticirrhus americanus (teleost) and, to a lesser extent, smooth dogfish. Despite this evidence for piscivory, their relatively low densities suggest that predation by these elasmobranchs is unlikely to affect teleost populations in shallow coastal ocean habitats. If shared prey were to become scarce, then competitive interactions are possible.     

合浦珠母贝代谢产物对异枝麒麟菜生长的促进作用

于１９９５年４月间在海南省三亚市、陵水县分别采集合浦珠母贝和异枝麒麟菜并进行混养实验，测定贝释放的三氮（ＮＨ４－Ｎ，ＮＯ３－Ｎ，ＮＯ２－Ｎ）以及藻类对贝释放的三氮的吸收及其生长，在期探讨合浦珠母贝代谢产物促进异枝麒麟菜生长的原因。结果表明，贝释放物中以ＮＨ４－Ｎ为主，ＮＯ３－Ｎ次之，ＮＯ２－Ｎ含量较少；藻对三氮的吸收 依此顺序递减。实验组藻体的生长速率明显高于对照组的，在模拟实验组中，通过加入无机     

Effects of reservoir stratification and watershed hydrology on manganese and iron in a dam‐regulated river

The presence of metals, including manganese (Mn) and iron (Fe), adversely impacts water quality. In seasonally stratified reservoirs, Mn and Fe can accumulate in the water column due to reducing conditions in sediments and be released to downstream rivers through dam discharge. In addition to reservoir stratification influences, the release of metals downstream is influenced by hydrologic conditions in the river. We examined the seasonal and spatial variability of Mn and Fe concentrations in a eutrophic, hydropower reservoir and the downstream river over a two‐year period. Overall, we found that reservoir stratification was a strong predictor of tailrace Mn and Fe concentrations but that tailrace Fe concentrations were also influenced by dam discharge. Downgradient of the tailrace, river discharge and suspended sediment were the dominant predictors of both Mn and Fe concentrations. Using our data, we develop a conceptual model of seasonal and hydrologic drivers of metal concentrations. The model can be modified for other systems aiding drinking water utilities and other water users in forecasting under what seasonal and hydrologic conditions that Mn and Fe concentrations in river systems are likely to be elevated.     

Groundwater flood of a river terrace in southwest Wisconsin,USA

Intense rainstorms in 2008 resulted in wide-spread flooding across the Midwestern United States. In Wisconsin, floodwater inundated a 17.7-km² area on an outwash terrace, 7.5 m above the mapped floodplain of the Wisconsin River. Surface-water runoff initiated the flooding, but results of field investigation and modeling indicate that rapid water-table rise and groundwater inundation caused the long-lasting flood far from the riparian floodplain. Local geologic and geomorphic features of the landscape lead to spatial variability in runoff and recharge to the unconfined sand and gravel aquifer, and regional hydrogeologic conditions increased groundwater discharge from the deep bedrock aquifer to the river valley. Although reports of extreme cases of groundwater flooding are uncommon, this occurrence had significant economic and social costs. Local, state and federal officials required hydrologic analysis to support emergency management and long-term flood mitigation strategies. Rapid, sustained water-table rise and the resultant flooding of this high-permeability aquifer illustrate a significant aspect of groundwater system response to an extreme precipitation event. Comprehensive land-use planning should encompass the potential for water-table rise and groundwater flooding in a variety of hydrogeologic settings, as future changes in climate may impact recharge and the water-table elevation.     

The Great Barrier Reef World Heritage Marine Protected Area: valuing local perspectives in environmental protection

The Great Barrier Reef (GBR), Queensland, Australia, is one of the most recognisable coral reefs in the world. In 1981 the reef was listed on the World Heritage List, to be preserved as an environmental asset of global significance for all people in perpetuity. The GBR is also a landmark Marine Protected Area (MPA) under the World Heritage Marine Programme. Yet management of this iconic property is not without controversy and in recent years a number of impacts, including coastal developments, increased shipping traffic and global warming, have all threatened the reef. Any breach of Australia's World Heritage obligation to protect and conserve the property may yet result in the GBR being placed on the World Heritage List in Danger. In light of the persistent controversy surrounding GBR management, this paper gives voice to the perspectives and values of stakeholders located in and around one site of controversy, Gladstone Harbour, in the southern section of the GBR World Heritage Area. We present the views of users directly exposed to the controversial port expansion development at Gladstone Harbour in the southern GBR to shed light on the importance of community perspectives in marine park management. Our findings show that local views act to reinforce the global environmental protection narrative which underpins the World Heritage (WH) system. In this study local and global values collide and, we argue, that overlooking the perspectives of users has potential deleterious consequences for WH marine site management.     

Arsenic Geochemistry and Hydrostratigraphy in Midwestern U.S. Glacial Deposits

Arsenic concentrations exceeding the U.S. EPA's 10 μg/L standard are common in glacial aquifers in the midwestern United States. Previous studies have indicated that arsenic occurs naturally in these aquifers in association with metal-(hydr)oxides and is released to groundwater under reducing conditions generated by microbial oxidation of organic matter. Despite this delineation of the arsenic source and mechanism of arsenic mobilization, identification of arsenic-impacted aquifers is hindered by the heterogeneous and discontinuous nature of glacial sediments. In much of the Midwest, the hydrostratigraphy of glacial deposits is not sufficiently characterized to predict where elevated arsenic concentrations are likely to occur. This case study from southeast Wisconsin presents a detailed characterization of local stratigraphy, hydrostratigraphy, and geochemistry of the Pleistocene glacial deposits and underlying Silurian dolomite. Analyses of a single core, water chemistry data, and well construction reports enabled identification of two aquifers separated by an organic-rich aquitard. The upper, unconfined aquifer provides potable water, whereas arsenic generally exceeds 10 μg/L in the deeper aquifer. Although coring and detailed hydrostratigraphic characterization are often considered impractical, our results demonstrate that a single core improved interpretation of the complex lithology and hydrostratigraphy. This detailed characterization of hydrostratigraphy facilitated development of well construction guidelines and lays the ground work for further studies of the complex interactions among aquifer sediments, hydrogeology, water chemistry, and microbiology that lead to elevated arsenic in groundwater.     

Arsenic release from chlorine-promoted alteration of a sulfide cement horizon: Evidence from batch studies on the St. Peter Sandstone,Wisconsin, USA

Elevated As concentrations have been measured in wells in the St. Peter Sandstone aquifer of eastern Wisconsin, USA. The primary source is As-bearing sulfide minerals (pyrite and marcasite) within the aquifer. There is concern that well disinfection by chlorination may facilitate As release to groundwater by increasing the rate and extent of sulfide oxidation. The objective of this study was to examine the abiotic processes that mobilize As from the aquifer solids during controlled exposure to chlorinated solutions. Thin sections made from sulfidic aquifer material were characterized by quantitative electron probe micro-analysis before and after 24 h exposure to solutions of different Cl₂ concentrations. Batch experiments using crushed aquifer solids were also conducted to examine changes in solution chemistry over 24 h. Results of the combined experiments indicate that Cl₂ addition affects As release and uptake in two ways. First, Cl₂ increases oxidation of sulfide minerals, releasing more As from the mineral structure. Chlorine addition also increases the rate of Fe(II) oxidation and subsequent hydrous ferric oxide (HFO) precipitation, allowing for increased uptake of As onto the mineral surface. Although HFOs can act as sinks for As, they can release As if biogeochemical conditions (e.g. redox, pH) change. These results have implications not only for disinfection of drinking water wells in the study area, but also suggest that introduction of oxidants may adversely affect water quality during aquifer storage and recovery programs in aquifers containing As-bearing minerals.