Partitioning of polycyclic aromatic hydrocarbons between water and particles compared to bioaccumulation in mussels: a harbour case

Water and particles from three sites located in Halifax Harbour, near and further away from combined municipal sewage effluents (CMSE) were analysed for parental and alkylated polycyclic aromatic hydrocarbons (par and alkPAH). Bioavailability of PAH was compared for inter-tidal mussels collected at the same sites in April and November. The PAH fingerprint determined over 9 sampling times covering a period of 19 months differed more between phases (water and particles) and seasons, than between sites. In the spring, more alkPAH associated with diesel and gasoline were detected in the soluble phase, along with more bioaccumulation of alkPAH in inter-tidal mussels. A broader number of parPAH were detected in mussels collected in the fall. The mean sum of dissolved alkPAH concentrations was higher in water at the site closer to raw CMSE than at the other two sites and particles of that site. However, lowest bioconcentration factors (BCF) were determined in mussels of this more contaminated site. Similar biota-particle accumulation factors (BPAF) were determined for parPAH in mussels from the three sites, all lower than the BCF of alkPAH. The study indicates that sewage treatment plants will reduce the amount of parPAH especially larger than fluoranthene and pyrene from being deposited in the harbour; that alk naphthalenes and fluorenes present in water will continue to be discharged; that the disturbance of sediments can make particle-bound PAH available to mussels.     

Provenance of Conglomerate and Sandstone from Early Permian Shoushangou Formation in Xi Ujimqin, Inner Mongolia: Implications for Understanding Paleo-Asian Ocean Subduction

During the Late Carboniferous to Early Permian, a rift was formed by post-collisional extension after ocean closure or an island arc-related basin formed by Paleo-Asian Ocean (PAO) subduction in the Xi Ujimqin area. Nevertheless, the closure time of the PAO is still under debate. Thus, to identify the origin of the PAO, the geochemistry and U-Pb age of zircons were analyzed for the extra-large deep marine, polymict clastic boulders and sandstones in the Shoushangou Formation within the basin. The analyses revealed magmatic activity and tectonic evolution. The conglomerates include megaclasts of granite (298.8 ± 9.1?Ma) and granodiorite porphyry (297.1 ± 3.1?Ma), which were deposited by muddy debris flow. Results of this study demonstrated that the boulders of granitoids have the geochemistry of typical I-type granite, characterized by low Zr + Nb + Ce + Y and low Ga/Al values. The granitoid boulders were formed in island arc setting, indicating the presence of arc magmatism in the area that is composed of the Late Carboniferous to Early Permian subduction-related granitoid in southern Xi Ujimqin. Multiple diagrams for determining sedimentary provenance using major and trace elements indicate that Shoushangou sediments originated from continental island arc-related felsic rocks. Detrital zircon U-Pb age cluster of 330–280?Ma was obtained, indicating input from granite, ophiolite, Xilin Gol complex, and Carboniferous sources to the south. The basin was geographically developed behind the arc during the Early Permian period because the outcropped intrusive rocks in the Late Carboniferous to Early Permian form a volcanic arc. The comprehensive analyses of source areas suggest that Shoushangou sediments developed in a backarc basin in response to the northward subduction of the PAO. The backarc basin and intrusive rocks, in addition to previously published Late Carboniferous to Early Permian magmatic rocks of arc unit in Xilin Gol, confirm the presence of an Early Permian trench-arc-basin system in the region, represented by the Baolidao arc and Xi Ujimqin backarc basin. This study highlights the importance and potential of combined geochemical and geochronological studies of conglomerates and sandstone for reconstructing the geodynamic setting of a basin.     

EFFECTS OF THREE KINDS OF PHYSICAL PROCESSES ON TYPHOON INTENSITY*

This paper designs three quasi-geostrophic barotropic models with a radial/horizontal grid length being 2 kin,one in the polar coordinates,one on a stationary typhoon circulation condition and another on a non-stationary typhoon circulation condition in the Cartesian coordinates,to investigate the effects of azimuthal and radial linear advections,and nonlinear advection on the inward propagation of mesoscale vorticity and the changes of typhoon intensity.Results show that the azimuthal linear advection may result in the formation of spiral vorticity bands;the radial linear advection in a certain parameter set is able to transfer vorticity inwards,leading to a slight enhancement of typhoon;the nonlinear advection of perturbation vorticity on a stationary typhoon circulation condition may transfer more vorticities inwards,thus resulting in a distinct enhancement of typhoon;and the nonlinear advection on a non-stationary typhoon circulation condition possesses duality,i.e.on the one hand,the advection increases the vorticity of inward propagation,thus favorable to the intensification of typhoon,and on the other hand,in the inward propagation process of vorticity the originally concentric and axisymmetric structure of typhoon basic flow is damaged,and a complex flow pattern forms,which in turn tends to weaken the circulation of typhoon.At last the paper discusses the possible applications of those results in typhoon intensity prediction.     

Numerical analysis of landslide-generated debris flow on July 3, 2021 in Izu Mountain area,Shizuoka County,Japan

With the increasing of extreme rainfall frequency, landslides accompanied by mudslides often lead to serious casualties and property damage. On 3rd July 2021, a debris flow occurred in Izu Mountain area, Shizuoka County, Japan, and then resulted in 26 deaths and 131 houses destroyed, where houses were mainly built along the banks of the creek. In order to analyse the landslide state and distribution, a two-dimensional debris flow dynamic model(Massflow) was selected to simulate the process of th...     

Effect of Zn2+-Cu2+ combined heavy metal on mechanical properties and microstructure of clayey soil

The strength deterioration mechanism of soil polluted by heavy metals plays a crucial role in the research of mine site pollution. In this study, an unconfined compressive strength(UCS) test, a p H test, a scanning electron microscopy(SEM) test, a low filed nuclear magnetic resonance(NMR) test, and an X-ray diffraction(XRD) test were conducted on Zn²⁺,Cu²⁺ and the combination of Zn²⁺ and Cu²⁺ polluted soil to investigate the strength deterioration mech...     

Titanium Isotope Analysis of Igneous Reference Materials using a Double-spike MC-ICP-MS Method

Ti separation was achieved by ion-exchange chromatography using Bio-Rad AG 1-X8 anion-exchange and DGA resins. For high-Fe/Ti and high-Mg/Ti igneous samples, a three-column procedure was required, whereas a two-column procedure was used for low-Fe/Ti and low-Mg/Ti igneous samples. The Ti isotopes were analysed by MC-ICP-MS, and instrumental mass bias was corrected using a 47Ti-49Ti double-spike technique. The 47Ti-49Ti double-spike and SRM 3162a were calibrated using SRM 979-Cr, certificated value 53Cr/52Crtrue = 0.11339. Isobaric interference was evaluated by analysing Alfa-Ti doped with Na, Mg, Ca, and Mo, and results indicate that high concentrations of Na and Mg have no significant effect on Ti isotope analyses; however, Ca and Mo interferences lead to erroneous δ49/47Ti values when Ca/Ti and Mo/Ti ratios exceed 0.01 and 0.1, respectively. Titanium isotopic compositions were determined for 12 igneous reference materials, BCR-2, BHVO-2, GBW07105, AGV-1, AGV-2, W-2, GBW07123, GBW07126, GBW07127, GBW07101, JP-1, and DTS-2b. Samples yield δ49/47Ti (‰) of ?0.035 ± 0.022, ?0.038 ± 0.031, 0.031 ± 0.022, 0.059 ± 0.038, 0.044 ± 0.037, 0.000 ± 0.015, 0.154 ± 0.044, ?0.044 ± 0.018, 0.010 ± 0.022, 0.064 ± 0.043, 0.169 ± 0.034, and ?0.047 ± 0.025 (relative to OL-Ti, ±2SD), respectively; of which isotopic compositions of DTS-2b, JP-1, GBW07101, GBW07105, GBW07123, GBW07126, and GBW07127 are reported for the first time. Standard Alfa-Ti was analysed repeatedly over a ten-month period, indicating a reproducibility of ±0.047 (2SD) for δ49/47Ti, similar to the precisions obtained for geochemical reference materials.     

The Existence and Significance of Two Kinds of Effective Reservoirs in Deep Water Area of the Western Qaidam Basin

<正>Objective Deep-water deposit has become one of the greatest potential and economic areas for petroleum exploration. In the western Qaidam Basin, the deep-water sedimentary area account for nearly 2/3 of the basin area, but the related reports is less. Scholars generally believed that the salt water medium can inhibit the extension of the sand(Qian et al., 1984).     

Geochemical Characteristics and Tectonic Significance of the Kecun Dyke Swarm in the Jiuhuashan Geopark

Please refer to the attachment(s) for more details.     

Research on Formation Mechanisms of Hot Dry Rock Resources in China

As an important geothermal resource, hot dry rock(HDR) reserves have been studied in many countries. HDR resources in China have huge capacity and have become one of the most important resources for the potential replacement of fossil fuels. However, HDR resources are difficult to develop and utilise. Technologies for use with HDR, such as high–temperature drilling, reservoir characterisation, reservoir fracturing, microseismic monitoring and high–temperature power stations, originate from the field of oil and drilling. Addressing how to take advantage of these developed technologies is a key factor in the development of HDR reserves. Based on the thermal crustal structure in China, HDR resources can be divided into four types: high radioactive heat production, sedimentary basin, modern volcano and the inner–plate active tectonic belt. The prospective regions of HDR resources are located in South Tibet, West Yunnan, the southeast coast of China, Bohai Rim, Songliao Basin and Guanzhong Basin. The related essential technologies are relatively mature, and the prospect of HDR power generation is promising. Therefore, analysing the formation mechanisms of HDR resources and promoting the transformation of technological achievements, large–scale development and the utilisation of HDR resources can be achieved in China.     

Fluid Inclusion and Stable Isotope Geochemistry of the Shangxu Gold Deposit, Northern Tibet

正Objective The Shangxu gold deposit is located in the south of the middle Bangong-Nujiang suture zone in northern Tibet.The origin of this deposit as an orogenic gold deposit is debatable.The study of the Shangxu deposit has a profound implication on gold exploration in the BangongNujiang metallogenic belt and can also improve our understanding of gold mineralization in northern Tibet.