Zusammenfassung Mikroskopische Anschliffe feinkörniger Aufbereitungsprodukte können nur dann quantitativ ausgewertet werden, wenn ihre Schliffqualität so hoch ist, daß auch feinste Partien sicher zu bestimmen sind. Daneben muß gewährleistet sein, daß die an der Schliffoberfläche erfaßten Körner die tatsächliche Verteilung der Mineralien der Probe repräsentieren. Diese Forderung kann nur durch zweckentsprechende Präparation, die dem eigentlichen Schleif- und Polierprozeß vorausgeht, erfüllt werden. Als günstigste Lösung erscheint es, das Korngemisch exakt als Einkornschicht zu präparieren und anschließend wie Stückproben anzuschleifen. Die Schliffe können dann nach den gleichen statistischen Gesetzmäßigkeiten ausgewertet werden, wie sie bei praktisch zweidimensionalen Dünnschliffen oder bei Streupräparaten nichtopaker Korngemische vorliegen.
Quantitative examination of fine-grained ore dressing products depends on good quality of the sections and on whether very small particles and areas of grains can be determined. Besides, it must absolutely be guaranteed that the grains at the section surface represent the actual distribution of the minerals in the sample. This condition can only be realized by suitable grain mounting prior to grinding and polishing. The best method for this purpose appears to be the preparation of a mono-grain layer. The polished sections can then be examined according to the same statistical laws as two-dimensional thin sections or immersion-liquid slides of non-opaque mixtures of grains.
Mitteilung Nr. 141 aus dem Forschungsinstitut für Aufbereitung der Deutschen Akademie der Wissenschaften zu Berlin, Freiberg (Sachsen). Direktor: Prof. Dr.-Ing. habil. H. Kirchberg. 相似文献
An analytical artefact is reported here related to differences in instrumental mass fractionation between NIST SRM glasses and natural geological glasses during SIMS boron isotope determinations. The data presented demonstrated an average 3.4‰ difference between the NIST glasses and natural basaltic to rhyolitic glasses mainly in terms of their sputtering-induced fractionation of boron isotopes. As no matrix effect was found among basaltic to rhyolitic glasses, instrumental mass fractionation of most natural glass samples can be corrected by using appropriate glass reference materials. In order to confirm the existence of the compositionally induced variations in boron SIMS instrumental mass bias, the observed offset in SIMS instrumental mass bias has been independently reproduced in two laboratories and the phenomenon has been found to be stable over a period of more than one year. This study highlights the need for a close match between the chemical composition of the reference material and the samples being investigated. 相似文献
The solar irradiance modulation due to active regions during 1980 has been investigated in detail. Specifically, we estimate the uncertainties caused by ground-based data used as input in the modeling effort, and by our currently incomplete knowledge of the proper parameters that describe the angular variation of sunspot and facular contrasts. We conclude that the most significant uncertainties are due to errors in area measurements and, possibly, varying spot and facular brightness. A standard model for later use is derived by a best-fit technique of the currently available ACRIM irradiance data and the predictions of our models with appropriately varied parameters. Finally, we compute the expected irradiance for the entire year of 1980.NRC Senior Research Associate on leave from the Joint Institute for Laboratory Astrophysics and the Astro-Geophysics Department, University of Colorado at Boulder, Colo., U.S.A. 相似文献
Extracellular polymeric substances (EPS) are continuously produced by bacteria during their growth and metabolism. In soils, EPS are bound to cell surfaces, associated with biofilms, or released into solution where they can react with other solutes and soil particle surfaces. If such reaction results in a decrease in EPS bioaccessibility, it may contribute to stabilization of microbial-derived organic carbon (OC) in soil. Here we examined: (i) the chemical fractionation of EPS produced by a common Gram positive soil bacterial strain (Bacillus subtilis) during reaction with dissolved and colloidal Al species and (ii) the resulting stabilization against desorption and microbial decay by the respective coprecipitation (with dissolved Al) and adsorption (with Al(OH)3(am)) processes. Coprecipitates and adsorption complexes obtained following EPS-Al reaction as a function of pH and ionic strength were characterized by Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). The stability of adsorbed and coprecipitated EPS against biodegradation was assessed by mineralization experiments for 1100 h. Up to 60% of the initial 100 mg/L EPS-C was adsorbed at the highest initial molar Al:C ratio (1.86), but this still resulted only in a moderate OC mass fraction in the solid phase (17 mg/g Al(OH)3(am)). In contrast, while coprecipitation by Al was less efficient in removing EPS from solution (maximum values of 33% at molar Al:C ratios of 0.1-0.2), the OC mass fraction in the solid product was substantially larger than that in adsorption complexes. Organic P compounds were preferentially bound during both adsorption and coprecipitation. Data are consistent with strong ligand exchange of EPS phosphoryl groups during adsorption to Al(OH)3(am), whereas for coprecipitation weaker sorption mechanisms are also involved. X-ray photoelectron analyses indicate an intimate mixing of EPS with Al in the coprecipitates, which is not observed in the case of EPS adsorption complexes. The incubation experiments showed that both processes result in overall stabilization of EPS against microbial decay. Stabilization of adsorbed or coprecipitated EPS increased with increasing molar Al:C ratio and biodegradation was correlated with EPS desorption, implying that detachment of EPS from surface sites is a prerequisite for microbial utilization. Results indicate that the mechanisms transferring EPS into Al-organic associations may significantly affect the composition and stability of biomolecular C, N and P in soils. The observed efficient stabilization of EPS might explain the strong microbial character of organic matter in subsoils. 相似文献
The Totalp-Platta-Malenco ophiolites in the Eastern Central Alps offer a unique opportunity to study the behaviour of Li, Be and B in ultramafic rocks in response to serpentinization and to progressive Alpine metamorphism. These units represent the remnants of a former ocean-continent transition that was intensely serpentinized during exposure on the Jurassic seafloor of the Ligurian Tethys. From north to the south, three isograd reactions (lizardite⇒antigorite+brucite;lizardite+talc⇒antigorite;lizardite+tremolite⇒antigorite+diopside) have been used to quantify the evolution of the light element content of metamorphic minerals. We determined the Li, Be and B concentrations in major silicate minerals from the ultramafic bodies of Totalp, Platta and Malenco by secondary ion mass spectrometry. Mantle minerals have Be concentrations (e.g. <0.001-0.009 μg/g in olivine) similar to the metamorphic minerals that replace them (e.g. <0.001-0.016 μg/g in serpentine). The mantle signature of Be is thus neither erased during seafloor alteration nor by progressive metamorphism from prehnite-pumpellyite to epidote-amphibolite facies. In contrast, the Li and B inventories of metamorphic minerals are related to the lizardite-to-antigorite transition. Both elements display higher concentrations in the low-temperature serpentine polymorph lizardite (max. 156 μg/g Li, max. 318 μg/g B) than in antigorite (max. 0.11 μg/g Li, max. 12 μg/g B). Calculated average B/Li ratios for lizardite (∼1395) and antigorite (∼115) indicate that Li fractionates from B during the lizardite-to-antigorite transition during prograde metamorphism in ultramafic rocks. In subduction zones, this signature is likely to be recorded in the B-rich nature of forearc fluids.Relative to oceanic mantle the Be content of mantle clinopyroxene is much higher, but similar to Be values from mantle xenoliths and subduction-related peridotite massifs. These data support previous hypothesis that the mantle rocks from the Eastern Central Alps have a subcontinental origin. We conclude that Be behaves conservatively during subduction metamorphism of ultramafic rocks, at least at low-temperature, and thus retains the fingerprint of ancient subduction-related igneous events in mantle peridotites. 相似文献
Significant short-term fluctuations are characteristic of geological history since Precambrian times. Only the younger Quaternary climatic fluctuations are known in more detail as a result of a high grade time resolution. Climatic change can also be postulated with respect to older, cold periods during which polar inland ice sheets developed. From a discussion of endogene and exogene interpretations it is shown that global climatic changes, and the sea-level changes induced by them, as well as changes in the position and extent of climatic zones throughout the world provide a control mechanism for sedimentation which is consistent with cyclic sedimentation in Late Palaeozoic times, and also if the basin subsides non-cyclically. The model allows an explanation of the development of the Permo-Carboniferous sedimentary cycles without numerous short-term vertical oscillations of the earth's crust. In reality, exogene and endogene controls on sedimentation act together in great variety of combinations. 相似文献
Salt-loaded effluents were introduced into the river Wipper during the mining period for almost a century. Beginning with the year 1990, the waste water load was strongly reduced due to the termination of the potash industry. Prior to 1990, monthly means of the chloride concentrations at times exceeded 6,000 mg l−1 in the strongly polluted sections. Maximum concentrations reached twice these values. Up to 1998, mean annual chloride concentrations decreased to values below 2,000 mg l−1. This led to more balanced fluctuations in salinity which had been pronounced before, depending on discharge and short-term changes in production. Similarly, the physiologically adverse ion conditions improved due to decrasing potassium and increasing calcium proportions.
In 1963/64, 1986 and 1998, samples of epilithic, epiphytic and epipsammic diatoms were taken at locations of different salinities along the river and examined for the effects of the salinization on the structure of the diatom assemblages. These structures changed in dependence on salinity. Increasing salt concentrations coincided with decreasing oligohalophilic and increasing mesohalophilic and polyhalophilic species numbers. Above a chloride concentration of about 3,000 mg l−1, the proportion of the latter exceed that of the former (halobion index > 50). Corresponding to different conditions of salinization along the river, characteristic diatom assemblages occur differring from each other and which are specific for the river section. Spring and autumn aspects of the diatom assemblages show also salt-dependent differences. The assemblages found in 1998 after decrease of salinization have changed markedly in comparison to those from 1963/64 and 1986. Halobiontic species predominating formerly occurred only occasionally or not at all. They were replaced by oligohalobic-indifferent forms.
An ecological assessment of the changes was performed based on the halobion index calculated from all the samples. For the strongly salinized section of the river Wipper, a shift from -mesohalobic/polyhalobic conditions in 1963/64 and 1986 to -oligohalobic/β-mesohalobic conditions in 1998 was found. However, constant -oligohalobic conditions are still not given. With regard to the transition from -oligohalobic (limnetic) to β-mesohalobic (brackish) conditions, a maximum chloride concentration of 600 mg l−1 was found. To guarantee -oligohalobic conditions, a maximum chloride concentration of 400 mg l−1 should not be exceeded. 相似文献
Strontium-isotopic ratios of dated corals have been obtained from submerged reefs formed during Quaternary glacial periods off the Hawaiian islands. These data, combined with data from deep-sea sediments, tightly constrain the secular variation of marine 87Sr/86Sr for the past 800,000 yr. Although long-term trends are apparent, no significant (>0.02‰), rapid (<100,000 yr) excursions in 87Sr/86Sr were resolved nor did we observe any samples with 87Sr/86Sr greater than that of modern seawater. Strontium in mollusks from elevated marine terraces formed during interglacial periods on the southern California coast show resolvable and consistent variations in 87Sr/86Sr which, when compared to the trend of Quaternary marine 87Sr/86Sr, can be used to infer uplift rates and define approximate ages for the higher terraces. The Sr-isotope age estimates indicate that uplift rates vary among crustal blocks and were not necessarily constant with time. No contrast in Sr-isotopic ratios between similar-age Hawaiian and California fossils was observed, confirming that any change in marine 87Sr/86Sr from glacial to interglacial periods must be small. A realistic appraisal of the potential of Sr-isotope stratigraphy for chronometric applications in the Quaternary suggests that the technique will be limited to relatively coarse distinctions in age. 相似文献
This review paper intends to summarize the state of the art in loess research at the first international “Loess-fest’99” conference and to outline progress in loess research during the past decade. The focus is on loess as a terrestrial archive of climatic and environmental change during the Quaternary. The review highlights remarkable new results from regional investigations into European loess, as well as the emergence of new methods and refinements of established techniques, focussing on stratigraphy, dating and palaeoenvironment. It is concluded that loess research during the past decade not only has developed rapidly to take an outstanding place in Quaternary sciences, but also promises exciting perspectives for the next decade, in particular when combined approaches are applied to benefit from the now comprehensive pool of established and new methods. 相似文献