Geochemical characteristics of mineral air particles emitted inside a clay atomisation plant which introduces waste recycling processes

The objective of this work is to assess the concentrations of three factions of air particles (settable particles, TSP and PM10) and the levels of several toxic elements in a clay atomisation industry through aerosol sampling at several points inside an industrial plant. Mechanical activities, which produce diffuse emissions, are the main process of discharge of particles in both indoor and outdoor workplace environments in the atomisation plant. The levels of As, Cd, Pb, Zn, Ba and Ni increase in the zones with higher concentrations of particles and lower ventilation. The concentrations of As and F are not influenced by the recycling processes. The levels of Cd and Pb do not show great enrichment in air particles collected inside the atomisation plant although the content of both elements is associated with ceramic muck recycling. Finally, the content of B in waste water is mainly transferred in gaseous phase to the atmosphere during the process of drying by atomisation.     

土地利用/土地覆被变化遥感监测研究

根据1990年和1999年两期TM/ETM 遥感数据,运用遥感分类中的监督分类方法,全面分析乌鲁木齐市的土地利用的数量变化特征和空间变化特征,阐明了区域土地利用变化的区域特点。     

Peat extraction, conservation and the rural economy in Northern Ireland

Northern Ireland has a tradition of peat cutting; 78 per cent by area of remaining lowland bogs and 46 per cent of blanket bogs have been cut in the past. Since the early 1980s, machine peat extraction for fuel and horticulture has increased, against a background of changing economic support for agriculture, high rural unemployment and agricultural underemployment. Cutting fuel peat can reduce household fuel costs and some peat fuel is sold to gain income. Horticultural peat is cut mainly for sale. Expansion of machine extraction, with possible environmental impacts, occurred as interest in peatland conservation increased. Potential conflict arises between local economic needs and conservation. Machine cutting for fuel is widespread, but affects only 2.6 per cent of the blanket peat area; horticultural extraction is more localized and is only one-fifth of the extent of fuel extraction. Altitude, distance from roads, land ownership and rights, turbary, religious affiliation, local economic needs and the role of government departments all contribute to explaining the distribution and extent of extraction.     

A Borehole Test for Chlorinated Solvent Diffusion and Degradation Rates in Sedimentary Rock

We present a new field measurement and numerical interpretation method (combined termed “test”) to parameterize the diffusion of trichloroethene (TCE) and its biodegradation products (DPs) from the matrix of sedimentary rock. The method uses a dual-packer system to interrogate a low-permeability section of the rock matrix adjacent to a previously contaminated borehole and uses the borehole monitoring history to establish the pretest condition. TCE and its DPs are removed from the groundwater between the packers at the onset of the testing. The parameters estimated by fitting a radial diffusion model to the concentration history and borehole concentration data, also termed back diffusion, are the tortuosity factor and sorption coefficients of TCE and DPs in the rock matrix and the TCE and DP biodegradation rate coefficients in the borehole. We demonstrate the equipment design and the interpretive method using a borehole accessing the gray mudstone at a TCE contaminated site in the Newark Basin. In this test, both nonreactive (bromide) and reactive (trichlorofluoroethene) tracers are used to constrain the estimated parameters; however, the bromide tracer was not needed to estimate the parameters in this test. The parameters estimated from the field test are consistent with values measured independently in laboratory experiments using field samples of similar lithology. From the interpretation, we compute the TCE and DP concentration distributions in the rock matrix prior to the test to illustrate how the results can be used to enhance understanding of contaminant distribution in the rock matrix.     

Effects of waterlogging,salinity and light on the productivity of Bruguiera gymnorrhiza and Heritiera littoralis seedlings

This study aimed to establish the effects of waterlogging, salinity and light on the early development of mangroves. Seedlings of Bruguiera gymnorrhiza (L.) Lamk. and Heritiera littoralis Dryand were exposed to 12 weeks of waterlogging, during which time growth and photosynthesis were measured every two weeks. The salinity of the water inundation ranged from fresh water to full-strength sea water (salinity 35). Seedlings were exposed to either full sunlight of 1 500 µmol photon m^–2 s^–1 (SD 397) at midday or shade conditions of 325 µmol photon m^–2 s^–1 (SD 40) of light at midday, to explore whether the plants would be differently affected by prolonged waterlogging in increased salinities and under different light conditions. Heritiera littoralis was more sensitive to waterlogging, salinity and light, displaying a least relative growth rate of 0.127 g g^–1 week^–1 (SE 0.032) under shade, and 0.025 g g^–1 week^–1 (SE 0.021) in full light; while under shade, photosynthesis continued only in fresh water, but photosynthetic yield decreased from 0.7 to 0.4 with increasing duration of waterlogging. By 12 weeks, all H. littoralis seedlings treated with any saltwater mixture had died. Bruguiera gymnorrhiza seedlings maintained a moderate rate of photosynthesis throughout inundation in both shade and full light, with yields of 0.7 and 0.3, respectively. Furthermore, B. gymnorrhiza survived waterlogging in up to 66% seawater, and maintained comparable relative growth rates of 0.164 g g^–1 week^–1 (SE 0.066) with 0.083 g g^–1 week^–1 (SE 0.065) and 0.074 g g^–1 week^–1 (SE 0.036) with 0.052 g g^–1 week^–1 (SE 0.037) under shade and in full light between fresh water and the highest salinity conditions, respectively. These results suggest that B. gymnorrhiza is broadly tolerant, making it a potential candidate species for restoring vulnerable mangrove forests.     

塔里木二叠纪基性-中性-酸性岩浆岩的年代学及其地质意义

塔里木西部柯坪地区出露的早二叠纪玄武岩与盆地内其他地区广泛分布的玄武岩共同构成一个面积约0.25Mkm²的溢流玄武岩省。巴楚地区出露的早二叠纪辉绿岩、正长岩、石英正长岩与石英正长斑岩等多种岩浆岩构成了连续的基性-中性-酸性岩浆序列。野外露头观察表明,巴楚麻扎尔塔格地区的基性-中性-酸性岩浆岩为近同时侵位。柯坪塔格开派兹雷克组顶部层位玄武岩的锆石SHRIMP U-Pb年龄为279.0±4.5Ma, 该年龄值可限定该区二叠纪溢流玄武岩喷发的最晚时限。巴楚麻扎尔塔格石英正长斑岩脉的锆石SHRIMP U-Pb年龄为273.0±3.7Ma, 与前人测定的巴楚辉绿岩脉和正长岩的锆石年龄在误差范围内一致,表明巴楚地区的基性-中性-酸性岩浆岩为近同时侵位,时间在275Ma左右。综合已发表的塔里木二叠纪岩浆岩高精度年代数据,本文提出：整个塔里木大火成岩省岩浆作用的持续时间约为20Myrs; 291~287Ma喷发的巨量溢流玄武岩可能构成塔里木大火成岩省的主体,是地幔柱头部熔融的直接产物; 283~272Ma侵位的巴楚、一间房和塔北地区的其它类型岩浆岩体积较小,为塔里木大火成岩省晚期岩浆作用的产物。     

Biogeochemical evolution of a landfill leachate plume, Norman, Oklahoma

Leachate from municipal landfills can create groundwater contaminant plumes that may last for decades to centuries. The fate of reactive contaminants in leachate-affected aquifers depends on the sustainability of biogeochemical processes affecting contaminant transport. Temporal variations in the configuration of redox zones downgradient from the Norman Landfill were studied for more than a decade. The leachate plume contained elevated concentrations of nonvolatile dissolved organic carbon (NVDOC) (up to 300 mg/L), methane (16 mg/L), ammonium (650 mg/L as N), iron (23 mg/L), chloride (1030 mg/L), and bicarbonate (4270 mg/L). Chemical and isotopic investigations along a 2D plume transect revealed consumption of solid and aqueous electron acceptors in the aquifer, depleting the natural attenuation capacity. Despite the relative recalcitrance of NVDOC to biodegradation, the center of the plume was depleted in sulfate, which reduces the long-term oxidation capacity of the leachate-affected aquifer. Ammonium and methane were attenuated in the aquifer relative to chloride by different processes: ammonium transport was retarded mainly by physical interaction with aquifer solids, whereas the methane plume was truncated largely by oxidation. Studies near plume boundaries revealed temporal variability in constituent concentrations related in part to hydrologic changes at various time scales. The upper boundary of the plume was a particularly active location where redox reactions responded to recharge events and seasonal water-table fluctuations. Accurately describing the biogeochemical processes that affect the transport of contaminants in this landfill-leachate-affected aquifer required understanding the aquifer's geologic and hydrodynamic framework.