SOLID-LIQUID INTERFACE PROCESS OF HEAVY METALS IN THE CHANGJIANG ESTUARYKINETICS OF ADSORPTION OF Pb, Cu AND Cd ON HFO

The adsorption kinetics of Pb, Cu and Cd on hydrous ferrk oxide (HFO) has been approached in tthe simulated environmental conditions of the Changjiang Estuary. The forward adsorption rate constants of different systems under different temperatures have been determined, and the activation energies of the adsorption for Pb and Cu evaluated (Pb=7 kcal/mol, Cu= 11 kcal/mol). The results show that Pb and Cu are strongly adsorbed by HFO; the order of their adsorption rate is found to be Pb≥Cu≥Cd, which follows thte order of their theonody-namic equilibrium constants. It has been demonstrated that the surface exchange-adsorption is the determining step of the solid-liquid interface process. The field investigation results are theoretically explained by the kinetic mechanism.     

Effects of pulp bleach plant effluents on hepatic xenobiotic biotransformation enzymes in fish: Laboratory and field studies

The present preliminary report on studies of the influence of pulp bleach plant effluents on hepatic biotransformation enzymes in fish is a part of a major characterisation of biochemical and physiological effects of effluents from pulp industries in Sweden. Our studies on the xenobiotic biotransformation enzymes demonstrate, so far, that the pulp effluents have the potential to strongly induce 7-ethoxyresorufin-O-deethylase activity (EROD) in fish liver and that fish living in the receiving water of an effluent from a pulp bleach plant have induced hepatic EROD activities as well as higher hepatic UDP glucuronyltransferase activities than those living in an unpolluted area. It is thus apparent that measures of induction of biotransformation enzymes in fish liver may be a useful approach in monitoring the presence of potential hazardous compounds released from pulp industries.     

Size distribution of colloidal trace metals and organic carbon during a coastal bloom in the Baltic Sea

The physico-chemical speciation of organic carbon and selected metals was measured during a coastal bloom in Ekhagen Bay, Baltic Sea, using ultrafiltration.One important objective with the study was to see if any depletion of trace metals could be measured in the directly bioavailable fraction (<1000 Da, the soluble low molecular weight fraction, LMW) during a plankton bloom. Filters with five different cut-offs were used (1 kD (1000 Da), 5 kD, 10 kD, 100 kD and 0.22 μm) in order to delineate the size distribution of colloidal organic carbon (COC) and trace metals.During the bloom in May, LMW Al, Co, Cu, Mn and Ni concentrations decreased although the colloidal and particulate concentrations were relatively high. Data show that desorption of colloidal and particulate bound trace metals to the LMW fraction was slower than the process depleting the LMW fraction.Estimates of the maximum active uptake of Cu, Ni and Mn by the phytoplankton, and the loss of non-bioactive Al from the LMW fraction, indicate that processes other than active uptake by phytoplankton must contribute to the observed depletion of trace metals in the LMW fraction. Hence, in order to estimate the bioavailable pool of trace metals for plankton during bloom conditions, these other processes must be understood and quantified.Transparent Exopolymeric Particles (TEP, reflecting sugar-rich phytoplankton exudates) increased around eight times during the plankton bloom. We hypothesize that the formation of TEP is a process that might be important for the transfer of trace metals from the LMW to the particulate fraction during the phytoplankton bloom, but the significance of TEP for this depletion in Baltic Sea surface water remains to be shown.     

虾蟹类亲体生殖营养需求研究的进展

本文综述了虾蟹类生殖营养的最新研究成果,并讨论了各营养素对虾蟹类亲体成熟、生殖和幼体质量的影响．此外,就今后在虾蟹类亲体生殖营养方面开展深入研究提出了一些建议。     

The POC / Th ratio of settling particles isolated using split flow-thin cell fractionation (SPLITT)

The common assumption that the ratio between particulate organic carbon (POC) and particulate ²³⁴Th obtained from shallow sediment traps and filterable particles are representative of the ratio in the total particle settling flux should be treated with caution in view of well-known biases associated with tethered shallow sediment traps and the decoupling between size and settling velocity of many natural particle regimes. To make progress toward reliably constraining the POC / ²³⁴Th ratio on truly settling particles, we have tested here a settling collection technique designed to remove any hydrodynamic bias; split flow-thin cell fractionation (SPLITT). These first results from a North Sea fjord and an open Baltic Sea time-series station indicates that the POC / ²³⁴Th ratio on the more complete particle-settling spectrum, isolated with SPLITT, was higher than the POC / ²³⁴Th ratio obtained simultaneously from tethered shallow sediment traps in seven out of seven parallel deployments with an average factor of 210%. The POC / ²³⁴Th ratio from the SPLITT was either in the same range or higher than that obtained on filtered “bulk” particles. To explain this novel data we hypothesize that the slowest settling fraction is organic-matter rich and does not strongly complex ²³⁴Th (i.e., high POC / ²³⁴Th). We suggest that this ultra-slow sinking fraction is better collected by SPLITT than with tethered sediment traps because of minimized hydrodynamic bias.This was tested using the ratio of POC / Al as a tracer of detrital mineral-ballast influenced settling velocity. The higher POC / Al ratios in SPLITT samples relative to in traps is consistent with the hypothesis that SPLITT is better suited for collecting also the slow-settling component of sinking particles. This important slow-settling component appears to here consist primarily of non-APS/TEP components of plankton exudates or other less-strongly ²³⁴Th-complexing organic matter. Further applications of the SPLITT technique are likely to return increasingly new insights on the composition (including “truly settling” POC / ²³⁴Th) of the total spectrum of particles settling out of the upper ocean.     

多目标粒子群算法与选址中的形状优化

选址问题是GIS最基本的任务之一.一般性的选址是基于点的位置优化,可利用有关GIS功能完成.实际的选址问题是很复杂的.在给定设施的数量和面积前提下,需要在空间上确定设施的最佳位置,并对形状进行优化,以获取最大的效用.采用一般的方法无法求解这种最优化问题.而且,当选址问题涉及多个目标和不同的约束性条件时,就会变得异常复杂.提出了利用多目标粒子群优化算法和区域形状变异算法相结合来解决复杂的空间选址问题.具有智能的搜索方法,大大提高了空间搜索能力,并保持了搜索区域的连通性,取得了较好的效果.     

基于蚁群智能的遥感影像分类新方法

智能式遥感分类是遥感研究的新热点.提出了一种基于蚁群智能规则挖掘(ant-miner)的遥感影像分类新方法.遥感数据各波段之间存在较强的相关性,这种相关性往往会导致分类产生误差.而ant-miner算法中的信息素是基于规则整体性能的,信息素的动态更新能有效地处理相关性较强的数据,所提供的正反馈信息能纠正启发式函数缺陷所造成的错误.因此,蚁群智能算法应用于遥感分类具有一定的优势.将该方法用于广州市地区的遥感影像,取得了较好的分类结果.并与See5.0决策树方法及最大似然方法(MLH)进行了对比研究,实验结果表明,蚁群智能算法分类精度比后两者的分类精度更高.     

三峡水库区兴山后坝滑坡成因分析

文章通过对三峡水库区兴山后坝滑坡的地质、结构及变形特征研究以及稳定性分析,阐明了该滑坡成因和影响因素。研究发现,滑坡活动主要受地形地貌、地层岩性、人类工程活动以及降雨等因素的影响。运用剩余推力法对比分析天然及暴雨条件下不同层位的滑坡稳定性系数,得出在暴雨作用下滑坡表层滑带稳定性系数最小,不同滑带的稳定性受降雨的影响也各不相同,呈表层〉浅层〉深层的规律;这主要受滑带土的粘土矿物组分的影响。     

山东省日照市蓝色经济区工程建设适宜性评价

本文以山东省日照市蓝色经济区为研究区, 通过野外地质调查和室内综合分析, 选取场地稳定性、工程地质条件、地下水条件, 地形排水条件、地质灾害及其他因素6个一级评价因子, 构造活动、场地土类型、建筑场地类别等13个二级评价因子, 利用专家-层次分析定权法进行区内工程建设适宜性评价, 得到了相应工程建设评价分区图。评价结果表明, 日照市场地工程建设适宜性总体较好, 大部分地区适宜进行高层建筑工程建设, 占84.50%; 地下空间开发利用条件优越, 全区多数地区属于城市地下空间建设适宜区, 适宜性差及不适宜区主要分布在付疃河两岸附近和海岸附近、大型高速公路和铁路沿线一带区域及城区; 轨道交通建设适宜性良好, 小部分不适宜区主要集中在付疃河下游夹仓和小古镇一带及其沿海地区。评价结果可有效地服务于该地区规划布局、建设发展和工程选址, 具有重要的理论和实践指导意义。