Diatoms indicate that calcium decline,not acidification,explains recent cladoceran assemblage changes in south-central Ontario softwater lakes

In recent decades, softwater lakes across Canada have experienced a wide array of anthropogenic influences, with acidification and climate warming of particular concern. Here, we compare modern and pre-industrial sedimentary diatom assemblages from 36 softwater lakes located on the Canadian Shield in south-central Ontario to determine whether lake acidification or reduced calcium availability was the main stressor responsible for recent declines in Ca-sensitive cladoceran taxa. Regional surveys of south-central Ontario water chemistry have identified the pH recovery of many formerly acidified lakes, and our fossil diatom-inferred pH analyses indicate that modern lakewater pH in the 36 study lakes is similar to (or higher than) pre-industrial levels, with diatom assemblages from both time periods dominated by taxa with similar pH preferences. In addition, modern diatom assemblages compared to pre-industrial assemblages contained higher relative abundances of planktonic diatom taxa (e.g. Asterionella formosa and the Discostella stelligera complex) and lower relative abundances of heavily silicified diatoms (e.g. Aulacoseira taxa) and benthic fragilarioid taxa. These taxonomic shifts are consistent with warming-induced changes in lake properties including a longer ice-free period, decreased wind speed and/or increased thermal stability. We conclude that recent changes observed within the cladoceran assemblages of these lakes are not a response to acidification, but are likely a consequence of Ca declines. In addition, our data suggest that regional climate warming is now responsible for the diatom changes observed in this region.     

Arctic forcing of decadal variability in the tropical Pacific Ocean in a high-resolution global coupled GCM

The hypothesis that northern high-latitude atmospheric variability influences decadal variability in the tropical Pacific Ocean by modulating the wind jet blowing over the Gulf of Tehuantepec (GT) is examined using the high-resolution configuration of the MIROC 3.2 global coupled model. The model is shown to have acceptable skill in replicating the spatial pattern, strength, seasonality, and time scale of observed GT wind events. The decadal variability of the simulated GT winds in a 100-year control integration is driven by the Arctic Oscillation (AO). The regional impacts of the GT winds include strong sea surface cooling, increased salinity, and the generation of westward-propagating anticyclonic eddies, also consistent with observations. However, significant nonlocal effects also emerge in concert with the low-frequency variability of the GT winds, including anomalously low upper ocean heat content (OHC) in the central tropical Pacific Ocean. It is suggested that the mesoscale eddies generated by the wind stress curl signature of the GT winds, which propagate several thousand kilometers toward the central Pacific, contribute to this anomaly by strengthening the meridional overturning associated with the northern subtropical cell. A parallel mechanism for the decadal OHC variability is considered by examining the Ekman and Sverdrup transports inferred from the atmospheric circulation anomalies in the northern midlatitude Pacific directly associated with the AO.     

Characterizing the degree of amplitude‐variation‐with‐offset nonlinearity in seismic physical modelling reflection data

The nonlinearity of the seismic amplitude‐variation‐with‐offset response is investigated with physical modelling data. Nonlinearity in amplitude‐variation‐with‐offset becomes important in the presence of large relative changes in acoustic and elastic medium properties. A procedure for pre‐processing physical modelling reflection data is enacted on the reflection from a water‐plexiglas boundary. The resulting picked and processed amplitudes are compared with the exact solutions of the plane‐wave Zoeppritz equations, as well as approximations that are first, second, and third order in , , and . In the low angle range of 0°–20°, the third‐order plane‐wave approximation is sufficient to capture the nonlinearity of the amplitude‐variation‐with‐offset response of a liquid‐solid boundary with , , and ρ contrasts of 1485–2745 m/s, 0–1380 m/s, and 1.00–1.19 gm/cc respectively, to an accuracy value of roughly 1%. This is in contrast to the linear Aki–Richards approximation, which is in error by as much as 25% in the same angle range. Even‐order nonlinear corrective terms are observed to be primarily involved in correcting the angle dependence of , whereas the odd‐order nonlinear terms are involved in determining the absolute amplitude‐variation‐with‐offset magnitudes.     

Understanding fen hydrology across multiple scales

Fens, which are among the most biodiverse of wetland types in the USA, typically occur in glacial landscapes characterized by geo‐morphologic variability at multiple spatial scales. As a result, the hydrologic systems that sustain fens are complex and not well understood. Traditional approaches for characterizing such systems use simplifying assumptions that cannot adequately capture the impact of variability in geology and topography. In this study, a hierarchical, multi‐scale groundwater modelling approach coupled with a geologic model is used to understand the hydrology of a fen in Michigan. This approach uses high‐resolution data to simulate the multi‐scale topographic and hydrologic framework and lithologic data from more than 8500 boreholes in a statewide water well database to capture the complex geology. A hierarchy of dynamically linked models is developed that simulates groundwater flow at all scales of interest and to delineate the areas that contribute groundwater to the fen. The results show the fen receiving groundwater from multiple sources: an adjacent wetland, local recharge, a nearby lake and a regional groundwater mound. Water from the regional mound flows to an intermediate source before reaching the fen, forming a ‘cascading’ connection, while other sources provide water through ‘direct’ connections. The regional mound is also the source of water to other fens, streams and lakes in this area, thus creating a large, interconnected hydrologic system that sustains the entire ecosystem. In order to sustainably manage such systems, conservation efforts must include both site‐based protection and management, as well as regional protection and management of groundwater source areas. Copyright © 2016 John Wiley & Sons, Ltd.     

The effect of increasing gravel cover on forest roads for reduced sediment delivery to stream crossings

Direct sediment inputs from forest roads at stream crossings are a major concern for water quality and aquatic habitat. Legacy road–stream crossing approaches, or the section of road leading to the stream, may have poor water and grade control upon reopening, thus increasing the potential for negative impacts to water quality. Rainfall simulation experiments were conducted on the entire running surface area associated with six reopened stream crossing approaches in the south‐western Virginia Piedmont physiographic region, USA. Event‐based surface run‐off and associated total suspended solid (TSS) concentrations were compared among a succession of gravel surfacing treatments that represented increasing intensities of best management practice (BMP) implementation. The three treatments were no gravel (10–19% cover), low gravel (34–60% cover), and high gravel (50–99% cover). Increased field hydraulic conductivity was associated with maximized surface cover and ranged from 7.2 to 41.6, 11.9 to 46.3, and 16.0 to 58.6 mm h⁻¹ respectively for the no gravel, low gravel, and high gravel treatments. Median TSS concentration of surface run‐off for the no gravel treatment (2.84 g l⁻¹) was greater than low gravel (1.10 g l⁻¹) and high gravel (0.82 g l⁻¹) by factors of 2.6 and 3.5 respectively. Stream crossing approaches with 90–99% surface cover had TSS concentrations below 1 g l⁻¹. Reducing the length of road segments that drain directly to the stream can reduce the costs associated with gravel surfacing. This research demonstrates that judicious and low‐cost BMPs can ameliorate poor water control and soil erosion associated with reopening legacy roads. Copyright © 2014 John Wiley & Sons, Ltd.     

Computational issues and applications of line-elements to model subsurface flow governed by the modified Helmholtz equation

Two new approaches are presented for the accurate computation of the potential due to line elements that satisfy the modified Helmholtz equation with complex parameters. The first approach is based on fundamental solutions in elliptical coordinates and results in products of Mathieu functions. The second approach is based on the integration of modified Bessel functions. Both approaches allow evaluation of the potential at any distance from the element. The computational approaches are applied to model transient flow with the Laplace transform analytic element method. The Laplace domain solution is computed using a combination of point elements and the presented line elements. The time domain solution is obtained through a numerical inversion. Two applications are presented to transient flow fields, which could not be modeled with the Laplace transform analytic element method prior to this work. The first application concerns transient single-aquifer flow to wells near impermeable walls modeled with line-doublets. The second application concerns transient two-aquifer flow to a well near a stream modeled with line-sinks.     

Separating freshwater flux effects on ENSO in a hybrid coupled model of the tropical Pacific

Climate Dynamics - Freshwater flux (FWF) at the sea surface, defined as precipitation minus evaporation, is a major atmospheric forcing to the ocean that affects sea surface salinity (SSS) and...     

Methods for reactive oxygen species (ROS) detection in aqueous environments

This review summarizes direct and indirect analytical methods for the detection and quantification of the reactive oxygen species (ROS): ¹O₂, O ₂ ^·? /HOO·, H₂O₂, HO·, and CO ₃ ^·? in aqueous solution. Each section briefly describes the chemical properties of a specific ROS followed by a table (organized alphabetically by detection method, i.e., absorbance, chemiluminescence, etc.) summarizing the nature of the observable (associated analytical signal) for each method, limit of detection, application notes, and reaction of the probe molecule with the particular ROS.     

Monte Carlo simulations of the water vapor plumes on Enceladus

Monte Carlo simulations are used to model the July 14, 2005 UVIS stellar occultation observations of the water vapor plumes on Enceladus. These simulations indicate that the observations can be best fit if the water molecules ejected along the Tiger Stripes in the South Polar region of Enceladus have a vertical surface velocity of 300-500 m/s at the surface. The high surface velocity suggests that the plumes on Enceladus originate from some depth beneath the surface. The total escape rate of water molecules is 4-6×¹⁰²⁷ s⁻¹, or 120-180 kg/s, consistent with previous works, and more than 100 times the estimated mass escape rate for ice particles. The average deposition rate in the South Polar region is on the order of 10¹¹ cm⁻² s⁻¹, yielding a resurfacing rate as high as 3×¹⁰⁻⁴ cm/yr. The globally averaged deposition rate of water molecules is about one order of magnitude lower.