Pharmaceuticals and Other Organic Waste Water Contaminants Within a Leachate Plume Downgradient of a Municipal Landfill

Ground water samples collected from the Norman Landfill research site in central Oklahoma were analyzed as part of the U.S. Geological Survey (USGS) Toxic Substances Hydrology Program's national reconnaissance of pharmaceuticals and other organic waste water contaminants (OWCs) in ground water. Five sites, four of which are located downgradient of the landfill, were sampled in 2000 and analyzed for 76 OWCs using four research methods developed by the USGS. OWCs were detected in water samples from all of the sites sampled, with 22 of the 76 OWCs being detected at least once. Cholesterol (a plant and animal steroid), was detected at all five sites and was the only compound detected in a well upgradient of the landfill. N,N-diethyltoluamide (DEBT used in insect repellent) and tri(2-chloroethyl) phosphate (fire-retardant) were detected in water samples from all four sites located within the landfill-derived leachate plume. The sites closest to the landfill had more detections and greater concentrations of each of the detected compounds than sites located farther away. Detection of multiple OWCs occurred in the four sites located within the leachate plume, with a minimum of four and a maximum of 17 OWCs detected. Because the landfill was established in the 1920s and closed in 1985, many compounds detected in the leachate plume were likely disposed of decades ago. These results indicate the potential for long-term persistence and transport of some OWCs in ground water.     

Brown trout (Salmo trutta) removal by rotenone alters zooplankton and phytoplankton community composition in a shallow mesotrophic reservoir

Brown trout (Salmo trutta) are known to have effects on multiple trophic levels in New Zealand streams, but their impacts on lower trophic levels are less well understood within lentic systems. We examined the effects of brown trout removal using rotenone on zooplankton and phytoplankton community composition in the Upper Karori Reservoir, New Zealand. Significant shifts were observed in zooplankton and phytoplankton composition following removal of brown trout from the reservoir. Shifts in zooplankton community composition did not occur immediately following trout removal (February), but instead followed the likely timing of galaxiid spawning (July). The removal of brown trout likely resulted in reduced predation pressure on galaxiids. A major change occurred in the zooplankton community with the dominance shifting from larger crustaceans to smaller rotifers, indicating an increased predation pressure from the larval native galaxiid. A delayed response in zooplankton community composition change indicates rotenone was not the direct cause of this. A major shift in phytoplankton community composition occurred immediately following trout removal. This was not consistent with the trophic cascade hypothesis of reduced grazing pressure from larger zooplankton due to increased galaxiid predation as a result of brown trout removal.     

Degradates provide insight to spatial and temporal trends of herbicides in ground water

Since 1995, a network of municipal wells in Iowa, representing all major aquifer types (alluvial, bedrock/karst region, glacial drift, bedrock/nonkarst region), has been repeatedly sampled for a broad suite of herbicide compounds yielding one of the most comprehensive statewide databases of such compounds currently available in the United States. This dataset is ideal for documenting the insight that herbicide degradates provide to the spatial and temporal distribution of herbicides in ground water. During 2001, 86 municipal wells in Iowa were sampled and analyzed for 21 herbicide parent compounds and 24 herbicide degradates. The frequency of detection increased from 17% when only herbicide parent compounds were considered to 53% when both herbicide parents and degradates were considered. Thus, the transport of herbicide compounds to ground water is substantially underestimated when herbicide degradates are not considered. A significant difference in the results among the major aquifer types was apparent only when both herbicide parent compounds and their degradates were considered. In addition, including herbicide degradates greatly improved the statistical relation to the age of the water being sampled. When herbicide parent compounds are considered, only 40% of the wells lacking a herbicide detection could be explained by the age of the water predating herbicide use. However, when herbicide degradates were also considered, 80% of the ground water samples lacking a detection could be explained by the age of the water predating herbicide use. Finally, a temporal pattern in alachlor concentrations in ground water could only be identified when alachlor degradates were considered.     

Socioeconomic dynamics of the Ghanaian tuna industry: a value-chain approach to understanding aspects of global fisheries

This study investigated how an industrial tuna fishery functions in terms of procedures, practices, governance and finance in the context of Ghana, West Africa. Tuna is Ghana’s biggest seafood export, contributing significantly to the domestic fisheries sector. A case-study approach was used to analyse relevant social and economic factors at the local scale to better understand how the global seafood industry operates in a low-income country. A value-chain framework was adopted to assess market structures, sales pathways and revenue distribution. We also investigated the role of actors engaged in the industry using secondary data, interviews, questionnaires and participant observations. The results revealed a changing organisational structure in tuna production, moving from bait-boat fishing with smaller companies to large-scale purse-seine fishing backed by consolidated Asian seafood companies. Production was found to depend significantly on local female intermediaries for access to funds through prefinancing arrangements. Considerable illegalities were identified within the value chain, highlighting the need for improved partnership and licensing negotiations, and for low-cost marine control and surveillance tools. As vertical integration increases within the industry, the influence of corporations as keystone actors becomes evident for the future social and ecological sustainability of the industry.     

岩浆侵入体对有机质生烃(成熟)作用的影响及数值模拟

火山作用带来的热源对有机质的成烃进程和成烃量产生了重要影响,这种热效应一方面可以加速烃源岩的成熟和成烃作用,另一方面可以破坏先期形成的油藏。目前国内外对火山作用的生烃热效应方面的研究主要在热成熟度参数变化描述及岩浆侵入体引起的围岩热蚀变程度的讨论。火山作用对成烃/成藏的利弊,影响的时/空范围、程度的定量研究尚未报道。本次在前人研究基础上,建立了描述岩浆侵入体散热的热传导模型,进一步结合EasyRo%模型和前人报道的实测Ro数据进行了模型检验。通过调整模型的参数和岩浆侵入体厚度、位置及个数等进行了火山作用对有机质成熟作用及生烃影响的研究。模拟结果表明:岩浆侵入体的热作用范围是有限的,但是不同地质情况,影响的范围广度也不相同,对于相同厚度的侵入体,初始温度越高,作用范围越广,但是一般X/D3(X/D代表离接触面的距离与侵入体厚度的比值)。对于不同厚度侵入体而言,在侵入体热作用影响的范围内,侵入体越厚,热作用的范围越广。同时数值模拟结果也表明岩浆侵入体的存在可以改变烃源岩生烃期。