The solubility of aragonite in seawater—I. Effect of pH and water chemistry at one atmosphere

The effect of water chemistry on the solubility of aragonite in seawater has been defined experimentally as a series of apparent solubility products measured with respect to pH at one atmosphere.The dominant control of the apparent solubility product of aragonite is the carbonate ion concentration, and this is primarily a function of pH. In the light of this fact, we have reconciled our data with 81 other reported values of aragonite solubility by simply examining the water chemistry of the waters in which they were determined.     

Trends in 1,4-Dioxane Analyses: Implications for Identification and Characterization of Contaminated Groundwater Sites

1,4-Dioxane is a contaminant of emerging concern, and there is significant uncertainty about how its environmental occurrence in groundwater is being assessed given the various analytical methods available. This study compiled public sampling records from 2000 to 2019 that included >106,000 analyses of 1,4-dioxane from 822 different U.S. sites. The 1,4-dioxane detection frequency in the entire dataset (including all methods) was 45%, and the median detected concentration was 10 μg/L, highlighting the dilute nature of 1,4-dioxane in environmental media and the importance of selecting methods with adequate sensitivity. The annual distribution of samples analyzed by each method type confirmed a shift towards methods designed for semi-volatile compounds (Method 8270 and Method 8270 SIM) that exhibited consistently lower reporting limits (median reporting limit for each year typically ≤1 μg/L). In contrast, the method designed for volatile compounds (Method 8260) exhibited less sensitivity for 1,4-dioxane (median reporting limit per year between 40 and 100 μg/L) and its use declined significantly over time with increasing use of the moderately sensitive Method 8260 SIM in later years. This shift contributed to an increase in the 1,4-dioxane detection frequency over time, with a strong correlation between the annual detection frequency and the median reporting limit. Sites where 1,4-dioxane was analyzed but not detected overwhelmingly used less-sensitive methods that may not have been adequate for the expected concentration levels. Given the sub-μg/L groundwater criteria issued for 1,4-dioxane by some regulatory agencies, more sensitive and accurate methods will be increasingly needed to assess compliance.     

北吕宋岛菲律宾活动带蛇绿岩及其上覆浊积岩的放射虫研究新进展

The basement of the Philippine Mobile Belt (PMB) is mainly composed of ophiolites that are mostly overlain by Paleogene to Miocene turbidites in central Luzon. To clarify the geological development of the PMB with respect to the initial stage of the arc volcanism (eg. Yumul et al., 2003, 2008; Dimalanta and Yumul, 2003; Suzuki et al., 2011), radiolarian dating was examined in siliceous sediments associated with the ophiolites and turbidites. The samples were collected from sites identified with the Zambales and Montalban ophiolites, basic tuff phyllites in NW Din-galan, and their overlying formations.     

Relationship of diagenetic chlorite rims to depositional facies in Lower Cretaceous reservoir sandstones of the Scotian Basin

The relationship between diagenetic chlorite rims and depositional facies in deltaic strata of the Lower Cretaceous Missisauga Formation was investigated using a combination of electron microprobe, bulk geochemistry and X‐ray diffraction data. The succession studied comprises several stacked parasequences. The delta progradational facies association includes: (i) fluvial or distributary channel sandstones (some with tidal influence); (ii) thick‐bedded delta‐front graded beds of sandstone interpreted as resulting from fluvial hyperpycnal flow during floods and storms; and (iii) more distal muddier delta‐front and prodeltaic facies. The transgressive facies association includes lag conglomerate, siderite‐cemented muddy sandstone and mudstone, and bioclastic sandy limestone. Chlorite rims are absent in the fluvial facies and best developed in thick sandstones lacking mudstone baffles. Good quality chlorite rims are well correlated with Ti in bulk geochemistry. Ti is a proxy for Fe availability, principally from the breakdown of abundant detrital ilmenite (FeTiO₃). Under conditions of sea floor diagenesis, the abrupt decrease in sedimentation rate at transgressive surfaces caused progressive shallowing of the sulphate‐depletion level and of the overlying Eh‐controlled diagenetic zones, resulting in conditions suitable for diagenetic formation of berthierine to migrate upwards through the packet of reservoir sandstones. This early diagenetic berthierine suppressed silica cementation and later recrystallized to chlorite. Thick euhedral outer chlorite rims were precipitated from formation water in sandstone lacking muddy baffles on this chlorite substrate and inhibited late carbonate cementation. This study thus shows that the preservation of porosity by chlorite rims is a two‐stage process. Rapidly deposited delta‐front turbidite facies create early diagenetic conditions that eventually lead to the formation of chlorite rims, but the best quality chlorite rims are restricted to sandstones with high permeability during burial diagenesis.     

Mesozoic Evaniidae (Insecta: Hymenoptera) in Spanish Amber: Reanalysis of the Phylogeny of the Evanioidea

<正>One new genus and five new species of the family Evaniidae are described from the Early Cretaceous (Albian)Spanish amber of Penacerrada-Ⅰ(Province of Burgos),San Just and Arroyo de la Pascueta(both in the Province of Teruel):Cretevania alonsoi sp.nov.,C.montoyai sp.nov.,C.alcalai sp.nov.,C.rubusensis sp.nov.,and Iberoevania roblesi gen.and sp.nov.Taxonomic changes include Cretevania pristina(Zhang and Zhang,2000) comb.nov.,C.exquisita(Zhang,Rasmtsyn,Wang and Zhang,2007)comb.nov.,C.vesca(Zhang,Rasnitsyn,Wang and Zhang,2007)comb.nov.,and C.cyrtocerca(Deans,2004)comb.nov.,as a result of the reinterpretation of the genera Procretevania and Eovernevania.The new well preserved specimens of the genus Cretevania,together with the characters shown by the type specimens of the synonymized genera,give new information about their anatomical characters of taxonomical importance,and the genus Cretevania Rasnitsyn,1975 is re-diagnosed.The holotypes of the Russian species in amber have been revised.A cladistic analysis of fossil and extant groups of the superfamily Evanioidea is included.Cretevania had a wide palaeogeographic distribution,with the highest diversity known from Spain.The 13 known Cretevania species show a high interspecific variation mainly in wing characteristics,and a wide range of body and wing size.     

Application of ultraviolet fluorometry and excitation-emission matrix spectroscopy (EEMS) to fingerprint oil and chemically dispersed oil in seawater

Excitation-emission matrix spectroscopy (EEMS) was used to characterize the ultra violet fluorescence fingerprints of eight crude oils (with a 14,470-fold range of dynamic viscosity) in seawater. When the chemical dispersant Corexit 9500 was mixed with the oils prior to their dispersion in seawater, the fingerprints of each oil changed primarily as an increase in fluorescence over an emission band centered on 445 nm. In order to simplify the wealth of information available in the excitation-emission matrix spectra (EEMs), two ratios were calculated. A 66-90% decrease in the slope ratio was observed with the addition of Corexit. When the slope ratios were reduced in complexity to intensity ratios, similar trends were apparent. As a result either of the ratios could be used as a simple and rapid means of identifying and monitoring chemically dispersed oil in the open ocean.     

A local spatial decision support system for developing countries based on MCA,fuzzy sets and OWA – case study of a municipality in Cuba

This paper presents a Spatial Decision Support System for local governments of developing countries. It allows municipality government, enterprises, scientific community and civil society to address decision problems using GIS. The framework is supported by four modules of information technologies: Environmental Decision Support Database, Data Manipulation, Decision Support, and Mapping. A case study is presented covering the implementation of this framework in one municipality of Cuba. An example of land suitability planning for coconut crops is used to evaluate the system performance and usability. Results show local municipalities are able to use this framework to solve local decision problems using state of the art decision making even with low infrastructure development.     

Effects of chemical dispersants and mineral fines on crude oil dispersion in a wave tank under breaking waves

The interaction of chemical dispersants and suspended sediments with crude oil influences the fate and transport of oil spills in coastal waters. A wave tank study was conducted to investigate the effects of chemical dispersants and mineral fines on the dispersion of oil and the formation of oil-mineral-aggregates (OMAs) in natural seawater. Results of ultraviolet spectrofluorometry and gas chromatography flame ionized detection analysis indicated that dispersants and mineral fines, alone and in combination, enhanced the dispersion of oil into the water column. Measurements taken with a laser in situ scattering and transmissometer (LISST-100X) showed that the presence of mineral fines increased the total concentration of the suspended particles from 4 to 10microl l(-1), whereas the presence of dispersants decreased the particle size (mass mean diameter) of OMAs from 50 to 10microm. Observation with an epifluorescence microscope indicated that the presence of dispersants, mineral fines, or both in combination significantly increased the number of particles dispersed into the water.