The geochemistry of lead in rivers,estuaries and the continental shelf of the Southeastern United States

Transport by southeastern rivers has insignificant influence on the lead concentration of southeastern shelf waters. If the rate of mobilization and transport of lead by these rivers is representative of uncontaminated fluvial transport during the Pleistocene, only about 5% of the prehistoric output of lead to the North Atlantic can be accounted for by river input.Lead concentrations in southeastern shelf waters are similar to those of North Atlantic Water from the upper 1000 m, which is probably similar to the intrusion source water for the shelf. Atmospheric inputs to the shelf of the same magnitude as observed for the Western North Atlantic are difficult to reconcile given the residence time of shelf waters and their lead concentration unless the rate of loss of lead to shelf sediments is about the same as the atmospheric flux.     

Impact of mercury emissions from incineration of automobile shredder residue in Japan

Mercury emissions from the incineration of automobile shredder residues (ASRs) were investigated. Continuous monitoring of elemental and reactive gaseous Hg in flue gas was performed in lab-scale and plant-scale ASR incineration. Results of continuous monitoring agreed with those obtained using the JIS K0222 method and Ontario-Hydro method. Before cleaning by air pollutant control devices (APCDs), reactive Hg was the dominant form of that element in both lab-scale and plant-scale results. Emission factors of reactive Hg before APCDs estimated from monitoring results showed large differences between plant-scale and lab-scale emissions. The emission factor in the plant scale was more than 10 times larger than that in the lab-scale, which is explainable by the different Hg contents of ASR. Based on plant-scale monitoring at the stack, emission factors after APCDs were estimated as 0.79 mg-Hg/Mg-ASR for elemental Hg and 6.8 mg-Hg/Mg-ASR for reactive Hg. Using these emission factors, total Hg emissions from ASR incineration were estimated as 2.2 kg/a. An ASR incineration plant investigated in this study used highly effective APCDs. Consequently, these emission factors might result in underestimation of national Hg emissions from ASR incineration. Emission factors estimated from lab-scale monitoring at a fabric filter outlet side might be more appropriate. However, even if emission factors calculated from plant-scale or the lab-scale monitoring are used, estimated emissions are still less than 1.0% of total Hg emissions in Japan. Therefore, Hg emissions from ASR incineration can be evaluated as insignificant. Unless Hg contents of ASR increase extremely, ASR incineration would be a minor source of Hg atmospheric emission in Japan, even if all ASRs were incinerated.     

Near inertial motion excited by wind change in a margin of the Typhoon 9019

An excitation of inertial oscillation in the upper layer east of course of Typhoon 9019 was fortuitously observed at three surface buoys deployed during the Ocean Mixed Layer Experiment (OMLET). The observed inertial oscillation was compared with wind fluctuation measured at Ocean Weather Station T (29°N, 135°E) which was placed at the center of a triangle with three vertexes occupied by the respective surface buoys. Inertial oscillation is effectively excited in the mixed layer at the eastern margin of the typhoon by a rapid decrease of wind rather than by prevailing strong wind. It is shown by means of a least square deviation that the inertial oscillation observed in the mixed layer has a period of 23.9 hours shorter than the local inertial period of 24.7 hours. This shorter period suggests that the inertial oscillation has the finite velocities of phase and group as an inertial internal wave. A theoretically obtained ratio of vertical component of group velocity to that of phase velocity, approximately agrees with observed value. The inertial internal wave is excited by fluctuation of divergence with near inertial period in the mixed layer.     

Sio Guyot: A complex volcanic edifice in the western Mid-Pacific Mountains

Sio Guyot, in the westernmost edge of the Mid-Pacific Mountains, is a large, complex volcanic edifice rising to more than 1200 m below sea level. The summit is divided into two flat-topped areas by a WNW-trending sediment-filled trough. Seismic reflection profiles reveal three acoustic units: an upper transparent layer (pelagic cap), a lower opaque layer (reef- and lagoon-derived sediments), and an acoustic (volcanic) basement. Free-air gravity anomalies indicate three eruptive centers or conduits within the main edifice, which apparently was constructed during late Cretaceous time on a broad basement swell or plateau that today is more than 3400 m below sea level (1500 m above regional abyssal depths).     

Branching and joining of the Tsushima Current around the Oki Islands

We discussed the branching and joining of the Tsushima Current around the Oki Islands, based on ADCP and CTD measurements carried out in June 1990 by the quadrireciprocal method (Katoh, 1988). The volume transport of the northeastward current northwest of the Izumo Coast was about 2 Sv. The triple-branch structure of the Tsushima Current was obscure there. This northeastward current divided into the eastward and northward currents, with volume transports of 0.5 Sv and 1.5 Sv, respectively, at the west entrance of the Oki Strait. Most of the first branch of the Tsushima Current seemed to be separated again from the other confluent branches and to pass through the Oki Strait as this eastward current. The northward current was composed of the second and the third branches of the Tsushima Current. It detoured the Oki Islands, and almost all of it returned south to the Tajima Coast. In the vicinity of the Tajima Coast, the eastward current was abruptly strengthened through the confluence of the southward one which was originated from the northward current west of the Oki Islands. This showed that the first branch finally joined the compound of the second and the third branches detouring the Oki Islands. Between the Oki Strait and the Tajima Coast, the two-layer structure of currents was clearly found.     

A description of short period temperature fluctuations in the upper ocean

Dynamical properties of short-period temperature fluctuations are studied. Water temperature was measured continuously at several depths at the following stations: at 38°29.5′N, 141°35.8′E (100 m depth) on the continental shelf off Miyagi Prefecture in the summer of 1967, at 35°01.8′N, 139°0.8.5′E (100 m depth) in Sagami Bay in the summer of 1968, and at 32°32.2′N, 129°53.7′E (74 m depth) in Tachibana Bay in the summer of 1970. These measurements were made with a thermistor array laid down from the R. V.Tanseimaru (Ocean Research Institute, University of Tokyo) which was fixed with bow and stern anchors. Significant temperature fluctuations found at the first and the third stations are thought to be due to first mode internal waves having amplitude 3 to 5 m and period 5 to 20 minutes. The wave length of the waves is estimated to be 25 m to 400 m from the observed density structure. At the second station, we found second-mode internal waves. The period, amplitude and wave length of the waves are about 30 minutes, 1.3 m and 600 m, respectively. In all cases, the spectral density of the temperature fluctuations decreases with increase in frequency. However, the decrease obey neither the ?3 power law nor the ?5/3 power law. Coherences in the temperature fluctuations between two depths of measurement in the seasonal thermocline are significantly high in the range of frequencies lower than the local Brunt-Väisälä frequency, but are low in the higher frequency range. At the first and the third stations, the difference in the level of coherences between the lower frequencies and the higher frequencies are large. Phase differences between two depths in the thermocline are small in the lower frequency range. This suggests that the first-mode internal waves are predominant over higher-mode internal waves and over other disturbances.     

Transport of copper from the Bering Sea to the northwestern North Pacific

Dissolved copper concentrations in surface waters of the Bering Sea ranged from 106 to 882 ngl^–1. Higher concentrations were found in continental shelf waters. In the northwestern North Pacific dissolved copper ranged from 54 to 140 ngl^–1. Particulate copper concentrations varied regionally and seasonally from 6 to 79 ngl^–1. Regionally averaged particulate copper concentrations decreased from 175 to 33g g^–1 against an increase in suspended materials because of the dilution effects of biological fractions. Apparent sporadic increases in copper concentrations were found in the mixing area of the Kuroshio and the Oyashio waters. The feature is attributed to the lateral distribution of different water types rather than to the upwelling of deeper waters by eddies. In the same area west of 160E, waters with high concentrations of dissolved copper (96±9 ngl^–1) were found. Their origin appears to be the continental shelf of the Bering Sea. In spite of intensive biological activity, a considerable fraction of copper added to shelf waters was transported to the area off Japan via the circulation in the Bering Sea and the Oyashio current.     

Bachelor-modon type eddies and isolated eddies near the coast on anf-plane

The behavior of isolated meso-scale eddies near the coastal boundary is studied by numerical experiments based on the quasi-geostrophic equation in a basin on an f-plane. First, Bachelor-modon type eddies are investigated as an idealized model of isolated eddies close to the wall. The first-mode Bachelor-modon type eddy is found to be robust enough to recover its original form even after it turns a corner of the basin. In contrast, the second mode is unstable; it tends to move away from the wall and finally splits into two eddies proceeding in opposite directions along the wall. An initially Gaussian eddy a little distant from the boundary interacts with a Bachelor-modon type eddy translating along the boundary, sometimes resulting in vortex merging and pairing just as in the head-on collision of two modons on a beta-plane. It is found that an initially Gaussian eddy located moderately close to the coast rapidly settles down to a steadily translating eddy, which can be approximated remarkably well by a first-mode Bachelor-modon type eddy not only in appearance but also in translation velocity within an error of about 20%.     

Estimating the geostrophic velocity obtained by HF radar observations in the upstream area of the Kuroshio

A method to extract geostrophic current in the daily mean HF radar data in the Kuroshio upstream region is established by comparison with geostrophic velocity determined from the along-track altimetry data. The estimated Ekman current in the HF velocity is 1.2% (1.5%) and 48° (38°)-clockwise rotated with respect to the daily mean wind in (outside) the Kuroshio. Furthermore, additional temporal smoothing is found necessary to remove residual ageostrophic currents such as the inertial oscillation. After removal of the ageostrophic components, the HF geostrophic velocity agrees well with that from the altimetry data with rms difference 0.14 (0.12) m/s in (outside) the Kuroshio.     

Changing grading of soil: effect on critical states

Examples of situations are presented where the grading of a soil changes during its lifetime either by crushing of particles leading to an increase of fine material or by slow transport of fine particles with seepage leading to a decrease of fine material. Such grading changes influence the basic constitutive properties of the soil, in particular properties such as critical states which are dependent on the available range of densities of packing. Discrete element modelling is used to show the dependence of critical state conditions on grading and the way in which the particle assembly seeks out new critical state conditions as the grading changes.