Sources and sinks of sea salt in a newfoundland blanket bog

Over an oceanic peatland, the concentration of Na in fog averaged 38.1 mgl^?1 compared with 1.8 mgl^?1 in rain, resulting in a significant flux of mineral elements to the surface. Between 16 May and 20 June 1990 the average mass flux of Na to the bog surface by fog, rain, and dry deposition was 21.9, 10.4 and 7.0 mg m^?2 d^?1. There was little long-term storage of Na within the peatland system, where Na losses measured in stream runoff averaged 34.8 mg m² d^?1, and deep groundwater losses 4 mg m^?2 d^?1. Calcium and Mg were preferentially retained in the organic soil, whereas K was relatively mobile. Potassium tended to become concentrated in the unsaturated zone. Stream runoff had a consistently higher pH than groundwater, corresponding to higher Ca and Mg concentrations, which may have been from mineral sources in the headwater ponds. Otherwise, the stream water chemistry was closely related to groundwater in the upper layers of the peat deposit.     

TREK: A cosmic-ray experiment on the Russian space station MIR

The goals of the TREK experiment, now in place on the MIR Space Station, are to resolve and measure the composition of both odd-Z and even-Z cosmic-ray nuclei up to uranium, to measure the isotopic composition of Fe-group nuclei, and to search for transuranic nucleic and exotic particles such as strangelets. To collect tracks of ultraheavy cosmic rays, exterior panels holding an array of BP-1 phosphate glass 1.2m² in area and 16 plates thick are now mounted outside the Kvant-2 module on MIR. Heaters and relays regulate the temperature of the glass at 25°±5°C. The detectors will record 10³ cosmic-ray tracks withZ50 during 2.5 years. An interior panel consisting of an array 0.09 m² in area and 32 plates thick and mounted on the inside wall of the Soyuz spacecraft (attached to the Space Station) will collect tracks of about 13000 Fe and 500 Ni nuclei.     

Dating megafaunal extinction on the Pleistocene Darling Downs,eastern Australia: the promise and pitfalls of dating as a test of extinction hypotheses

A key to understanding Late Pleistocene megafaunal extinction dynamics is knowledge of megafaunal ecological response(s) to long-term environmental perturbations. Strategically, that requires targeting fossil deposits that accumulated during glacial and interglacial intervals both before and after human arrival, with subsequent palaeoecological models underpinned by robust and reliable chronologies. Late Pleistocene vertebrate fossil localities from the Darling Downs, eastern Australia, provide stratigraphically-intact, abundant megafaunal sequences, which allows for testing of anthropogenic versus climate change megafauna extinction hypotheses. Each stratigraphic unit at site QML796, Kings Creek Catchment, was previously shown to have had similar sampling potential, and the basal units contain both small-sized taxa (e.g., land snails, frogs, bandicoots, rodents) and megafauna. Importantly, sequential faunal horizons show stepwise decrease in taxonomic diversity with the loss of some, but not all, megafauna in the geographically-small palaeocatchment. The purpose of this paper is to present the results of our intensive, multidisciplinary dating study of the deposits (>40 dates). Dating by means of accelerator mass spectrometry (AMS) ¹⁴C (targeting bone, freshwater molluscs, and charcoal) and thermal ionisation mass spectrometry U/Th (targeting teeth and freshwater molluscs) do not agree with each other and, in the case of AMS ¹⁴C dating, lack internal consistency. Scanning electron microscopy and rare earth element analyses demonstrate that the dated molluscs are diagenetically altered and contain aragonite cements that incorporated secondary young C, suggesting that such dates should be regarded as minimum ages. AMS ¹⁴C dated charcoals provide ages that occur out of stratigraphic order, and cluster in the upper chronological limits of the technique (～40–48 ka). Again, we suggest that such results should be regarded as suspicious and only minimum ages. Subsequent OSL and U/Th (teeth) dating provide complimentary results and demonstrate that the faunal sequences actually span ～120–83 ka, thus occurring beyond the AMS ¹⁴C dating window. Importantly, the dates suggest that the local decline in biological diversity was initiated ～75,000 years before the colonisation of humans on the continent. Collectively, the data are most parsimoniously consistent with a pre-human climate change model for local habitat change and megafauna extinction, but not with a nearly simultaneous extinction of megafauna as required by the human-induced blitzkrieg extinction hypothesis. This study demonstrates the problems inherent in dating deposits that lie near the chronological limits of the radiocarbon dating technique, and highlights the need to cross-check previously-dated archaeological and megafauna deposits within the timeframe of earliest human colonisation and latest megafaunal survival.     

Sedimentological evaluation of general circulation model simulations for the “greenhouse” Earth: Cretaceous and Jurassic case studies

Conceptual climate models, based on the workings of the present-day climate system, provided a first-order approach to ancient climate systems. They are potentially very subjective in character. Their main drawback was that they involved the relocation of continents beneath a stable atmospheric circulation modelled upon that of the present. General circulation models (GCMs) use the laws of physics and an understanding of past geography to simulate climatic responses. They are objective in character. However, they require super computers to handle vast numbers of calculations. Nonetheless it is now possible to compare results from different GCMs for a range of times and over a wide range of parameterisations. GCMs are currently producing simulated climate predictions which compare favourably with the distributions of climatically sensitive facies (e.g. coals, evaporites and palaeosols). They have been used effectively in the prediction of oceanic upwelling sites and the distribution of petroleum source-rocks and phosphorites. Parameterisation is the main weakness in GCMs (e.g. sea-surface temperature, orography, cloud behaviour). Sensitivity experiments can be run on GCMs which simulate the effects of Milankovitch forcing and thus provide insights into possible patterns of climate change both globally and locally (i.e. provide predictions that can be evaluated against the rock record). Future use of GCMs could be in the forward modelling of sequence stratigraphic evolution and in the prediction of the diagenetic characteristics of reservoir units in frontier exploration areas. The sedimentary record provides the only way that GCMs may themselves be evaluated and this is important because these same GCMs are being used currently to predict possible changes in future climate.     

The energetics of interaction between oxygen vacancies in sillimanite: A model for the mullite structure

A microscopic model is introduced to discuss the modulated structure of mullite. The oxygen vacancies of this aluminosilicate are known to play a central role. In particular, a single vacancy strongly orders its surrounding Al/Si tetrahedral sites. It is shown in this work that if two oxygen vacancies approach too closely to one another, their Al/Si dressing overlap. This situation results in repulsive interaction. The field of interaction between the vacancies is estimated with the use of an atomistic computer simulation. We use a Bragg-Williams type of theory to dicuss the ordering pattern of the vacancies. Due to frustration between the two dominant repulsive interactions, our model predicts a modulated phase transition in agreement with observation.     

Spatially enabled bushfire recovery

Over the last decade growth in spatial information use for disaster management has been considerable. Maps and spatial data are now recognized as critical elements in each of the four phases of disaster management: mitigation, preparedness, response, and recovery. The use of spatial information to support the phases of mitigation, preparedness and response to bushfires is widely understood. Less attention, however, has been given to the role of spatial information in the recovery. Moreover, the application of the spatially enabled society concept to bushfire recovery has not been explored. This paper explores the role that spatial information plays and could play in the recovery phase of a bushfire disaster. The bushfires in Victoria, Australia that took place during February 2009 are used as the primary case study. It is found that: Spatial information for recovery requires a pre-existing infrastructure; Spatial capacity must be developed across agencies dealing with recovery; Spatially enabled address and parcel information are the key dataset required to support all recovery tasks; Spatial integration of bushfire datasets (spread and intensity) require linking with planning regimes, and Spatial information that is volunteered could be incorporated into recovery activities.     

Estimates of groundwater discharge to a coastal wetland using multiple techniques: Taylor Slough, Everglades National Park, USA

Quantifying water exchange between a coastal wetland and the underlying groundwater is important for closing water, energy and chemical budgets. The coastal wetlands of the Florida Everglades (USA) are at the forefront of a large hydrologic restoration project, and understanding of groundwater/surface-water interactions is needed to comprehend the effects of the project. Four independent techniques were used to identify water exchange at varying spatial and temporal scales in Taylor Slough, Everglades National Park. The techniques included a water-budget study and measurements of hydraulic head gradients, geochemical tracers, and temperature. During the 18-month study, the four methods converged as to the timing of groundwater discharge, typically between June and September, contemporaneous with the wet season and increasing surface-water levels. These results were unexpected, as groundwater discharge was predicted to be greatest when surface-water levels were low, typically during the dry season. Either a time lag of 1?C5?months in the response of groundwater discharge to low surface-water levels or precipitation-induced groundwater discharge may explain the results. Groundwater discharge was a significant contributor (27?%) to the surface water in Taylor Slough with greater rates of discharge observed towards the coastline in response to seawater intrusion.     

Petrogenesis of the Greenhills Complex,Southland, New Zealand: magmatic differentiation and cumulate formation at the roots of a Permian island-arc volcano

A Permian (~265 Ma) intrusive complex which formed as a magmatic feeder reservoir to an immature island-arc volcano is fortuitously exposed in southern New Zealand. Known as the Greenhills Complex, this intrusion was emplaced at shallow crustal levels and consists of two layered bodies which were later intruded by a variety of dykes. Cumulates, which include dunite, olivine clinopyroxenite, olivine gabbro, and hornblende gabbro-norite, are related products of parent-magma fractionation. Both primary (magmatic) and secondary platinum-group minerals occur within dunite at one locality. Using the composition of cumulus minerals, mafic dykes and melt inclusions, we have determined that the parent magmas of the complex were hydrous, low-K island-arc tholeiites of ankaramitic affinities. Progressive magmatic differentiation of this parent magma generated fractionated melt of high-alumina basalt composition which is now preserved only as dykes which cut the Complex. Field evidence and cumulus mineral profiles reveal that the magma chambers experienced turbulent magmatic conditions during cumulate-rock formation. Recharge of the chambers by primitive magma is likely to have coincided with eruption of residual melt at the surface. Similar processes are inferred to account for volcanic-rock compositions in other parts of this arc terrane and in modern island-arc systems.