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Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans in sediments from Hong Kong 总被引:4,自引:0,他引:4
Müller JF Gaus C Prange JA Päpke O Poon KF Lam MH Lam PK 《Marine pollution bulletin》2002,45(1-12):372-378
Concentrations of 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were determined in 14 sediment samples collected from four sites in the Mai Po Marshes Nature Reserve (within a RAMSAR Site) and from another six sites in Victoria Harbour and along the Hong Kong coastline. Elevated levels of PCDDs, and particularly OCDD, were detectable in all samples collected from the Mai Po Marshes and five of the six sites. In contrast to PCDDs, PCDFs were mainly found in sediment samples collected from industrial areas (Kwun Tong and To Kwa Wan) in Victoria Harbour. PCDD/F levels and congener profiles in the samples from the Mai Po Marshes Nature Reserve in particular show strong similarities to those reported in studies which have attributed similar elevated PCDD concentrations to nonanthropogenic PCDD sources. 相似文献
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月相反映着日地和月地两直线间的特定交角变化。不同的月相就是表示在一个朔望月内的不同时期。本文重点讨论朔、望、上、下弦四个特定的月相对唐山余震序列的影响。发现应变能释放的峰值在朔、望、上、下弦附近,较大的余震起伏明显受月相的调制和触发作用。 相似文献
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地磁低点位移异常类型特征与地震活动 总被引:2,自引:0,他引:2
通过对大量的地磁低点位移异常震例研究,结果表明: ① 地磁低点位移异常的形态、空间展布有明显的地区特征。异常大致可分为: 大范围异常和区域性异常二大类, 还可细分为 5个类型 ; ② 地磁低点位移异常与我国的地质活动构造有较密切的联系。 异常范围的大小、形态与异常所在地区的活动构造的规模、展布形态特征,以及这一地区即将发生的地震强度有关。 相似文献
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讨论了一些有关地壳均衡概念的模型。业已证明 ,这些模型既不能用以正确评估地球的平衡状态 ,也不能用以解释构造成因。介绍一种新的地壳均衡模型 ,它与地球的某一种旋转方式相适应。地球体与球的偏差 ,被用来作为地球平衡的判据。地球被认为是在偏差趋近于零的那些点上得到平衡的。地球体与球体之间标志的差异 ,是由地球外壳中地质作用的方向所确定的。所提出的是大地地壳均衡模型 ,是地壳中构造形成新旋转假说的基础。 相似文献
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Iron sulfide was synthesized by reacting aqueous solutions of sodium sulfide and ferrous chloride for 3 days. By X-ray powder diffraction (XRPD), the resultant phase was determined to be primarily nanocrystalline mackinawite (space group: P4/ nmm) with unit cell parameters a = b = 3.67 Å and c = 5.20 Å. Iron K-edge XAS analysis also indicated the dominance of mackinawite. Lattice expansion of synthetic mackinawite was observed along the c-axis relative to well-crystalline mackinawite. Compared with relatively short-aged phase, the mackinawite prepared here was composed of larger crystallites with less elongated lattice spacings. The direct observation of lattice fringes by HR-TEM verified the applicability of Bragg diffraction in determining the lattice parameters of nanocrystalline mackinawite from XRPD patterns. Estimated particle size and external specific surface area (SSAext) of nanocrystalline mackinawite varied significantly with the methods used. The use of Scherrer equation for measuring crystallite size based on XRPD patterns is limited by uncertainty of the Scherrer constant (K) due to the presence of polydisperse particles. The presence of polycrystalline particles may also lead to inaccurate particle size estimation by Scherrer equation, given that crystallite and particle sizes are not equivalent. The TEM observation yielded the smallest SSAext of 103 m2/g. This measurement was not representative of dispersed particles due to particle aggregation from drying during sample preparation. In contrast, EGME method and PCS measurement yielded higher SSAext (276-345 m2/g by EGME and 424 ± 130 m2/g by PCS). These were in reasonable agreement with those previously measured by the methods insensitive to particle aggregation. 相似文献
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