Variability in the nutritional value of the major copepods in Cape Cod Bay (Massachusetts, USA) with implications for right whales

The North Atlantic right whale, a seriously endangered species, is found in Cape Cod Bay (Massachusetts, USA) during the winter and early spring. During their residency in these waters, these whales are frequently observed feeding. This study evaluated spatial and temporal changes in the chemical composition (carbon weight and C/N ratio) of the food resource targeted by the right whales in Cape Cod Bay. The three taxa measured (Centropages typicus, Pseudocalanus spp., and Calanus finmarchicus) had highly variable chemical compositions resulting from the different life strategies and from fluctuations in their surrounding environment. The impact of seasonal variability in the energy densities of the food resource of right whales was calculated and compared to the energetic requirements of these whales. Calculations indicated that differences in the nutritional content of the zooplankton prey in Cape Cod Bay could have a considerable effect on the nutrition available to the right whales. Therefore, it is likely that using more precise estimates of the energetic densities of the prey of right whales would lead to a re‐evaluation of the adequacy of the food resource available to these whales in the North Atlantic.     

Phase transition in K2Cd2(SO4)3: Order parameter and microscopic distortions

The transition from P2₁3(T ⁴) to P2₁2₁2₁(D ₂ ⁴ ) in the langbeinite K₂Cd₂(SO₄)₃ has been analyzed using group theoretical methods and previously published structural data above and below the transition. We find that because the transition is strongly first-order, the primary-order parameter has relatively large values at the transition temperature, and higher order terms which involve the order parameter, the strain, and the coupling of the two must be included in the Landau expansion for the free energy. Complex displacements occur at the transition for all atoms of the unit cell, but these displacements can be resolved into contributions which can be shown from symmetry considerations to transform as the _{2 3} irrep of P2 ₁ 3(T ⁴) as well as contributions from symmetry-preserving displacements which transform under the irrep ₁. Therefore, the transition is not a simple one and involves sulfate rotations and cadmium and potassium ion displacements.     

A new model for X-ray emission from NGC 4151

We present an analysis of the reported spectral features of NGC 4151 in X-rays. It is shown that the origin of X-rays from the source is inconsistent with a single production mechanism. We suggest a new two-component model in which soft X-rays arise from the black-body emission of a tiny hot nucleus withT2×10⁷ K and the hard X-ray photons are generated in an extended region by inverse Compton scattering of electrons with the infrared photons.     

Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

S-wave Velocity Models in the Scotia Sea Region, Antarctica, from Nonlinear Inversion of Rayleigh Waves Dispersion

—More than 60 events recorded by four recently deployed seismic broadband stations around Scotia Sea, Antarctica, have been collected and processed to obtain a general overview of the crust and upper mantle seismic velocities.¶Group velocity of the fundamental mode of Rayleigh waves in the period between 10 s to 30–40 s is used to obtain the S-wave velocity versus depth along ten different paths crossing the Scotia Sea region. Data recorded by two IRIS (Incorporated Research Institutions for Seismology) stations (PMSA, EFI) and the two stations of the OGS-IAA (Osservatorio Geofisico Sperimentale—Instituto Antarctico Argentino) network (ESPZ, USHU) are used.¶The Frequency-Time Analysis (FTAN) technique is applied to the data set to measure the dispersion properties. A nonlinear inversion procedure, "Hedgehog," is performed to retrieve the S-wave velocity models consistent with the dispersion data.¶The average Moho depth variation on a section North to South is consistent with the topography, geological observations and Scotia Sea tectonic models.¶North Scotia Ridge and South Scotia Ridge models are characterised by similar S-wave velocities ranging between 2.0 km/s at the surface to 3.2 km/s to depths of 8 km/s. In the lower crust the S-wave velocity increases slowly to reach a value of 3.8 km/s. The average Moho depth is estimated between 17 km to 20 km and 16 km to 19 km, respectively, for the North Scotia Ridge and South Scotia Ridge, while the Scotia Sea, bounded by the two ridges, has a faster and thinner crust, with an average Moho depth between 9 km and 12 km.¶On other paths crossing from east to west the southern part of the Scotia plate and the Antarctic plate south of South Scotia Ridge, we observe an average Moho depth between 14 km and 18 km and a very fast upper crust, compared to that of the ridge. The S-wave velocity ranges between 3.0 and 3.6 km/s in the thin (9–13 km) and fast crust of the Drake Passage channel. In contrast the models for the tip of the Antarctic Peninsula consist of two layers with a large velocity gradient (2.3–3.0 km/s) in the upper crust (6-km thick) and a small velocity gradient (3.0–4.0) in the lower crust (14-km thick).     

Effect of heat treatment on tourmaline from Brazil

The crystal-chemical behaviour of tourmaline from Araçuaí, Minas Gerais state, Brazil, when subjected to heating in air atmosphere has been studied by several techniques, including EMPA, UV–Vis, TGA, and Mössbauer spectroscopy. The tourmaline samples are typically intermediate members of the elbaite-schorl series. The origin of colour and of its change after treatment has been discussed in terms of local disorder, presence of metal transition elements, oxidation of ferrous iron at the octahedral site, and simultaneous trap of the excess electron. These findings may be used to enhance the colour in tourmaline crystals or generate wanted colour changes.