Präparationstechnik für Aufbereitungsprodukte zur quantitativen erzmikroskopischen Untersuchung

Zusammenfassung Mikroskopische Anschliffe feinkörniger Aufbereitungsprodukte können nur dann quantitativ ausgewertet werden, wenn ihre Schliffqualität so hoch ist, daß auch feinste Partien sicher zu bestimmen sind. Daneben muß gewährleistet sein, daß die an der Schliffoberfläche erfaßten Körner die tatsächliche Verteilung der Mineralien der Probe repräsentieren. Diese Forderung kann nur durch zweckentsprechende Präparation, die dem eigentlichen Schleif- und Polierprozeß vorausgeht, erfüllt werden. Als günstigste Lösung erscheint es, das Korngemisch exakt als Einkornschicht zu präparieren und anschließend wie Stückproben anzuschleifen. Die Schliffe können dann nach den gleichen statistischen Gesetzmäßigkeiten ausgewertet werden, wie sie bei praktisch zweidimensionalen Dünnschliffen oder bei Streupräparaten nichtopaker Korngemische vorliegen.

---

Quantitative examination of fine-grained ore dressing products depends on good quality of the sections and on whether very small particles and areas of grains can be determined. Besides, it must absolutely be guaranteed that the grains at the section surface represent the actual distribution of the minerals in the sample. This condition can only be realized by suitable grain mounting prior to grinding and polishing. The best method for this purpose appears to be the preparation of a mono-grain layer. The polished sections can then be examined according to the same statistical laws as two-dimensional thin sections or immersion-liquid slides of non-opaque mixtures of grains.

---

---

Mitteilung Nr. 141 aus dem Forschungsinstitut für Aufbereitung der Deutschen Akademie der Wissenschaften zu Berlin, Freiberg (Sachsen). Direktor: Prof. Dr.-Ing. habil. H. Kirchberg.     

Composition-Induced Variations in SIMS Instrumental Mass Fractionation during Boron Isotope Ratio Measurements of Silicate Glasses

An analytical artefact is reported here related to differences in instrumental mass fractionation between NIST SRM glasses and natural geological glasses during SIMS boron isotope determinations. The data presented demonstrated an average 3.4‰ difference between the NIST glasses and natural basaltic to rhyolitic glasses mainly in terms of their sputtering-induced fractionation of boron isotopes. As no matrix effect was found among basaltic to rhyolitic glasses, instrumental mass fractionation of most natural glass samples can be corrected by using appropriate glass reference materials. In order to confirm the existence of the compositionally induced variations in boron SIMS instrumental mass bias, the observed offset in SIMS instrumental mass bias has been independently reproduced in two laboratories and the phenomenon has been found to be stable over a period of more than one year. This study highlights the need for a close match between the chemical composition of the reference material and the samples being investigated.     

Solar irradiance modulation by active regions during 1980

The solar irradiance modulation due to active regions during 1980 has been investigated in detail. Specifically, we estimate the uncertainties caused by ground-based data used as input in the modeling effort, and by our currently incomplete knowledge of the proper parameters that describe the angular variation of sunspot and facular contrasts. We conclude that the most significant uncertainties are due to errors in area measurements and, possibly, varying spot and facular brightness. A standard model for later use is derived by a best-fit technique of the currently available ACRIM irradiance data and the predictions of our models with appropriately varied parameters. Finally, we compute the expected irradiance for the entire year of 1980.NRC Senior Research Associate on leave from the Joint Institute for Laboratory Astrophysics and the Astro-Geophysics Department, University of Colorado at Boulder, Colo., U.S.A.     

Cyclic sedimentation and climatically caused sea-level changes in the Late Palaeozoic of Central Europe

Significant short-term fluctuations are characteristic of geological history since Precambrian times. Only the younger Quaternary climatic fluctuations are known in more detail as a result of a high grade time resolution. Climatic change can also be postulated with respect to older, cold periods during which polar inland ice sheets developed. From a discussion of endogene and exogene interpretations it is shown that global climatic changes, and the sea-level changes induced by them, as well as changes in the position and extent of climatic zones throughout the world provide a control mechanism for sedimentation which is consistent with cyclic sedimentation in Late Palaeozoic times, and also if the basin subsides non-cyclically. The model allows an explanation of the development of the Permo-Carboniferous sedimentary cycles without numerous short-term vertical oscillations of the earth's crust. In reality, exogene and endogene controls on sedimentation act together in great variety of combinations.     

The Cloud Ice Mountain Experiment (CIME) 1998: experiment overview and modelling of the microphysical processes during the seeding by isentropic gas expansion

The second field campaign of the Cloud Ice Mountain Experiment (CIME) project took place in February 1998 on the mountain Puy de Dôme in the centre of France. The content of residual aerosol particles, of H₂O₂ and NH₃ in cloud droplets was evaluated by evaporating the drops larger than 5 μm in a Counterflow Virtual Impactor (CVI) and by measuring the residual particle concentration and the released gas content. The same trace species were studied behind a round jet impactor for the complementary interstitial aerosol particles smaller than 5 μm diameter. In a second step of experiments, the ambient supercooled cloud was converted to a mixed phase cloud by seeding the cloud with ice particles by the gas release from pressurised gas bottles. A comparison between the physical and chemical characteristics of liquid drops and ice particles allows a study of the fate of the trace constituents during the presence of ice crystals in the cloud.In the present paper, an overview is given of the CIME 98 experiment and the instrumentation deployed. The meteorological situation during the experiment was analysed with the help of a cloud scale model. The microphysics processes and the behaviour of the scavenged aerosol particles before and during seeding are analysed with the detailed microphysical model ExMix. The simulation results agreed well with the observations and confirmed the assumption that the Bergeron–Findeisen process was dominating during seeding and was influencing the partitioning of aerosol particles between drops and ice crystals. The results of the CIME 98 experiment give an insight on microphysical changes, redistribution of aerosol particles and cloud chemistry during the Bergeron–Findeisen process when acting also in natural clouds.     

Behaviour of H2O2, NH3, and black carbon in mixed-phase clouds during CIME

We investigated the partitioning of trace substances during the phase transition from supercooled to mixed-phase cloud induced by artificial seeding. Simultaneous determination of the concentrations of H₂O₂, NH₃ and black carbon (BC) in both condensed and interstitial phases with high time resolution showed that the three species undergo different behaviour in the presence of a mixture of ice crystals and supercooled droplets. Both H₂O₂ and NH₃ are efficiently scavenged by growing ice crystals, whereas BC stayed predominantly in the interstitial phase. In addition, the scavenging of H₂O₂ is driven by co-condensation with water vapour onto ice crystals while NH₃ uptake into the ice phase is more efficient than co-condensation alone. The high solubility of NH₄⁺ in the ice could explain this result. Finally, it appears that the H₂O₂–SO₂ reaction is very slow in the ice phase with respect to the liquid phase. Our results are directly applicable for clouds undergoing limited riming.     

Desalinization of running waters: III. Changes in the structure of diatom assemblages caused by a decreasing salt load and changing ion spectra in the river Wipper (Thuringia, Germany)

Salt-loaded effluents were introduced into the river Wipper during the mining period for almost a century. Beginning with the year 1990, the waste water load was strongly reduced due to the termination of the potash industry. Prior to 1990, monthly means of the chloride concentrations at times exceeded 6,000 mg l⁻¹ in the strongly polluted sections. Maximum concentrations reached twice these values. Up to 1998, mean annual chloride concentrations decreased to values below 2,000 mg l⁻¹. This led to more balanced fluctuations in salinity which had been pronounced before, depending on discharge and short-term changes in production. Similarly, the physiologically adverse ion conditions improved due to decrasing potassium and increasing calcium proportions.

In 1963/64, 1986 and 1998, samples of epilithic, epiphytic and epipsammic diatoms were taken at locations of different salinities along the river and examined for the effects of the salinization on the structure of the diatom assemblages. These structures changed in dependence on salinity. Increasing salt concentrations coincided with decreasing oligohalophilic and increasing mesohalophilic and polyhalophilic species numbers. Above a chloride concentration of about 3,000 mg l⁻¹, the proportion of the latter exceed that of the former (halobion index > 50). Corresponding to different conditions of salinization along the river, characteristic diatom assemblages occur differring from each other and which are specific for the river section. Spring and autumn aspects of the diatom assemblages show also salt-dependent differences. The assemblages found in 1998 after decrease of salinization have changed markedly in comparison to those from 1963/64 and 1986. Halobiontic species predominating formerly occurred only occasionally or not at all. They were replaced by oligohalobic-indifferent forms.

An ecological assessment of the changes was performed based on the halobion index calculated from all the samples. For the strongly salinized section of the river Wipper, a shift from -mesohalobic/polyhalobic conditions in 1963/64 and 1986 to -oligohalobic/β-mesohalobic conditions in 1998 was found. However, constant -oligohalobic conditions are still not given. With regard to the transition from -oligohalobic (limnetic) to β-mesohalobic (brackish) conditions, a maximum chloride concentration of 600 mg l⁻¹ was found. To guarantee -oligohalobic conditions, a maximum chloride concentration of 400 mg l⁻¹ should not be exceeded.