Evidence for a seismic activity mainly constituted of hybrid events at Cayambe volcano,Ecuador. Interpretation in a iced-domes volcano context

The high activity level of Hybrid Events (HE) detected beneath the Cayambe volcano since 1989 has been more thoroughly investigated with data from a temporary array. The unusual HE spectral content allows separating a high-frequency signal riding on a low-frequency one, with a probable single source. HEs are interpreted as high frequency VT events, produced by the interaction between magmatic heat and an underground water system fed by thaw water from the summital glacier, which trigger simultaneous low-frequency fluid resonance in the highly fractured adjacent medium. Pure VTs are interpreted as ‘aborted’ HEs occurring probably in the oldest and coldest part of the volcano complex. To cite this article: B. Guillier, J.-L. Chatelain, C. R. Geoscience 338 (2006).     

Impact of nitrogenous fertilizers on carbonate dissolution in small agricultural catchments: Implications for weathering CO2 uptake at regional and global scales

The goal of this study was to highlight the occurrence of an additional proton-promoted weathering pathway of carbonate rocks in agricultural areas where N-fertilizers are extensively spread, and to estimate its consequences on riverine alkalinity and uptake of CO₂ by weathering. We surveyed 25 small streams in the calcareous molassic Gascogne area located in the Garonne river basin (south-western France) that drain cultivated or forested catchments for their major element compositions during different hydrologic periods. Among these catchments, the Hay and the Montoussé, two experimental catchments, were monitored on a weekly basis. Studies in the literature from other small carbonate catchments in Europe were dissected in the same way. In areas of intensive agriculture, the molar ratio (Ca + Mg)/HCO₃ in surface waters is significantly higher (0.7 on average) than in areas of low anthropogenic pressure (0.5). This corresponds to a decrease in riverine alkalinity, which can reach 80% during storm events. This relative loss of alkalinity correlates well with the content in surface waters. In cultivated areas, the contribution of atmospheric/soil CO₂ to the total riverine alkalinity (CO_{2 ATM-SOIL}/HCO₃) is less than 50% (expected value for carbonate basins), and it decreases when the nitrate concentration increases. This loss of alkalinity can be attributed to the substitution of carbonic acid (natural weathering pathway) by protons produced by nitrification of N-fertilizers (anthropogenic weathering pathway) occurring in soils during carbonate dissolution. As a consequence of these processes, the alkalinity over the last 30 years shows a decreasing trend in the Save river (one of the main Garonne river tributaries, draining an agricultural catchment), while the nitrate and calcium plus magnesium contents are increasing.We estimated that the contribution of atmospheric/soil CO₂ to riverine alkalinity decreased by about 7-17% on average for all the studied catchments. Using these values, the deficit of CO₂ uptake can be estimated as up to 0.22-0.53 and 12-29 Tg¹ yr⁻¹ CO₂ on a country scale (France) and a global scale, respectively. These losses represent up to 5.7-13.4% and only 1.6-3.8% of the total CO₂ flux naturally consumed by carbonate dissolution, for France and on a global scale, respectively. Nevertheless, this loss of alkalinity relative to the Ca + Mg content relates to carbonate weathering by protons from N-fertilizers nitrification, which is a net source of CO₂ for the atmosphere. This anthropogenic CO₂ source is not negligible since it could reach 6-15% of CO₂ uptake by natural silicate weathering and could consequently partly counterbalance this natural CO₂ sink.     

Floods and livelihoods: The impact of changing water resources on wetland agro-ecological production systems in the Tana River Delta,Kenya

Wetlands are highly dynamic and productive systems that have been under increased pressure from changes in land use and water management strategies. In Eastern Africa, wetlands provide resources at multiple spatial and temporal levels through farming, fishing, livestock ownership and a host of other ecosystem services that sustain the local economy and individual livelihoods. As part of a broader effort to describe future development scenarios for East African coastal wetlands, this qualitative study focuses on understanding the processes by which river water depletion has affected local food production systems in Kenya's Tana River Delta over the past 50 years, and how this situation has impacted residents’ livelihoods and well-being. Interviews performed in six villages among various ethnic groups, geographical locations and resource profiles indicated that the agro-ecological production systems formerly in place were adapted to the river's dynamic flooding patterns. As these flooding patterns changed, the local population diversified and abandoned or adopted various farming, fishing and livestock-rearing techniques. Despite these efforts, the decrease in water availability affected each subcomponent of the production systems under study, which led to their collapse in the 1990s. Water depletion negatively impacted local human well-being through the loss of food security. The current study provides a detailed account of the dynamics of agro-ecological production systems facing the effects of river water depletion in a wetland-associated environment in Sub-Saharan Africa.     

Early Devensian sediments and palaeovenvironmental evidence from the excavations at the Royal Oak Portal Paddington,West London,UK

This paper discusses the results of the investigation of Pleistocene sediments at the Royal Oak Portal (ROP) site on the new Crossrail scheme near Paddington Station, London. The site was sampled and recorded in May 2011 by archaeologists from Oxford Archaeology commissioned by Crossrail Ltd. The investigation revealed a sedimentary sequence associated with cool climate waterlain deposition towards the edge of the River Westbourne floodplain. During excavation an assemblage of around 100 identifiable large mammal bones was recovered, dating to the Late Pleistocene. The major concentration of bones, from bison and reindeer, was located and excavated from a shallow sequence of sediments. Analysis of the bones indicates that they represent a natural death assemblage, scavenged and subsequently disarticulated, transported by water, exposed and further dispersed and broken by trampling. The site is of regional and national importance because the assemblage derives from a well-constrained geological context, with associated dating evidence suggesting accumulation during the later parts of Marine Isotope Stage (MIS) 5 and continuing within MIS 4. The site is also of significance because it is one of a growing number of recently discovered sites away from the main fluvial archive for the British Middle and Upper Pleistocene. These sites have the potential to add significantly to our understanding of parts of the Pleistocene record that remain difficult to document through the investigation of the more active systems associated with major rivers such as the Thames, Severn or Trent.     

An Observational Study of the Mesoscale Mistral Dynamics

We investigate the mesoscale dynamics of the mistral through the wind profiler observations of the MAP (autumn 1999) and ESCOMPTE (summer 2001) field campaigns. We show that the mistral wind field can dramatically change on a time scale less than 3 hours. Transitions from a deep to a shallow mistral are often observed at any season when the lower layers are stable. The variability, mainly attributed in summer to the mistral/land–sea breeze interactions on a 10-km scale, is highlighted by observations from the wind profiler network set up during ESCOMPTE. The interpretations of the dynamical mistral structure are performed through comparisons with existing basic theories. The linear theory of R. B. Smith [Advances in Geophysics, Vol. 31, 1989, Academic Press, 1–41] and the shallow water theory [Schär, C. and Smith, R. B.: 1993a, J. Atmos. Sci. 50, 1373–1400] give some complementary explanations for the deep-to-shallow transition especially for the MAP mistral event. The wave breaking process induces a low-level jet (LLJ) downstream of the Alps that degenerates into a mountain wake, which in turn provokes the cessation of the mistral downstream of the Alps. Both theories indicate that the flow splits around the Alps and results in a persistent LLJ at the exit of the Rhône valley. The LLJ is strengthened by the channelling effect of the Rhône valley that is more efficient for north-easterly than northerly upstream winds despite the north–south valley axis. Summer moderate and weak mistral episodes are influenced by land–sea breezes and convection over land that induce a very complex interaction that cannot be accurately described by the previous theories.     

Variability of NO2 in different environments at a moderately polluted island over the southwestern Indian Ocean

This work presents the temporal evolution and spatial distribution of nitrogen dioxide (NO₂) measured with the help of passive diffusion tubes in different environments: rural, sub-urban, urban, at La Réunion Island in December 1997 and November 2000 (austral spring), respectively. NO₂ concentration exhibits notable enhancement from 1997 to 2000. For instance, its mean concentration was 16 and 20 μg/m³ in December 1997 and November 2000, respectively, at La Réunion Island, especially in inhabited regions due to increase of local anthropogenic activities, mainly traffic circulation, in the absence of house heating and biomass burning. We also observe a net increase of pollutant levels by a factor two in rural/remote areas within 3 years, which is tied to the extension of inhabited areas and air-flows from enhanced local sources. The increase of atmospheric pollutants is mainly due to enhancement of anthropogenic activities (traffic) since the 1990s at La Réunion Island, which results from a constant increase of population and consequently, from a higher number of vehicles in circulation. Importantly, in cities like Saint-Denis, where traffic network has been subject to notable improvement (e.g. single to double lanes, etc.), pollutant levels exhibit little variability as in temperate continental latitudes. Semi-continuous NO₂ concentration measured in parallel with ozone in November 2000 also showed that daytime photochemical ozone production is influenced by pollutant and precursor (NO₂) levels at Saint-Denis, while nighttime ozone increase is mainly tied to dynamical processes. The November 2000 ozone diurnal pattern is notably different from that observed in September 1995, during which a daytime ozone loss was observed, pointing out that atmospheric conditions have been subject to notable changes, i.e., clean to moderately polluted, within a few years at La Réunion Island. The results presented here point out that the ‘source enhancement effect’ is superimposed on dynamical and photochemical processes to influence pollutants variability and hence atmospheric chemistry, in a quite ‘pristine’ tropical oceanic region.     

Formation of U-depleted rhyolite from a basanite at El Hierro, Canary Islands

Phonolite and trachyte are the felsic magmas of the alkaline magma suites, which characterize the Canary Islands. The October 2011 submarine eruption off El Hierro, the westernmost island, nevertheless, produced a small volume of rhyolitic magma. The rhyolite occurred as highly vesicular, white coloured pumices enveloped in and mingled with darker coloured basanitic pumice. The basanitic pumice is relatively crystal poor with a few euhedral olivines (mostly Fo_77–79), clinopyroxenes and Fe-rich spinels, whereas very rare olivine of same composition is found together with equally rare Fe-sulphide and FeTi-rich oxides in the rhyolite. The Fe–Mg exchange equilibrium in the oxides permits to calculate an equilibrium temperature of 970–890 °C for the rhyolite, in agreement with quartz-melt equilibrium at ca. 930 °C. A striking mineralogical feature of the rhyolite is the presence of rounded to contorted grains of milky quartz, which are xenocrysts incorporated and partly dissolved into the magma. Analyses of residual volatile concentrations in the glasses show that the rhyolite melt was highly degassed, whereas the basanitic glass still has important halogen concentrations. Trace element patterns of the mafic glasses and their elevated incompatible element concentrations are typical of the western Canary Island basanites. In contrast, the trace element composition of the rhyolite shows surprisingly low concentrations for all elements except the most incompatible ones (e.g. Rb, Ba, K and Th). All other measured LILE, HFSE and REE have significantly lower concentration than the basanitic counterpart that can be explained by fractionation of accessory phases (1 % apatite, 1 % sphene and 0.1 % zircon). Surprisingly, low U concentration is presumably related to elevated oxygen fugacity in the rhyolite, causing U to be in a hexavalent state, and fluxing of F-rich gas leading to volatilization of UF₆, known to emanate at low temperature. The results suggest that a gas-rich basanitic melt remobilized a small volume of stagnant rhyolitic melt formed by incorporation of approximately 10 % quartz-rich sediment into a late differentiate of trachytic composition. Sediments at the interface of an old oceanic crust adjacent to a continental shield and younger volcanic island are likely to act as magma traps were sediment assimilation may alter the mantle-derived magma composition. Quartz assimilation thus explains the production of rhyolite magma in a volcanic island characterized by an alkaline magma series from primitive basanites to trachytes.     

Sigmoidal particle density distribution in a subplinian scoria fall deposit

A general expression to describe particle density distribution in tephra fall deposits is essential to improve fallout tephra mass determination and numerical modelling of tephra dispersion. To obtain particle density distributions in tephra fall deposits, we performed high-resolution componentry and particle density analyses on samples from the 2006 subplinian eruption of Tungurahua volcano in Ecuador. Six componentry classes, including pumice and scoria, have been identified in our sample collection. We determined the class of 300 clasts in each 0.5? fractions from ?4.5? to 3.5? and carried out water pycnometry density measurements on selected size fractions. Results indicate that the mean particle density increases with ? up to a plateau of ~2.6?g/cm³ for clasts finer than 1.5?. The density of scoria and pumice increases between ?3 and 1?, while dense particle density is sub-constant with grainsize. We show that the mean particle density ?? of the vesicular fractions is a function of grainsize i (? scale) given by a sigmoidal law: $ \mu (i)={{{K+\beta }} \left/ {{\left( {1+\alpha {e^{-ri }}} \right)}} \right.} $ , where K, ??, ?? and r are constants. These sigmoidal distributions can be used to determine accurately the load of each componentry class and should be applicable to many tephra deposits and for modelling purposes.