Isotopic characteristics of precipitation in Slovenia and Croatia: Comparison of continental and maritime stations

The stable isotopic composition of hydrogen and oxygen (δ²H and δ¹⁸O) and tritium activity (³H) were monitored in monthly precipitation at two continental stations (Ljubljana, Zagreb) and six stations along the eastern Adriatic coasts of Slovenia and Croatia in the period 2001–2003. Mean air temperatures and amount of precipitation were also recorded.

Distinct differences in both meteorological and isotopic data between the continental and maritime stations were observed. Seasonal variations in δ¹⁸O are smaller at the maritime stations than at the continental ones due to smaller seasonal temperature variations. A good correlation between δ¹⁸O and δ²H was obtained for each station, and the local meteoric water lines are close to the Global Meteoric Water Line, with a decreasing trend of slope for the south-Adriatic stations. Good correlations between δ¹⁸O in monthly precipitation and mean monthly air temperature were observed at all stations. The slope of δ¹⁸O vs. T varied between 0.37‰ °C⁻¹ and 0.15‰ °C⁻¹. Mean ³H activity and seasonal variation of ³H activity are smaller at maritime stations than at continental ones. Additionally, ³H activity decreases in the NW–SE direction of the Adriatic coast.

The study of spatial variations over this relatively small area rich in geographical and climatic diversities showed the complexity of the isotopic composition of precipitation and the isotopic data obtained for eight stations, most of them in the karstic area along the Adriatic coast, and gave valuable information for regional hydrological investigations and modelling of isotope variability over the Mediterranean basin.     

Meteotsunami in the Great Lakes and on the Atlantic coast of the United States generated by the “derecho” of June 29–30, 2012

Tsunami-like intense sea-level oscillations, associated with atmospheric activity (meteorological tsunamis), are common in the Great Lakes and on the East Coast of the United States. They are generated by various types of atmospheric disturbances including hurricanes, frontal passages, tornados, trains of atmospheric gravity waves, and derechos. “Derecho” is a rapidly moving line of convectively induced intense thunder storm fronts producing widespread damaging winds and squalls. The derecho of June 29–30, 2012 devastatingly propagated from western Iowa to the Atlantic coast, passing more than 1,000 km and producing wind gusts up to 35 m/s. This derecho induced pronounced seiche oscillations in Lake Michigan, Chesapeake Bay, and along the US Atlantic coast. Sea-level records from the updated National Oceanic and Atmospheric Administration (NOAA) tide gauge network, together with the NOAA and automated surface-observing system air pressure and wind records, enabled us to examine physical properties and temporal/spatial variations of the generated waves. Our findings indicate that the generation mechanisms of extreme seiches in the basins under study are significantly different: energetic winds play the main role in seiche formation in Chesapeake Bay; atmospheric pressure disturbances are most important for the Atlantic coast; and the combined effect of pressure oscillations and wind is responsible for pronounced events in the Great Lakes. The “generation coefficient,” which is the ratio of the maximum observed sea-level height and the height of air pressure disturbance, was used to map the sea-level response and to identify “hot spots” for this particular event, i.e., harbors and bays with amplified seiche oscillations. The Froude number, Fr = U/c, where U is the speed of the atmospheric disturbance and c is the long-wave speed, is the key parameter influencing the water response to specific atmospheric disturbances; the maximum response was found for those regions and disturbance parameters for which Fr ~1.0.     

Fortnightly oscillations observed in the Adriatic Sea

This paper documents the occurrence of strong fortnightly oscillations in the Adriatic Sea frequently observed in the current measurements. For that purpose, we analyzed half-decadal sea level series and long-term currents collected within different parts and layers of the Adriatic Sea. Harmonic analysis and band-pass filter with cutoff periods at 10 and 20 days have been applied to the series. The sea level Mf tide is found to be the only significant tidal constituent over periods between the diurnal and semi-annual ones, having no significant phase variations in the Adriatic Sea. Moreover, the currents on periods between 10 and 20 days could only partially be explained by atmospheric forcing. The fact that they are in-phase with the Mf tide gives a hint on a possible mechanism responsible for the generation of these oscillations. Additionally, these currents are usually strongly amplified during a weakly stratified season, indicating a baroclinic mechanism responsible for the multiplication of the fortnightly currents.     

Using Self-Organising Maps to investigate long-term changes in deep Adriatic water patterns

The paper attempts to document long-term changes in deep Adriatic water patterns by applying the Self-Organising Maps (SOM) method to temperature, salinity, dissolved-oxygen content, orthophosphate and total inorganic nitrogen profiles sampled at a single deep station in the South Adriatic Pit (SAP) over a half century (1957-2009). Seasonality observed in upper layers has been removed by the least-squares fitting of the annual and semi-annual sinusoidal functions. The sensitivity of the SOM to various parameter combinations reveals the importance of temperature, salinity and dissolved oxygen for mapping different water patterns, while nutrients have less influence on quality and applicability of SOM solutions to the extraction of characteristic SAP water profiles. The quality of fit obtained for different combination of the measured parameters introduced to a SOM suggests that the incomplete combinations of input parameters increase an imperfection in the applicability of SOMs to the dataset. Two modes of long-term changes in the SAP obtained by the SOM analyses are discussed with respect to the processes that drive the variability in the area, e.g., the Adriatic-Ionian Bimodal Oscillation: where the first mode is characterised by rapid changes in the transition of SAP water masses, observed before 1980s (less adoptable by the SOMs), and the second mode is characterised by steady transitions (better adoptable by the SOMs), observed in the 1990s and the 2000s. The SOM method is found to have certain advantages when compared to other methods that have previously been used to distinguish the Adriatic water masses, as it does not depend on predefinition of water mass sources and allows for gaps in series.     

Sources,Distribution and Behavior of Major and Trace Elements in a Complex Karst Lake System

Sources and distribution of major and trace elements were investigated in the Plitvice Lakes, a pristine cascade hydrological system of sixteen karst lakes situated in a sparsely populated area of the central Croatia. Water and surface sediment samples from 17 locations, including springs, tributaries and lakes, were analyzed for the content of 22 elements by high-resolution inductively coupled mass spectrometry. Principal component analysis of the collected data set showed that different springs and tributaries displayed distinct multielemental compositions, reflecting primarily the differences in their corresponding geological backgrounds. It was shown that the springs situated in the Upper and Middle Jurassic dolomite bedrock represented the main source of several trace elements, including some toxic metals (Cd, Zn, Ni and Tl), to the Plitvice Lakes system. The concentrations of most of the trace elements (Mn, Fe, Al, Cd, Zn, Cu, Ni, Pb, Co, Cr and Tl) showed decreasing spatial trends in the downstream direction, from sources to the lakes. Such a distribution was interpreted to be a consequence of an efficient removal of the dissolved elements in the lentic parts of the system, mainly by co-precipitation with authigenic calcite and Mn oxides. Nevertheless, most of the elements in the lake sediments were highly correlated with Al, which indicated their prevalent association with terrigenic material. It was shown that the multicascade system of the Plitvice Lakes had an enhanced autopurification efficiency regarding the elimination of most of the trace metals from the aqueous phase.