Palaeoenvironmental significance of Late Permian palaeosols in the South‐Eastern Iberian Ranges,Spain

The Late Permian (Wuchiapingian) Alcotas Formation in the SE Iberian Ranges consists of one red alluvial succession where abundant soil profiles developed. Detailed petrographical and sedimentological studies in seven sections of the Alcotas Formation allow six different types of palaeosols, with distinctive characteristics and different palaeogeographical distribution, to be distinguished throughout the South‐eastern Iberian Basin. These characteristics are, in turn, related to topographic, climatic and tectonic controls. The vertical distribution of the palaeosols is used to differentiate the formation in three parts from bottom to top showing both drastic and gradual vertical upwards palaeoenvironmental changes in the sections. Reconstruction of palaeoenvironmental conditions based on palaeosols provides evidence for understanding the events that occurred during the Late Permian, some few millions of years before the well‐known Permian‐Triassic global crisis.     

Facies distribution of the Lower Cambrian cryptic microbial and epibenthic archaeocyathan-microbial communities, western Anti-Atlas, Morocco

Marine microbial communities recorded in the Moroccan Anti‐Atlas were unaffected across the Neoproterozoic–Cambrian transition. A stromatolite‐dominated consortium was replaced at the beginning of the Atdabanian (ca 20 Myr after the Neoproterozoic–Cambrian boundary) by shelly metazoan and thromboid consortia, which contain the oldest biostratigraphically significant fossils of the Moroccan Cambrian. The associated collapse of microbial mat (stromatolitic) growth appears to coincide with a change from pre‐Atdabanian shallow‐water restricted conditions into Atdabanian deeper, open‐sea conditions. It is postulated that this environmental change led to an episode of improved water circulation over carbonate platform interiors, promoting shelly metazoan immigration into the region. The Tiout/Amouslek lithostratigraphic contact in the early Atdabanian marks the end of an episodically unstable seafloor as suggested by the abundance of slumping and sliding structures, and synsedimentary microfaults and cracks recorded in the underlying Tiout Member. Concurrent with the transition is the occurrence of a network of cryptic fissures and cavities that provided habitats for a coelobiontic chemosynthetic–heterotrophic microbial community composed of stromatolitic crusts, Renalcis–Epiphyton–Girvanella intergrowths, and Kundatia thalli. In the overlying Amouslek Formation, archaeocyathan–thromboid reefs were constrained by substrate stability, water depth and subsidence rate. Four reef geometries are distinguished: (i) patch reefs surrounded by shales, (ii) bioherms in which flank beds intercalate laterally with carbonate and shale inter‐reef sediments, (iii) biostromes or low‐relief structures formed as a result of lateral accretion of patch reefs, and (iv) kalyptrate complexes that nucleated because of a marked tendency for aggregation, and in which patch reefs and bioherms occur stacked together bounded by clay–marl–silt seams.     

CHARACTERIZATION OF FOODS BY INEXACT RULES:THE SEXIA EXPERT SYSTEM

SEXIA is an expert system that uses a new methodological approach to identify foods,particularly oliveoils according to varieties,olive zones and denominations of origin.The methodological approachprovides identification tools,associating a confidence degree or a belief interval to the final hypotheses.The certainty factor and the Dempster-Shaffer theory,with some modifications,have been implementedin SEXIA.The computer can work with 50 chemical parameters whose data have previously beenacquired by the food analyst via a dialogue in the Spanish language.The system has been verified with144 olive oil samples.In this paper some results obtained for distinguishing the Arbequina variety fromother varieties using SEXIA and the BMDP stepwise discriminant analysis program are presented.Finally,promising directions for future research are suggested.     

Strontium-isotope stratigraphy as a constraint on the age of condensed levels: examples from the Jurassic of the Subbetic Zone (southern Spain)

Condensed levels are often characterized by reworked fossils that may lead to incorrect age assessments. Strontium‐isotope stratigraphy is an important chronostratigraphic tool that can be used to verify the biostratigraphic information from condensed beds. This paper describes a study of the ⁸⁷Sr/⁸⁶Sr isotope ratios of 56 belemnite samples collected from 28 stratigraphic sections of the boundary between the Upper Member of the Gavilán Formation and the Zegrí Formation (Pliensbachian, Subbetic Zone). The petrographic and geochemical data (δ¹⁸O, δ¹³C, concentrations of Fe, Mn and Mg, and the Sr/Mn ratio) suggest that the belemnites have preserved their original marine geochemical composition. After plotting the samples in diagrams of ⁸⁷Sr/⁸⁶Sr values against time according to their biostratigraphic age, four different groups (A, B, C and D) were obtained with respect to the reference curve. In groups A and B, the age deduced from the Sr‐isotope ratio is in total or partial agreement, respectively, with the biostratigraphic age; therefore the ⁸⁷Sr/⁸⁶Sr ratio is a good method for the dating, correlation and assessment of biostratigraphic results. In groups C and D, the SIS age and the biostratigraphic age do not coincide. A graphic procedure is presented as a suitable methodology to constrain the age of the samples showing an SIS age that differs from the relative age deduced (by biostratigraphy or stratigraphic correlation) for the bed they were collected in. These situations are interpreted as being the result of reworking of the belemnites (group C) or ammonites (group D) that are included in condensed levels. These condensed levels formed during the maximum flooding event that led to the drowning of the Gavilán carbonate platform. The methodology supplied in this paper represents a valuable tool in identifying reworking processes, improving correlation and constraining biochronostratigraphic results. The values of ⁸⁷Sr/⁸⁶Sr represent a new contribution to the data set of ⁸⁷Sr/⁸⁶Sr ratios for the Pliensbachian.     

A mathematical model for unsteady supercritical flow on a mobile sandy bed

ABSTRACT

Supercritical flow with sediment transport is a common phenomenon in steep rivers. This kind of flow presents features not present in rivers flowing in subcritical conditions. The development of a mathematical model to simulate supercritical flow with sediment transport in sandy rivers is described. The model is based on a numerical scheme for the integral version of the full governing equations and takes into account bottom configurations.     

Internal anatomy of a mixed siliciclastic–carbonate platform: the Late Cenomanian–Mid Turonian at the southern margin of the Spanish Central System

The Late Cenomanian–Mid Turonian succession in central Spain is composed of siliciclastic and carbonate rocks deposited in a variety of coastal and marine shelf environments (alluvial plain–estuarine, lagoon, shoreface, offshore‐hemipelagic and carbonate ramp). Three depositional sequences (third order) are recognized: the Atienza, Patones and El Molar sequences. The Patones sequence contains five fourth‐order parasequence sets, while a single parasequence set is recognized in the Atienza and El Molar sequences. Systems tracts can be recognized both in the sequences and parasequence sets. The lowstand systems tracts (only recognized for Atienza and Patones sequences) are related to erosion and sequence boundary formation. Transgressive systems tracts are related to marine transgression and shoreface retreat. The highstand systems tracts are related to shoreface extension and progradation, and to carbonate production and ramp progradation. Sequences are bounded by erosion or emergence surfaces, whose locations are supported by mineralogical analyses and suggest source area reactivation probably due to a fall in relative sea‐level. Transgressive surfaces are subordinate erosion and/or omission surfaces with a landward facies shift, interpreted as parasequence set boundaries. The co‐existence of siliciclastic and carbonate sediments and environments occurred as facies mixing or as distinct facies belts along the basin. Mixed facies of coastal areas are composed of detrital quartz and clays derived from the hinterland, and dolomite probably derived from bioclastic material. Siliciclastic flux to coastal areas is highly variable, the maximum flux postdates relative sea‐level falls. Carbonate production in these areas may be constant, but the final content is a function of changing inputs in terrigenous sediments and carbonate content diminishes through a dilution effect. Carbonate ramps were detached from the coastal system and separated by a fringe of offshore, fine‐grained muds and silts as distinct facies belts. The growth of carbonate ramp deposits was related to the highstand systems tracts of the fourth‐order parasequence sets. During the growth of these ramps, some sediment starvation occurred basinwards. Progradation and retrogradation of the different belts occur simultaneously, suggesting a sea‐level control on sedimentation. In the study area, the co‐existence of carbonate and siliciclastic facies belts depended on the superimposition of different orders of relative sea‐level cycles, and occurred mainly when the second‐order, third‐order and fourth‐order cycles showed highstand conditions.     

Lateritized tephric palaeosols from Central Patagonia,Argentina: a southern high‐latitude archive of Palaeogene global greenhouse conditions

Palaeosols of the Koluel‐Kaike Formation, a red colour‐banded, pyroclastic succession from southern Argentina, constitute a proxy for Eocene climate changes. Reticulated and vertically elongated ferric mottles, along with iron and manganese nodules are the most significant climate indicators, which originated by alternating cycles of waterlogging and drying conditions causing Fe‐Mn mobilization and fixation. Clay minerals vary from a kaolinite > smectite suite in the lower and middle sections, to a smectite > kaolinite one in the upper part. High concentrations of iron oxides/hydroxides and kaolinite, lack of exchangeable bases, absence of carbonate cement, presence of ironstone and redness of hue in most of the palaeosols suggest intense chemical weathering related to leaching and lateritization processes. Five pedotypes, ordered in a stratigraphic sense, were identified. Strongly developed, red to orange Chornk (Fragiaquult) and Kápenk (Plinthaquult) pedotypes display argillic horizons, abundant ferric nodules and slickensides; they are dominant in the lower and middle sections, and formed in seasonal humid and megathermic (tropical) conditions with a mean annual precipitation of 1200 to 1300 mm and a mean annual temperature of 15 °C. Weakly developed, less structured Ornek (Vitrand) and Pólnek (Placaquand) pedotypes occur in the middle and upper sections, and originated in sub‐humid and mesic‐megathermic conditions with a mean annual precipitation around 1000 mm and a mean annual temperature around 12 °C. The brownish Soorsh (Argialboll) pedotype exhibits a granular structure and is present at the uppermost part of the unit. It developed in sub‐humid/semi‐arid and mesic conditions, with a mean annual precipitation of 600 to 700 mm and a mean annual temperature around 10 °C. This pedotype succession and clay mineral distribution indicates a decrease in chemical weathering and degree of soil development with time. Koluel‐Kaike palaeosols from Central Patagonia are some of the first continental non‐palaeobiological data linked to the Early Palaeogene global warming in South America; they show an especially close relationship with the Early Eocene Climatic Optimum and the following long‐term cooling and drying initiated by Middle to Late Eocene time.     

Glauberite–halite association of the Zaragoza Gypsum Formation (Lower Miocene, Ebro Basin, NE Spain)

Glauberite is the most common mineral in the ancient sodium sulphate deposits in the Mediterranean region, although its origin, primary or diagenetic, continues to be a matter of debate. A number of glauberite deposits of Oligocene–Miocene age in Spain display facies characteristics of sedimentologic significance, in particular those in which a glauberite–halite association is predominant. In this context, a log study of four boreholes in the Zaragoza Gypsum Formation (Lower Miocene, Ebro Basin, NE Spain) was carried out. Two glauberite–halite lithofacies associations, A and B, are distinguished: association (A) is composed of bedded cloudy halite and minor amounts of massive and clastic glauberite; association (B) is made up of laminated to thin‐bedded, clear macrocrystalline, massive, clastic and contorted lithofacies of glauberite, and small amounts of bedded cloudy halite. Transparent glauberite cemented by clear halite as well as normal‐graded and reverse‐graded glauberite textures are common. This type of transparent glauberite is interpreted as a primary, subaqueous precipitate. Gypsum, thenardite or mirabilite are absent in the two associations. The depositional environment is interpreted as a shallow perennial saline lake system, in which chloride brines (association A) and sulphate–(chloride) brines (association B) are developed. The geochemical study of halite crystals (bromine contents and fluid inclusion compositions) demonstrates that conditions for co‐precipitation of halite and glauberite, or for precipitation of Na‐sulphates (mirabilite, thenardite) were never fulfilled in the saline lake system.