Hydrochemical characteristics and the effects of irrigation on groundwater quality in Harran Plain,GAP Project,Turkey

Improper design, faulty planning, mismanagement and incorrect operation of irrigation schemes are the principle reasons for the deterioration of groundwater quality in a large number of countries, in particular in semi-arid and arid regions. The aim of this study is to determine the dimensions of groundwater quality after surface irrigation was begun in the semi-arid Harran Plain. Physical and chemical parameters of the groundwater including pH, temperature, electrical conductivity (EC), sodium, potassium, calcium, magnesium, chloride, bicarbonate, sulphate, nitrate, nitrite, ammonium, total phosphorus, total organic carbon and turbidity were determined monthly during the 2006 water year. The quality of the groundwater in the study area was assessed hydrochemically in order to determine its suitability for human consumption and agricultural purposes. In the general plain, the EC values measured were considerably above the guide level of 650 μS/cm, while nitrate in particular was found in almost all groundwater samples to be significantly above the maximum admissible concentration of 50 mg/l for the quality of water intended for human consumption as per the international and national standards. Total hardness reveals that a majority of the groundwater samples fall in the very hard water category. Interpretation of analytical data shows that Ca–HCO₃ and Ca–SO₄ are the dominant hydrochemical facies in the study area.     

Neural network prediction of nitrate in groundwater of Harran Plain, Turkey

Monitoring groundwater quality by cost-effective techniques is important as the aquifers are vulnerable to contamination from the uncontrolled discharge of sewage, agricultural and industrial activities. Faulty planning and mismanagement of irrigation schemes are the principle reasons of groundwater quality deterioration. This study presents an artificial neural network (ANN) model predicting concentration of nitrate, the most common pollutant in shallow aquifers, in groundwater of Harran Plain. The samples from 24 observation wells were monthly analysed for 1 year. Nitrate was found in almost all groundwater samples to be significantly above the maximum allowable concentration of 50 mg/L, probably due to the excessive use of artificial fertilizers in intensive agricultural activities. Easily measurable parameters such as temperature, electrical conductivity, groundwater level and pH were used as input parameters in the ANN-based nitrate prediction. The best back-propagation (BP) algorithm and neuron numbers were determined for optimization of the model architecture. The Levenberg–Marquardt algorithm was selected as the best of 12 BP algorithms and optimal neuron number was determined as 25. The model tracked the experimental data very closely (R = 0.93). Hence, it is possible to manage groundwater resources in a more cost-effective and easier way with the proposed model application.     

Facies analysis and sequence stratigraphy of Kometan Formation (Upper Cretaceous) in the imbricated zone,northeastern Iraq

Facies and sequence stratigraphic analysis of the Kometan Formation (Upper Cretaceous) were studied from Kometan village, Kurdistan region of northeastern Iraq. Lithologically, the formation consists of 44 m of white weathering, light grey, thin to medium-bedded highly fractured limestones with chert nodules. Petrographic study of the carbonates shows that both skeletal and non-skeletal grains were present. The skeletal grains include a variety of planktonic foraminifera (including Oligostegina), calcispheres, ostracods, pelecypods, larva ammonite, and echinoderms. Non-skeletal grains include peloids only. Three main microfacies types are distinguished in the studied formation. The results of stable carbon and oxygen isotopes of the studied carbonate samples show negative values of δ¹⁸O. These indicate that the seawater was warm with low salinity during precipitation of the carbonates in the Kometan Formation in northeastern Iraq. The positive δ¹³C values of carbonate samples, in the middle part of the formation, reflect the widespread deposition of organic-rich marine sediments during a transgression and deepening of the basin. Petrographic, facies and stable isotopic analyses revealed that the Kometan Formation was deposited in a warm, basinal, pelagic (open marine) environment with low salinity. The Kometan Formation consists of one complete third-order depositional sequence, separated by a sequence boundary (SB) of type 2. The third-order sequence is subdivided into a transgressive systems tract (TST) and highstand systems tract (HST). This reflects episodes of transgression and still stands of the relative sea level. The TSTs are topped by maximum flooding surface (MFS) characterized by deepening-/fining-upward parasequences implying a retrogradational stacking pattern. The HST is marked by shallowing-/coarsening-upward parasequences implying a progradational stacking pattern.     

Integrated methodology for flood risk assessment and application in urban communities of Pakistan

Flood disasters and its consequent damages are on the rise globally. Pakistan has been experiencing an increase in flood frequency and severity along with resultant damages in the past. In addition to the regular practices of loss and damage estimation, current focus is on risk assessment of hazard-prone communities. Risk measurement is complex as scholars engaged in disaster science and management use different quantitative models with diverse interpretations. This study tries to provide clarity in conceptualizing disaster risk and proposes a risk assessment methodology with constituent components such as hazard, vulnerability (exposure and sensitivity) and coping/adaptive capacity. Three communities from different urban centers in Pakistan have been selected based on high flood frequency and intensity. A primary survey was conducted in selected urban communities to capture data on a number of variables relating to flood hazard, vulnerability and capacity to compute flood risk index. Households were categorized into different risk levels, such as can manage risk, can survive and cope, and cannot cope. It was found that risk levels varied significantly across the households of the three communities. Metropolitan city was found to be highly vulnerable as compared to smaller cities due to weak capacity. Households living in medium town had devised coping mechanisms to manage risk. The proposed methodology is tested and found operational for risk assessment of flood-prone areas and communities irrespective of locations and countries.     

Eocene tonalite–granodiorite from the Havza (Samsun) area,northern Turkey: adakite-like melts of lithospheric mantle and crust generated in a post-collisional setting

ABSTRACT

Eocene intermediate to felsic plutons of different sizes and compositions are widespread in the Eastern Pontides Orogenic Belt in northern Turkey. Of these, the Ta?l?k Tepe pluton in the Havza (Samsun) area is fine-to-medium-grained, with granular, porphyritic, and micrographic textures, and include mafic microgranular enclaves (MMEs). LA-ICP-MS U-Pb zircon dating yielded emplacement ages of 42.9 (± 1.4) and 40.5 (± 1.3) Ma for the host granodioritic pluton and the dioritic MMEs, respectively. Petrochemically, the host pluton has I-type, high-K calc-alkaline, and metaluminous-to-slightly peraluminous features (A/CNK = 0.95–1.06). The host pluton also shows geochemical features of adakite-like rocks with high SiO₂ (67–68 wt%) and Al₂O₃ (15.5–16.0 wt%) content and Ba/La (17–23), Sr/Y (40.7–61.6), and La_N/Yb_N (14.4–23.7) ratios and low Y (8.2–9.9 ppm) and Yb_N (3.1–4.4) contents. Whole-rock major and trace element variations suggest that fractional crystallisation played a significant role in the pluton evolution. The N-MORB normalised trace element patterns of the pluton are similar to those of MMEs with enrichment in large-ion lithophile elements, Th and Ce, and negative Nb and Ti anomalies. Chondrite-normalised rare earth element plots show moderate-to-highly enriched concave patterns (La_N/Lu_N = 14.2–21.6) with insignificant negative Eu anomalies (Eu_N/Eu* = 0.86–1.14), all of which imply hornblende fractionation during magmatic evolution. The pluton samples have ⁸⁷Sr/⁸⁶Sr ratios of 0.704767 to 0.704927, ¹⁴³Nd/¹⁴⁴Nd ratios of 0.512767–0.512774, εNd values of (+2.52) – (+2.65), and δ¹⁸O values of 7.9–9.7‰. The isotopic compositions of the host pluton and MMEs are similar to I-type granitoids derived from mantle sources. The MMEs show incomplete magma mixing/mingling, representing small bodies of mafic parental magma. Combined with regional studies, these new data suggest that the parental magma of the studied adakite-like pluton was generated from the lithospheric mantle and then modified by fractional crystallisation and assimilation in a post-collisional setting.     

Joint parameter estimation from magnetic resonance and vertical electric soundings using a multi‐objective genetic algorithm

Magnetic resonance sounding (MRS) has increasingly become an important method in hydrogeophysics because it allows for estimations of essential hydraulic properties such as porosity and hydraulic conductivity. A resistivity model is required for magnetic resonance sounding modelling and inversion. Therefore, joint interpretation or inversion is favourable to reduce the ambiguities that arise in separate magnetic resonance sounding and vertical electrical sounding (VES) inversions. A new method is suggested for the joint inversion of magnetic resonance sounding and vertical electrical sounding data. A one‐dimensional blocky model with varying layer thicknesses is used for the subsurface discretization. Instead of conventional derivative‐based inversion schemes that are strongly dependent on initial models, a global multi‐objective optimization scheme (a genetic algorithm [GA] in this case) is preferred to examine a set of possible solutions in a predefined search space. Multi‐objective joint optimization avoids the domination of one objective over the other without applying a weighting scheme. The outcome is a group of non‐dominated optimal solutions referred to as the Pareto‐optimal set. Tests conducted using synthetic data show that the multi‐objective joint optimization approximates the joint model parameters within the experimental error level and illustrates the range of trade‐off solutions, which is useful for understanding the consistency and conflicts between two models and objectives. Overall, the Levenberg‐Marquardt inversion of field data measured during a survey on a North Sea island presents similar solutions. However, the multi‐objective genetic algorithm method presents an efficient method for exploring the search space by producing a set of non‐dominated solutions. Borehole data were used to provide a verification of the inversion outcomes and indicate that the suggested genetic algorithm method is complementary for derivative‐based inversions.     

Why was the 2008 Indian Ocean Dipole a short-lived event?

In this paper, the role of equatorial oceanic waves in affecting the evolution of the 2008 positive Indian Ocean Dipole (IOD) event was evaluated using available observations and output from a quasi-analytical linear wave model. It was found that the 2008 positive IOD was an early matured and abruptly terminated event: developed in April, matured in July, and diminished in September. During the development and the maturation of the 2008 positive IOD event, the wind-forced Rossby waves played a dominant role in generating zonal current anomalies in the western equatorial Indian Ocean, while a complex interplay between the wind-forced upwelling Kelvin waves and the eastern-boundary-generated Rossby waves accounted for most of the variability in the eastern basin. The latter induced eastward zonal current anomalies near the eastern boundary during the peak phase of the event. The 2008 positive IOD event was abruptly terminated in mid-July. We found that there were strong eastward zonal currents in mid-July, though the surface wind anomalies in the eastern basin continued to be westward (upwelling favorable). Our analysis shows that these eastward zonal currents mainly resulted from the easternboundary-generated upwelling Rossby waves, although the contribution from the wind-forced downwelling Kelvin waves was not negligible. These eastward zonal currents terminated the zonal heat advection and provided a favorable condition for surface heat flux to warm the eastern basin.