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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff
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We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
2.
The effects of natural fish oil,DHA oil and soybean lecithin in microparticulate diets on stress tolerance of larval gilthead seabream(Sparus aurata)were investigated after 15 days feeding trials.The tolerance of larval gilthead seabream to various stress factors such as exposure to air(lack of dissolved oxygen),changes in water temperature(low)and salinity(high) were determined.This study showed that microparticulate diet with natural fish oil and soybean lecithin was the most effective for in-creasing the tolerance of larval gilthead seabream to various stresses,and that microparticulate diet with natural fish oil and palmitic acid(16:0)was more effective than microparticulate diet with DHA oil and soybean lecithin. 相似文献
3.
对于改进的Encke方法,选择适当的参考轨道是一个关键.然而,对于人造地球卫星长弧轨道计算,目前所给出的几种参考轨道均需要逐段校正,这将给定轨问题带来附加的复杂性.本文将仔细探讨如何选择参考轨道和减少校正次数. 相似文献
4.
JINFeng-jun 《中国地理科学(英文版)》2003,13(2):97-103
It is very important to establish cooperative mechanism to guarantee all members to develop their e-conomies in the Yellow Sea Rim. In this paper, the development strategies ofshipplng centers and transportation networkare discussed based on economic giobalization tendency. The results argue that a united transportation network should bebuilt in order to promote the economic competition of Northeast Asia in the world. As a key component of the economiccooperation, a hierarchical shipping centers network should be established with Hong Kong, Shanghai, Pusan, Koho,and Tokyo as cores. The authorities of China, Japan, R. O. Korea and D. P. B. Korea should make more efforts tobuild a set of cooperation institutions based on raising the transportation efficiency. 相似文献
5.
The actual penetration depth of the Shoemaker-Levy 9 fragments into the Jovian atmosphere is still an open question. From fundamental equations of meteoric physics with variable cross-section, a new analytic model of energy release of the fragments is presented. In use of reasonable parameters, a series of results are calculated for different initial mass of the fragments. The results show that the largest fragment explodes above pressure levels of 3 bars and does not penetrate into the H2O cloud layer of the Jovian atmosphere, and that airburst of smaller fragments occur even above the upper cloud layer. 相似文献
6.
为建立社会主义市场经济的地矿工作新秩序,本文对国有地矿企业的经营者(厂长、经理)这一特殊群体进行了分析。着重研究了新形势下企业经营者实行年薪制的问题。指出年薪制就是以企业一个生产经营周期为单位确定经营者的报酬,这一周期通常为一年。进而阐述了为什么要实行企业经营者年薪制;企业经营者的收入应与职工工资完全脱钩;采用基础报酬加效益报酬的方法确定收入等等。并构想了实行经营者年薪制所需要的外部环境:建立经营者人才市场、经营者要能进能出、实行任职资格制度、建立风险机制、按劳动力市场经济规律办事。 相似文献
7.
Based on the CN and C2 comae isophotes for two comets (1961 IX and 1970 16) given by Rahe et al. and the relevant theory of physical chemistry, we have deduced the distributions of the CN and C2 modecules in the coma, their scale heights and mean lifetimes. The results favour the viewpoint that HCN is the parent of CN, and that C2H2 is the parent of C2. 相似文献
8.
CATASTROPHIC ECO-ENVIRONMENTAL CHANGE IN THE SONGNEN PLAIN, NORTHEASTERN CHINA SINCE 1900S 总被引:1,自引:1,他引:0
WANGHai-xia WANZhong-juan YUShao-peng LUOXin-zheng SUNGuang-you 《中国地理科学(英文版)》2004,14(2):179-185
Although the Songnen Plain in the northeastern China was developed relatively late in the temperate zone of the world, its eco-environment has changed greatly. This paper analyzes the changes of land cover and the rates and trends ofdesertification during the past 100 years in the Songnen Plain. According to the macroscopic analysis, we find that the eco-environment in the plain has reached to the threshold of catastrophic change since the 1950s. The Thorn Needle Catastrophic Model was used to determine and validate this conclusion. Human activities, including large-scale construction projects, such as huge dams and dikes, and excessive grazing were the primary factors contributing to regional eco-environmental catastrophe. And irrational reclamation of the wilderness also affected the eco-environmental change. The results reveal the complex human-land interactions. 相似文献
9.
THE SIMULATED STORAGE CAPACITY OF FLOOD AND WATERLOGGING IN THE TYPICAL AGRICULTURAL REGION IN JIANGHAN PLAIN 总被引:2,自引:0,他引:2
1INTRODUCTIONJianghanPlainisoneoftheimportantbasesofChina′sagriculturalproductivitylocatedinthemiddleChangjiangRivervalleyofcentralChina.TheJianghanplainapproximately6.6×104km2inareaandover30millioninpopulationistherenowned“countryoffishandrice"in… 相似文献
10.
Ken Ebisawa Aya Kubota Tsunefumi Mizuno Piotr Życki 《Astrophysics and Space Science》2001,276(1):11-14
The Ultra-luminous Compact X-ray Sources (ULXs)in nearby spiral galaxies and the Galactic super-luminaljet sources sharethe common spectral characteristic that they haveextremely high disk temperatures which cannot be explainedin the framework of the standard accretion disk modelin the Schwarzschild metric. We have calculated an extreme Kerr disk model to examine if the Kerr disk model can instead explain the observed `too hot' accretion disk spectra.We found that the Kerr disk spectrum becomes significantly hardercompared to the Schwarzschild disk only when the disk is highlyinclined.For super-luminal jet sources, which are known to beinclined systems, the Kerr disk model may thuswork if we choose proper values for the black hole angular momentum. For the ULXs, however, the Kerr disk interpretation will be problematic,as is is highly unlikely that their accretion disks are preferentiallyinclined. 相似文献