Migration Fractionation of Neutral Nitrogen Compounds of Crude Oils from Tabei Oilfield in the Tarim Basin, China

The absolute amounts and relative distributions of neutral nitrogen compounds in the Tabei oilfield (e. G. Blocks Ln1-Ln1 1) showed remarkable migration fractionation in the vertical direction. From Ordovician reservoirs (O) to oil legs TⅢ and T Ⅰ of Triassic reservoirs in blocks LN1-LN11, the concentrations of [a] [c] decreased from 1. 59μg/g, 0.49μg/g to 0.17 μg/g (oil). The ratios of various alkylcarbazole isomers, such as 1,8-dimethylcarbazole/nitrogenpartially shielded isomers and 1,8-dimethylcarbazole/nitrogen-exposed isomers, were adopted as the indicators of petroleum migration. The ratios increased from 0.13, 0.20 to 0.67 and from going from the south to the north of the Tabei oilfield, the absolute concentrations of neutral nitrogen compounds decreased drastically, and the nitrogen-shielded isomers were enriched relative to nitrogen-exposed isomers and nitrogen-partially shielded isomers. Crude oils in the Tabei oilfield migrated laterally from the Jilake structure to the Sangtamu fault uplift and Lunnan fault uplift, and crude oils in the same fault uplift migrated and remigrated vertically from Ordovician reservoirs, to oil legs TⅢ to TⅠ of Triassic reservoirs.     

An invariance in the carbazoles of petroleum

A remarkable invariance in the ratio of 1,3-dimethylcarbazole （DMC） to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate.     

立交桥曲线箱梁动力分析模型

提出了1种双脊骨空间有限元模型,用来模拟和分析立交桥曲线箱梁的固有振动特性和动力反应。将曲线箱梁分别看作是由空间梁或壳组成的空间结构,并分别采用分段空间直梁模型、壳元模型和实体元模型进行模拟,分析相同曲线箱梁的振动特性和地震时程反应,通过与双脊骨模型的计算结果的比较验证双脊骨模型的可靠性。初步研究了在相同曲率半径下不同跨度的曲线箱梁的固有振动特性,分析了双脊骨模型的脊骨间距、横向连接间距等参数对模型计算结果的影响。研究结果可为曲线梁桥抗震性能和地震反应分析提供参考。     

结构平稳随机地震反应时域分析:方法

给出了三种常用的随机地震地面运动过程模型,即理想白噪声模型、金井清模型、改进金井清模型的相关函数表达式.引入状态向量,在状态空间中建立地震地面运动激励下的结构振动方程,并求解出结构的复模态特性和复模态反应.利用复模态叠加法推导出线性时不变多自由度体系在这三种随机地震动激励下的平稳协方差反应的解析式,可在时域内直接计算结构随机反应的统计特征.该方法物理概念清晰,结论简便明确,可作为实际工程结构平稳随机地震反应的实用分析方法.     

多源地学信息综合处理技术研究

本义重点研究以遥感为主的多源信息综合处理技术，取得的主要成果是：对遥感数据采用特定的图像处理，减弱了植被、冻土带的干扰；开创性地从能谱图像中定性、定量地提取铀信息和从地球化学场角度揭示构造蚀变带；研究岩石反射光谱特征，突出找矿蚀变信息；利用重、磁图像挖掘深层构造信息及首次成功地研制出高几何配准精度的综合找矿预测影像图等。应用这些成果指导找矿，取得突破性进展，地表矿体和矿化体的揭露，显示出该项技术的科学性和实用价值。     

The Variance of Mango‘s Light—Hydrocarbon Parameter K

The analyses of light hydrocarbons in oils from the Tarim Basin show that the Mango‘s parameter K is about unity except those oils trapped in the eastern part of the Tazhong (Central Tarim)Fault Uplift,The regular variance of K may indicates the accumulation and admixture of the oil populations in the eastern part of the Tazhong Fault Uplift.     

辽宁五龙地区中生代火成岩成因及其找矿意义

辽宁五龙金矿是辽东地区大型岩浆热液型矿床之一,成矿作用主要与中生代火成岩有关,为了进一步理清五龙地区中生代火成岩成因,本文对五龙金矿区大量花岗斑岩脉、闪长岩脉、三股流岩体和其中的各类脉岩进行了单颗粒锆石LA-ICPMS U-Pb测年和岩石主、微量元素地球化学研究。结果表明,五龙地区岩浆岩形成时代主要有晚侏罗世和早白垩世,矿区内近南北向展布的花岗斑岩脉形成于晚侏罗世（154.3±0.9~155.6±1.1 Ma）,指示矿区在晚侏罗世受到区域最大主应力方向为近南北向;三股流岩体成岩最新年龄（116.8±0.8~117.3±0.7 Ma）基本位于前人报道的年龄范围（111~129 Ma）;地球化学数据表明各类岩浆岩属于高钾钙碱性—钾玄岩系列,具有相同源区特征,形成于活动大陆边缘俯冲伸展环境下的弧岩浆,并且具有壳幔混合及进一步演化特征;结合不同深度标高成矿元素丰度特征,指示闪长岩与成矿作用密切相关,并且越往深部成矿潜力越大,对该地区找矿预测具有重要指导意义。     

北部湾盆地福山凹陷古近系双层结构形成机制

以北部湾盆地区域构造分析为基础, 在福山凹陷构造活动性研究的基础上探讨了福山凹陷形成的动力学机制, 分析了凹陷东部地区古近系地层中双层结构的形成机制问题.研究认为: 福山凹陷在平面上受红河断裂的左行走滑和海南隆起顺时针旋转的双重作用, 流三段沉积期凹陷在旋转-拉分作用下发生强烈的水平伸展, 为东部地区下构造层中的反向断层提供动力源, 海南隆起的快速隆升作用形成了上构造层中的重力滑动生长断层, 渐新统早期在流二段泥岩中发育的火成岩侵入体在凹陷的东部地区形成一道天然屏障, 最终形成双层结构.结果表明, 双层结构形成过程可划分为裂陷雏形期、下构造层伸展断裂期、中部塑性层发育期、上构造层形成期以及双层结构定形期5个主要阶段.      

微分求积法在结构动力分析中的应用

微分求积法（DQM）是1种求解微分方程初（边）值问题的数值方法,通常以较小的计算工作量即可获得较高的数值精度。这种方法应用于工程领域时多用来解决梁、板等结构的静力分析或结构特征值分析等问题,即对边值问题的微分方程的求解。结构动力分析属于初值问题,荷载和结构反应都具有特殊性,直接套用DQM求解边值问题并不能获得问题的解。本文尝试利用微分求积原理建立求解结构动力反应的具体方法。借鉴单元法的思想,将荷载持时划分为若干个时步,在每个时步内对动态荷载和结构反应进行离散,然后用DQM对时步逐个进行求解,得到体系在整个时域内的反应过程。通过对3种不同自振周期的线弹性单自由度体系在不同频率简谐激励下反应的计算,阐释了本文方法的可行性以及高精度、高效率的特点,通过数值试验确定了时步内相对较优的节点数,并为时步长度的选取提供了建议。     

Geochemical Evidence for Coal and Carbonaceous Mudstone as the Possible Major Oil Source Rock in the Jurassic Turpan Basin,Northwest China

Petroleum geologists have debated whether the hydrocarbons from Jurassic coal measures are derived from the coals, carbonaceous mudstones or coal-measure mudstones in the Turpan Basin. Based on the geochemistry analysis of the 20 crude oils and 40 source rocks from the Turpan Basin, some data have been obtained as follows: carbon preference index and methylphenanthrene index of the Jurassic oils are 1.16–1.45 and 0.28–0.80, and the ααα C29 sterane 20S/(20S+20R) and C29 sterane ββ/(ββ+αα) are 0.44–0.51 and 0.4–0.54 respectively, which show the normal maturity of oils; the vitrinite reflectance of the source rocks from the Xishanyao to Badaowan Formations range from 0.47% to 0.97%, which indicate immature to mature thermal evolutionary stage and sufficient conditions for generating mass mature oil. The effect of hydrocarbon expulsion should be considered when studying the source of coal-derived oil by using Biomarkers. Biomarkers in the Jurassic oils from the basin are similar to those in the coals and carbonaceous mudstones, with a strong predominant content of pristane, relatively high ratio of C15/C16 sesquiterpenoids (>1), a relatively high content of low carbon number tricyclic terpanes and C24 tetracyclic terpane, little gammacerane and C29 Ts detected, an absolute predominant content of C29 sterane and a relatively high content of diasterane. However, the opposite characteristics are shown in mudstones, with an approximately equal content of pristane and phytane, relatively low ratio of C15/C16 sesquiterpenoids (<1), a relatively high content of high carbon number tricyclic terpanes and a low content of C24 tetracyclic terpane, peaks of gammacerane and C29 Ts detected obviously and an increasing C27 sterane content. All of these characteristics identify the coals and carbonaceous mudstones as the possible major oil source rocks in this area, and they were formed in the stronger oxidizing environment with shallower water than mudstones.