Phosphate adsorption and desorption in a tropical estuary (Maracaibo system)

The Maracaibo Estuary is of particular interest because of its location in the tropics, its large size (over 12,000 km²), the economic importance of its underlying hydrocarbon deposits and its increasing rate of pollution. Sediments from this estuary were studied in order to characterise their capacity to adsorb and desorb phosphorus. Considerable variability in capacity for phosphate sorption was found among the seventeen samples studied. This variability can be attributed first to the differences among the samples in total P content and, secondly, to their differences in free iron content. Also, it appears that P retention contributes to the control of P concentration in the water and therefore the sediments serve as a buffer in controlling P eutrophication in the estuary.     

Flotation of oxidized minerals of copper using a new synthetic chelating reagent as collector

A new synthetic reagent containing a mixed aliphatic-aromatic structure, with a hydrocarbon chain and an aminothiophenol chelating group, has proven to be an effective collector for the flotation of chrysocolla minerals. The flotation is optimum in the narrow pH range of 5.5 to 6, falls sharply at pH 5, and is moderate in the pH range 7 to 11. Infrared spectra indicate that copper aminothiophenolate chelates are formed on the surface of the chrysocolla under the conditions of maximum flotation.     

Comparison of water-level,extensometric, DInSAR and simulation data for quantification of subsidence in Murcia City (SE Spain)

Subsidence due to groundwater overexploitation has been recognized in the metropolitan area of Murcia (25 km²) in south-eastern Spain since the early 1990s. Previous published works have focused their attention on land subsidence that occurred during the drought period between 1995 and 2008. This work first analyzes the groundwater recovery that has occurred since 2008 and then determines the kind of associated ground deformation detected by the new extensometric data. Subsequently, subsidence time series are computed on 24 geotechnical boreholes scattered throughout the study area by means of a hydro-mechanical finite element code and a linear-elastic constitutive law. A spatio-temporal interpolation of the numerically modeled surface displacements is performed over the whole domain and compared with extensometers and DInSAR-derived displacement maps in two different periods: the drought period from 2004 to 2008, and the recovery period from 2008 to 2012. In spite of the limited information on the geomechanical parameters characterizing the modelled geological formations, the proposed approach is able to discriminate areas where the soils have an elastic behavior (small differences in the comparisons) or an elasto-plastic behavior (large differences in the comparisons). This zonation enhances the understanding of the subsidence phenomenon in Murcia City and could prevent, from a quantitatively point of view, future severe subsidence due to aquifer overexploitation.     

Site scale modeling of slow-moving landslides,a 3D viscoplastic finite element modeling approach

This paper presents an advanced 3D numerical methodology to reproduce the kinematics of slow active landslides, more precisely, to reproduce the nearly constant strain rate (secondary creep) and the acceleration/deceleration of the moving mass due to hydrological changes. For this purpose, finite element analyses are performed in a large area covering a long time-span (12 years), in order to exhibit different interacting slope movements. First, we perform a stability analysis using the shear strength reduction (SSR) technique with a Mohr-Coulomb failure criteria. It is done in order to compute factors of safety (FS) and to identify two different scenarios, the first one being stable (FS > 1) and the second one being unstable (FS < 1). In the studied test case, the Portalet landslide (Central Spanish Pyrenees), the first scenario corresponds to an initial stable configuration of the slope and the second one to an unstable excavated configuration. Second, taking the first scenario as an initial condition, a time-dependent analysis is performed using a coupled formulation to model solid skeleton and pore fluids interaction, and a simplified ground water model that takes into account daily rainfall intensity. In this case, a viscoplastic constitutive model based on Perzyna’s theory is applied to reproduce soil viscous behavior and the delayed creep deformation due to the excavation. The fluidity parameter is calibrated to reproduce displacements measured by the monitoring systems. Our results demonstrate that 3D analyses are preferable to 2D ones for reproducing in a more realistic way the slide behavior. After calibration, the proposed model is able to simulate successfully short- and medium-term predictions during stages of primary and secondary creep.     

Precipitation variability and trends in Ghana: An intercomparison of observational and reanalysis products

Inter-annual variability and trends of annual/seasonal precipitation totals in Ghana are analyzed considering different gridded observational (gauge- and/or satellite-based) and reanalysis products. A quality-controlled dataset formed by fourteen gauges from the Ghana Meteorological Agency (GMet) is used as reference for the period 1961–2010. Firstly, a good agreement is found between GMet and all the observational products in terms of variability, with better results for the gauge-based products—correlations in the range of 0.7–1.0 and nearly null biases—than for the satellite-gauge merged and satellite-derived products. In contrast, reanalyses exhibit a very poor performance, with correlations below 0.4 and large biases in most of the cases. Secondly, a Mann-Kendall trend analysis is carried out. In most cases, GMet data reveal the existence of predominant decreasing (increasing) trends for the first (second) half of the period of study, 1961–1985 (1986–2010). Again, observational products are shown to reproduce well the observed trends—with worst results for purely satellite-derived data—whereas reanalyses lead in general to unrealistic stronger than observed trends, with contradictory results (opposite signs for different reanalyses) in some cases. Similar inconsistencies are also found when analyzing trends of extreme precipitation indicators. Therefore, this study provides a warning concerning the use of reanalysis data as pseudo-observations in Ghana.     

Global distribution of the intensity and frequency of hourly precipitation and their responses to ENSO

Climate Dynamics - We investigate the global distribution of hourly precipitation and its connections with the El Niño–Southern Oscillation (ENSO) using both satellite precipitation...     

Positive solution of two-dimensional solute transport in heterogeneous aquifers

The transport of contaminants in aquifers is usually represented by a convection-dispersion equation. There are several well-known problems of oscillation and artificial dispersion that affect the numerical solution of this equation. For example, several studies have shown that standard treatment of the cross-dispersion terms always leads to a negative concentration. It is also well known that the numerical solution of the convective term is affected by spurious oscillations or substantial numerical dispersion. These difficulties are especially significant for solute transport in nonuniform flow in heterogeneous aquifers. For the case of coupled reactive-transport models, even small negative concentration values can become amplified through nonlinear reaction source/sink terms and thus result in physically erroneous and unstable results. This paper includes a brief discussion about how nonpositive concentrations arise from numerical solution of the convection and cross-dispersion terms. We demonstrate the effectiveness of directional splitting with one-dimensional flux limiters for the convection term. Also, a new numerical scheme for the dispersion term that preserves positivity is presented. The results of the proposed convection scheme and the solution given by the new method to compute dispersion are compared with standard numerical methods as used in MT3DMS.     

Influence of the oceanographic conditions during spring 2003 on the transport of the Prestige tanker fuel oil to the Galician coast

Hydrographic data collected during the cruise HIDROPRESTIGE were combined with meteorological and dynamic data provided by remote sensors and drifting/moored buoys, to describe the surface circulation of the Northern Iberian basin in March-April 2003. Sea surface winds transported the floating Prestige oil slicks from the sinking area to the continental slope off the Rías Baixas in 1/2 month: the surface current intensity was 2% of the wind intensity and it was rotated clockwise 5 degrees from the wind direction. Mesoscale cyclonic and anticyclonic structures west of 10 degrees W increased the residence time of oil patches in the Northern Iberian basin, as compared with the expected southwards flow of the Iberian current (IC). On the other hand, the Iberian poleward current (IPC) formed a marked surface front with coastal waters, preventing the entry of fuel oil into the rías. PAHs in the surface layer during the cruise were <0.5 microgL(-1), except in the Galicia bank (approximately 1 microg L(-1); where the Prestige tanker was still leaking) and the vicinity of Cape Fisterra (approximately 1.5 microg L(-1); where the convergence front between the IPC and coastal waters vanished).