Baroclinic nonlinear exchanges of energy and potential enstrophy in the quasi-geostrophic two-layer model

Abstract

Merilees and Warn's (1975) nonlinear interaction analysis of two-dimensional nondivergent flow is extended to examine the quasi-geostrophic two-layer model. Two sets of triads exist in this model (Salmon, 1978). The purely barotropic triads are the same as the triads examined by Merilees and Warn. Baroclinic-barotropic triads are found to exchange more energy or potential enstrophy with smaller or larger scales depending on the scale of motion as compared with the internal Rossby deformation radius and the relative wavenumber position of baroclinic and barotropic components.     

Effect of Biofuels on Biodegradation of Benzene and Toluene at Gasoline Spill Sites

The risk that benzene and toluene from spills of gasoline will impact drinking water wells is largely controlled by the natural anaerobic biodegradation of benzene and toluene. Benzene and toluene, as well as ethanol and other biofuels, are degraded under anaerobic conditions to the same pool of degradation products. Biodegradation of biofuels may produce concentrations of degradation products that make the thermodynamics for degradation of benzene and toluene infeasible under methanogenic conditions and produce larger plumes of benzene and toluene. This study evaluated the concentrations of fuel alcohols that are necessary to inhibit the anaerobic degradation of benzene and toluene under methanogenic conditions. At two ethanol spill sites, concentrations of ethanol greater ≥42 mg/L inhibited the anaerobic degradation of toluene. The pH and concentrations of acetate, dissolved inorganic carbon, and molecular hydrogen were used to calculate the Gibbs free energy for the biodegradation of toluene. In general, the anaerobic biodegradation of toluene was not thermodynamically feasible in water with ≥42 mg/L ethanol. In a microcosm study, when the concentrations of ethanol were ≥14 mg/L or the concentrations of n‐butanol were ≥16 mg/L, the biodegradation of the alcohols consistently produced concentrations of hydrogen, dissolved inorganic carbon, and acetate that would preclude natural anaerobic biodegradation of benzene and toluene by syntrophic organisms. In contrast, iso‐butanol and n‐propanol only occasionally produced conditions that would preclude the biodegradation of benzene and toluene.     

Simulating flow in karst aquifers at laboratory and sub-regional scales using MODFLOW-CFP

Groundwater flow in a well-developed karst aquifer dominantly occurs through bedding planes, fractures, conduits, and caves created by and/or enlarged by dissolution. Conventional groundwater modeling methods assume that groundwater flow is described by Darcian principles where primary porosity (i.e. matrix porosity) and laminar flow are dominant. However, in well-developed karst aquifers, the assumption of Darcian flow can be questionable. While Darcian flow generally occurs in the matrix portion of the karst aquifer, flow through conduits can be non-laminar where the relation between specific discharge and hydraulic gradient is non-linear. MODFLOW-CFP is a relatively new modeling program that accounts for non-laminar and laminar flow in pipes, like karst caves, within an aquifer. In this study, results from MODFLOW-CFP are compared to those from MODFLOW-2000/2005, a numerical code based on Darcy’s law, to evaluate the accuracy that CFP can achieve when modeling flows in karst aquifers at laboratory and sub-regional (Woodville Karst Plain, Florida, USA) scales. In comparison with laboratory experiments, simulation results by MODFLOW-CFP are more accurate than MODFLOW 2005. At the sub-regional scale, MODFLOW-CFP was more accurate than MODFLOW-2000 for simulating field measurements of peak flow at one spring and total discharges at two springs for an observed storm event.     

X射线荧光光谱法测定土壤样品中碳氮硫氯等31种组分

利用新型的ZSX Primus Ⅱ型X射线荧光光谱仪采用粉末压片法直接测定土壤样品中的C、N、S、Cl等31种元素。各元素分析晶体为N采用RX45，C采用RX61，Na、Mg采用RX25，C1、S、P采用Ge，Si、Al采用PET，其余元素均采用LiF200。结果表明，方法的检出限、精密度和准确度对绝大多数元素而言，均可满足多目标地球化学调查样品分析的质量要求：     

Generalized force vectors for multi‐mode pushover analysis

A generalized pushover analysis (GPA) procedure is developed for estimating the inelastic seismic response of structures under earthquake ground excitations. The procedure comprises applying different generalized force vectors separately to the structure in an incremental form with increasing amplitude until a prescribed seismic demand is attained for each generalized force vector. A generalized force vector is expressed as a combination of modal forces, and simulates the instantaneous force distribution acting on the system when a given response parameter reaches its maximum value during dynamic response to a seismic excitation. While any response parameter can be selected arbitrarily, generalized force vectors in the presented study are derived for maximum interstory drift parameters. The maximum value of any other response parameter is then obtained from the envelope of GPAs results. Each nonlinear static analysis under a generalized force vector activates the entire multi‐degree of freedom effects simultaneously. Accordingly, inelastic actions develop in members with the contribution of all ‘instantaneous modes’ in the nonlinear response range. Target seismic demands for interstory drifts at the selected stories are calculated from the associated drift expressions. The implementation of the proposed GPA is simpler compared with nonlinear response history analysis, whereas it is less demanding in computational effort when compared with several multi‐mode adaptive nonlinear static procedures. Moreover, it does not suffer from the statistical combination of inelastic modal responses obtained separately. The results obtained from building frames have demonstrated that GPA is successful in estimating maximum member deformations and member forces with reference to the response history analysis. When the response is linear elastic, GPA and response spectrum analysis produce identical results. Copyright © 2010 John Wiley & Sons, Ltd.     

Groundwater Flow Cycling Between a Submarine Spring and an Inland Fresh Water Spring

Spring Creek Springs and Wakulla Springs are large first magnitude springs that derive water from the Upper Floridan Aquifer. The submarine Spring Creek Springs are located in a marine estuary and Wakulla Springs are located 18 km inland. Wakulla Springs has had a consistent increase in flow from the 1930s to the present. This increase is probably due to the rising sea level, which puts additional pressure head on the submarine Spring Creek Springs, reducing its fresh water flow and increasing flows in Wakulla Springs. To improve understanding of the complex relations between these springs, flow and salinity data were collected from June 25, 2007 to June 30, 2010. The flow in Spring Creek Springs was most sensitive to rainfall and salt water intrusion, and the flow in Wakulla Springs was most sensitive to rainfall and the flow in Spring Creek Springs. Flows from the springs were found to be connected, and composed of three repeating phases in a karst spring flow cycle: Phase 1 occurred during low rainfall periods and was characterized by salt water backflow into the Spring Creek Springs caves. The higher density salt water blocked fresh water flow and resulted in a higher equivalent fresh water head in Spring Creek Springs than in Wakulla Springs. The blocked fresh water was diverted to Wakulla Springs, approximately doubling its flow. Phase 2 occurred when heavy rainfall resulted in temporarily high creek flows to nearby sinkholes that purged the salt water from the Spring Creek Springs caves. Phase 3 occurred after streams returned to base flow. The Spring Creek Springs caves retained a lower equivalent fresh water head than Wakulla Springs, causing them to flow large amounts of fresh water while Wakulla Springs flow was reduced by about half.     

An improvement to linear‐elastic procedures for seismic performance assessment

An improved linear‐elastic analysis procedure is developed in this paper as a simple approximate method for displacement‐based seismic assessment of the existing buildings. The procedure is mainly based on reducing the stiffness of structural members that are expected to respond in the inelastic range in a single global iteration step. Modal spectral displacement demands are determined from the equal displacement rule. Response predictions obtained from the proposed procedure are evaluated comparatively by using the results of benchmark nonlinear response history analysis, and both the conventional and the multi‐mode pushover analyses. In comparative evaluations, a twelve‐story RC plane frame and a six‐story unsymmetrical‐plan RC frame are employed by using 91 ground motion components. It is observed that the proposed procedure estimates the flexural deformation demands in deformation‐controlled members and the shear forces in force‐controlled members with reasonable accuracy. Copyright © 2010 John Wiley & Sons, Ltd.     

Limitations on linear elastic procedures in performance assessment of regular frames

Linear elastic analysis procedures are employed exclusively in the traditional seismic design of new structures and widely employed in the seismic assessment of existing structures. It is also a convenient tool for the initial checking of deformations in displacement‐based design. The limitations that should be imposed on linear elastic procedures have been evaluated in this study by comparing the deformation‐based response quantities obtained from response spectrum analysis with those from the nonlinear time history analysis. Both procedures were applied to different design variants of 5, 8, and 12 story moment frames, subjected to 20 strong motion components exhibiting a variety of intensities. Member plastic rotations and interstory drift ratios were employed as the basic response parameter in performance assessment. It has been found that average column demand to capacity ratio (DCR) (the ratio of flexural demand from linear elastic analysis to flexural capacity) and average beam DCR at the critical story are the most effective parameters in determining the validity range of linear elastic procedures in regular moment frames. Limiting values for these response parameters are proposed. Furthermore, amplification factors for member rotation demands predicted by the linear procedures are suggested for moment frames when these limiting values are exceeded. These factors ensure that the amplified linear elastic rotations are not smaller than 84 percentile (mean – 1sigma) of the rotations obtained from nonlinear time history analysis. Copyright © 2015 John Wiley & Sons, Ltd.