Two-stage metamorphic evolution of the Bemarivo Belt of northern Madagascar: constraints from reaction textures and in situ monazite dating

New results on the pressure–temperature–time evolution, deduced from conventional geothermobarometry and in situ U‐Th‐total Pb dating of monazite, are presented for the Bemarivo Belt in northern Madagascar. The belt is subdivided into a northern part consisting of low‐grade metamorphic epicontinental series and a southern part made up of granulite facies metapelites. The prograde metamorphic stage of the latter unit is preserved by kyanite inclusions in garnet, which is in agreement with results of the garnet (core)‐alumosilicate‐quartz‐plagioclase (inclusions in garnet; GASP) equilibrium. The peak metamorphic stage is characterized by ultrahigh temperatures of ～900–950 °C and pressures of ～9 kbar, deduced from GASP equilibria and feldspar thermometry. In proximity to charnockite bodies, garnet‐sillimanite‐bearing metapelites contain aluminous orthopyroxene (max. 8.0 wt% Al₂O₃) pointing to even higher temperatures of ～970 °C. Peak metamorphism is followed by near‐isothermal decompression to pressures of 5–7 kbar and subsequent near‐isobaric cooling, which is demonstrated by the extensive late‐stage formation of cordierite around garnet. Internal textures and differences in chemistry of metapelitic monazite point to a polyphasic growth history. Monazite with magmatically zoned cores is rarely preserved, and gives an age of c. 737 ± 19 Ma, interpreted as the maximum age of sedimentation. Two metamorphic stages are dated: M1 monazite cores range from 563 ± 28 Ma to 532 ± 23 Ma, representing the collisional event, and M2 monazite rims (521 ± 25 Ma to 513 ± 14 Ma), interpreted as grown during peak metamorphic temperatures. These are among the youngest ages reported for high‐grade metamorphism in Madagascar, and are supposed to reflect the Pan‐African attachment of the Bemarivo Belt to the Gondwana supercontinent during its final amalgamation stage. In the course of this, the southern Bemarivo Belt was buried to a depth of >25 km. Approximately 25–30 Myr later, the rocks underwent heating, interpreted to be due to magmatic underplating, and uplift. Presumably, the northern part of the belt was also affected by this tectonism, but buried to a lower depth, and therefore metamorphosed to lower grades.     

Assessment of spatial variations in water quality of Garra River at Shahjahanpur,Ganga Basin,India

Arabian Journal of Geosciences - A comprehensive study on the chemical considerations of thermal waters (springs and geothermal wells) on the performance of solute geothermometers in predicting the...     

Protection of marine birds and turtles at St Brandon’s Rock,Indian Ocean,requires conservation of the entire atoll

A survey of seabirds and turtles at St Brandon’s Rock, 400 km north of Mauritius, was undertaken in 2010. We estimated that 1 084 191 seabirds comprising seven breeding species and excluding non-breeders were present at the archipelago and we counted 279 turtle tracks and nesting pits of green turtles Chelonia mydas. Hawksbill turtles Eretmochelys imbricata were also present. Analyses of 30 different islets that make up the atoll showed that the seabird species mostly partitioned their use of islets based on islet size, with four species preferring larger islets and two species preferring smaller islets. Alien species introduced historically are still present and other threats, such as shipwrecks, remain. We propose conservation and other measures that should adequately protect the birds, turtles and coral reef by treating the atoll as a system.     

Diagenetic model of carbonate rocks of Guri Member of Mishan Formation (Lower to Middle Miocene) SE Zagros basin,Iran

In order to understand the post-depositional history of carbonate rocks of Guri Member (Lower to Middle Miocene), three stratigraphic sections were selected in north Bandar-Abbas in southeast of Iran. Sampling was carried out, analyzed for selective parameters such as oxygen and carbon isotopic compositions (δ¹⁸O and δ¹³C) and interpreted in the present study. We recognized several diagenetic processes including micritization, cementation, neomorphism, compaction, dissolution, silicification, dolomitization, fracturing and vein filling. Some of the diagenetic processes occurred at different conditions, so in order to achieve precise interpretation, samples from different carbonate components such as, micrite, fracture cement, solution pore cement, intergranular cement, and some biotic allochems were analyzed. In this study micrite samples were subdivided into two groups including micro-spary and micrite. They were recognized under Cathodoluminescence microscope. In addition, micrite samples were classified into five groups based on their depositional environments: supratidal, lagoon, coral bar, open sea, and open basin. There were minor changes in stable isotope ratios based on the sedimentary environments, stratigraphy successions, and micro-spary or micrite properties. In this study, similar calcite cements in petrography studies were differentiated by stable isotope data. Those calcite cements have formed in different diagenetic environments such as meteoric and burial cements. Paragenetic sequence of carbonate rocks were interpreted by integration of petrographic and isotopic studies. We have reconstructed diagenetic models of Guri Member into four stages including marine, meteoric, burial, and uplifting.     

Artificial neural network simulation for prediction of suspended sediment concentration in the River Ramganga,Ganges Basin,India

The relation between the water discharge (Q) and suspended sediment concentration (SSC) of the River Ramganga at Bareilly, Uttar Pradesh, in the Himalayas, has been modeled using Artificial Neural Networks (ANNs). The current study validates the practical capability and usefulness of this tool for simulating complex nonlinear, real world, river system processes in the Himalayan scenario. The modeling approach is based on the time series data collected from January to December (2008-2010) for Q and SSC. Three ANNs (T1-T3) with different network configurations have been developed and trained using the Levenberg Marquardt Back Propagation Algorithm in the Matlab routines. Networks were optimized using the enumeration technique, and, finally, the best network is used to predict the SSC values for the year 2011. The values thus obtained through the ANN model are compared with the observed values of SSC. The coefficient of determination (R2), for the optimal network was found to be 0.99. The study not only provides insight into ANN modeling in the Himalayan river scenario, but it also focuses on the importance of understanding a river basin and the factors that affect the SSC, before attempting to model it. Despite the temporal variations in the study area, it is possible to model and successfully predict the SSC values with very simplistic ANN models.     

Biogeochemical records of paleoenvironmental changes in Nainital Lake,Kumaun Himalayas,India

Rapid urbanization and increased tourism around Nainital Lake in the Kumaun Himalayan region in north India has raised concerns about sediment and water pollution. Lead-210 dated sediment cores from the lake represent ~95 years of accumulation and yield a mean sedimentation rate of ~4.7 mm year⁻¹. Total organic carbon (TOC), percent N and S and their atomic C/N and C/S ratios, stable isotopes (δ¹³C, δ¹⁵N, and δ³⁴S), and specific biomarkers (n-alkanes and pigments) were measured in the core. Organic matter is primarily derived from in-lake algal production and TOC flux varies from 1.0 to 3.5 g m⁻² year⁻¹. Sediments are anoxic (Eh −328 to −187 mV) and have low (0.10–0.30 g m⁻² year⁻¹) N, but high (0.37–1.0 g m⁻² year⁻¹) S flux. Shifts in δ¹³C, δ¹⁵N, and δ³⁴S suggest in-lake microbial processes dominated by denitrification and sulfate reduction. The sediments are dominated by short-chain hydrocarbons with low Carbon Preference Index values. The pigments indicate a gradual shift to cyanobacterial domination of the phytoplankton community in recent years. Despite an increase in external input of nutrients, the trophic state of the lake has remained largely unchanged, and the perceived human-induced impacts are limited.     

Relics of the Mozambique Ocean in the central East African Orogen: evidence from the Vohibory Block of southern Madagascar

The Vohibory Block of south‐western Madagascar is part of the East African Orogen, the formation of which is related to the assembly of the Gondwana supercontinent. It is dominated by metabasic rocks, which have chemical compositions similar to those of recent basalts from a mid‐ocean ridge, back‐arc setting and island‐arc setting. The age of formation of protolith basalts has been dated at 850–700 Ma by U–Pb SHRIMP analysis of magmatic cores in zircon, pointing to an origin related to the Neoproterozoic Mozambique Ocean. The metabasic rocks are interpreted as representing components of an island arc with an associated back‐arc basin. In the early stage of the Pan‐African orogeny, these rocks experienced high‐pressure amphibolite to granulite facies metamorphism (9–12 kbar, 750–880 °C), dated at 612 ± 5 Ma from metamorphic rims in zircon. The metamorphism was most likely related to accretion of the arc terrane to the margin of the Azania microcontinent (Proto‐Madagascar) and closure of the back‐arc basin. The main metamorphism is significantly older than high‐temperature metamorphism in other tectonic units of southern Madagascar, indicating a distinct tectono‐metamorphic history.     

Organic geochemical record of increased productivity in Lake Naukuchiyatal, Kumaun Himalayas, India

Organic geochemical proxies have been studied in a 45-cm-long core retrieved from Lake Naukuchiyatal in Kumaun Himalayas, India. Increase in TOC, N, hydrocarbons and pigments concentration from bottom to surface sediments of the core indicates increase in the lake productivity. Stable isotopes (δ¹³C and δ ¹⁵ N), biomarkers (TAR, CPI and n-ΣC_15,17,19) and C/N atomic (between 9 and 12) suggest dominance of algal derived organic matter in these sediments. Decrease in organic δ¹³C values (between ?27 and ?31‰) in surface sediments indicate influence of sewage and land runoff in shifting organic δ¹³C values, whereas low (between ?0.23 and 2.2‰) δ¹⁵N values together with high pigment concentrations (zeaxanthin and echinenone) represent dominance of cyanobacteria in the lake.     

Geochemistry,dissolved elemental flux rates,and dissolution kinetics of lithologies of Alaknanda and Bhagirathi rivers in Himalayas,India

Alaknanda and Bhagirathi (AB) river basins in the Himalayan region in India expose lithologies comprising mainly of granites, low–high-grade metamorphics, shales and carbonates which, in conjunction with the monsoon rains and glacial melt, control water chemistry and dissolved elemental flux rates. In the present study, we monitored two locations: (a) Srinagar on the Alaknanda river and (b) Maneri on the Bhagirathi river for daily variations in total suspended sediments, major ions and dissolved silica over one complete year (July 2004–June 2005). Based on long-term discharge data, discharge-weighted composition and dissolved elemental flux rates (with respect to Ca, Mg, HCO₃, Si) of the river were estimated. The information thus obtained has substantially added up to the existing chemical data of these rivers and has refined the flux rates. Our high-frequency samples provide informations such as (a) water chemical compositions that show a large temporal and spatial variation and (b) carbonate lithology that controls water chemistry predominantly. The dissolution kinetics of various lithologies namely leucogranite, gneiss, quartzite, phyllite and shale of the AB river basins were studied through batch experiments at controlled temperature (25 and 5°C) and pH (8.4) condition. In laboratory, these lithologies undergo slow rates of dissolution (10⁻¹³ to 10⁻¹⁵ mol/m² s), while field weathering rates based on dissolved elemental flux rates in the AB rivers are much higher (10⁻⁸ to 10⁻⁹ mol/m² s). Extremely high physical weathering rates in AB rivers, which enhance chemical weathering significantly, mainly attribute this wide discrepancy in laboratory-derived rates of representative basin rocks and dissolved elemental fluxes in the field. However, laboratory-simulated experiments facilitate to quantify elemental release rates, understand the kinetics of the dissolution reactions, and compare their roles at individual level.