Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.     

Tsunamis generated by landslides at the coast of conical islands: experimental benchmark dataset for mathematical model validation

This paper presents a new experimental campaign aimed at reproducing tsunamis generated by landslides at the flank of conical islands. In order to describe in high details the wave field around the island a special acquisition system, which consists of both fixed and movable wave gauges, has been employed. Indeed, each experiment has been repeated several times by changing the configuration of the movable gauges, then obtaining a single virtual experiment with high spatial resolution measurements. Fixed run-up gauges measure the waves at fixed locations to statistically quantify the repeatability of the experiments. Selected experimental results are illustrated within the paper that is mainly aimed at defining a benchmark dataset, available on request, for the development/calibration/validation of analytical and numerical models of tsunamis generated by landslides.     

Mantle source heterogeneity in the Campanian Region (South Italy) as inferred from geochemical and isotopic features of mafic volcanic rocks with shoshonitic affinity

Summary Major, trace element and Sr-Nd-isotopic data on mafic volcanic rocks with shoshonitic affinity from the islands of Procida and Ventotene (Campanian Region, South Italy) are reported. Within-suite chemical and isotopic variations are interpreted in terms of open system differentiation processes held responsible for enrichment in a number of trace elements and for radiogenic Sr observed in both Procida and Ventotene volcanic sequences. Conversely, trace element contents and Sr-Nd-isotopic compositions of the least-evolved among the investigated samples are thought to reflect source region characteristics with only negligible crustal contamination of the primary magmas.The data support an origin from distinct source regions for the primary magmas. In the case of Ventotene, the source would have been asthenospheric and/or lithospheric mantle with features similar to transitional mid-ocean ridge basalts (T-MORB), modified by enriching agents made up mainly of subducted slab-released components coming from marly sediments (about 7%) similar to cherts from Tuscan Apennines plus a limestone contribution. In the case of Procida, the source would have been asthenospheric and/or lithospheric mantle with a slightly more enriched T-MORB-like feature with respect to Ventotene, modified by slab-derived enriching agents, likely represented by a small amount of sediments (about 2.5%) of oceanic nature (mostly terrigenous/pelagic). These differences are constrained by lower Zr/Nb, Y/Nb, Sc/Nb, V/Nb, LILE/HFSE, LREE/HFSE and⁸⁷Sr/⁸⁶Sr, higher Ba/La and¹⁴³Nd/¹⁴⁴Nd ratios, as well as by the lack of a detectable negative Eu anomaly, in the least-evolved volcanic rocks of Procida, with respect to those of Ventotene, which show conversely a significant negative Eu anomaly. Thus, a sharp heterogeneity exists in the mantle beneath the Campanian Region. It is thought to be the consequence of two different slabs which are in contact along the Volturno River Plain tectonic line: a continental slab, seismically inactive, descending beneath the Latium Region, and an oceanic slab, seismically active, descending beneath the Calabria, up to the Campanian Region.

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Résumé De nouvelles analyses géochimiques d'éléments majeurs et en traces ainsi que des rapports isotopiques du Sr et du Nd sont été obtenues sur des roches volcaniques mafiques à affinité shoshonitiques provenant des îles de Procida et Ventotene (Région Campanienne, Italie du Sud). Les variations géochimiques et isotopiques observées au sein des séries volcaniques de ces deux îles sont interprétées en terme de processus de différenciation en système ouvert, tenu pour responsable d'un enrichissement d'un certain nombre d'éléments en traces et de leur composition en Sr radiogénique. Cependant, les teneurs en éléments traces et les compositions isotopiques en Sr et Nd des échantillons les moins évolués parmi ceux étudiés reflètent les caractéristiques de leur source, avec une contamination crustale très négligeable des magmas primitifs.Ces données démontrent que des sources distinctes sont à l'origine des magmas primitifs. Pour Ventotene, cette source doit être un manteau asthénosphérique et/ou lithosphérique dont la signature est similaire à celle de basaltes transitionnels de dorsale océanique (T MORB), légèrement enrichie en éléments dérivants d'une croûte plongeant dans une subduction comme des sédiments mameux (pour environ 7%) analogues aux cherts des Appenins de Toscane et comportant un apport en calcaire. Dans le cas de Procida, cette source doit être un manteau asthénosphérique et/ou lithosphérique montrant une signature de type T-MORB légèrement plus enrichie qu' à Ventotene, également modifiée par un apport venant d'une croûte en subduction, probablement une faible quantité (environ 2.5%) de sédiments de nature océanique (principalement terrigène/pélagique). Ces différences sont attestées par des rapports Zr/Nb, Y/Nb, Sc/Nb, V/Nb, LILE/HFSE, LREE/HSFE and⁸⁷Sr/⁸⁶Sr plus bas et des rapports Ba/La et¹⁴³Nd/¹⁴⁴Nd plus harts, ainsi que par l'absence d'une anomalie en Eu dans les compositions des roches volcaniques les moins évoluées de Procida par rapport à celles de Ventotene, qui elles, au contraire, montrent une anomalie en Eu significative.Ainsi, une importante hétérogénéité du manteau existe sous la Campanie. Cette hétérogénéité doit être la conséquence de la nature différente des croûtes en subduction et qui sont en contact le long de la ligne tectonique de la plaine de la rivière Volturno: an Nord-Ouest, une croûte continentale, sismiquement inactive, plonge sous le Latium alors qu'au Sud-Est, une croûte océanique, sismiquement active, plonge sous la Calabre et jusque sous la Campanie.

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With 9 Figures     

Upper-miocene submarine volcanism in the strait of sicily (banco senza nome)

Two basaltic fragments dredged from a volcanic seamount in the Sicilian continental slope of the Strait of Sicily show petrochemical features typical of within plate alkalibasaltic lavas and K/Ar age of about 10 m.y. The data represent the first volcanic evidence of Upper Miocene tensional tectonics in this sector of the African plate.     

Geotectonic settings of miocene-quaternary volcanism in and around the eastern Tyrrhenian sea border (Italy) as deduced from major element geochemistry

The volcanic rocks along the south-eastern and eastern Tyrrhenian border of Italy have been classified as converging plate margin magma types by using discriminant functions based on major element patterns. These rocks belong to calc-alkaline and shoshonitic associations (shoshonites, and predominant leucitic rocks) ranging in age from Upper Miocene to, mostly, Quaternary. According to the same method of classification, the remaining Italian volcanic rocks — alkali-sodic and subordinate tholeiitic basalts — around the Tyrrhenian border are found to be rocks of the tensional type of Mesozoic to prevailingly Quaternary age. The volcanic materials of the 650 km long SE and E Tyrrhenian border can be related to the convergence of the African-Adriatic and Tyrrhenian plates.     

Light curve analysis of the short period eclipsing binary RT and

We have analysed the 1978 UBV photoelectric observations of the short-period (RS CVn type) binary system RT And, using the rectifiable methods of Russell and Merrill (1952) and Kitamura (1965). The primary minimum is a transit. The solutions allow us to classify the system as a detached one, but a certain disagreement results with respect to solutions of previous epochs. A graphical test of the reliability of the solution is given.     

Application of wavelet transform analysis to landslide generated waves

The aim of this paper is to illustrate the results of a preliminary study on aerial landslide-generated waves, which has been mainly intended to establish a method for analyzing water surface records. Some simple physical experiments, reproducing the Scott Russell's wave generator, were carried out in a small two-dimensional wave flume; the Wavelet Transform (WT) is applied to analyze wave measurements and it is shown that useful information can be obtained by means of this technique. The celerity of impulsively generated waves, reflection by an overflow structure and seiching phenomena of the flume are studied. A discussion of the results along with some remarks about ongoing research is also given.     

Recent theoretical results on coronal heating

The scenario of magnetohydrodynamic turbulence in connection with coronal active regions has been actively investigated in recent years. According to this viewpoint, a turbulent regime is driven by footpoint motions and the incoming energy is efficiently transferred to small scales due to a direct energy cascade. The development of fine scales to enhance the dissipation of either waves or DC currents is therefore a natural outcome of turbulent models. Numerical integrations of the reduced magnetohydrodynamic equations are performed to simulate the dynamics of coronal loops driven at their bases by footpoint motions. These simulations show that a stationary turbulent regime is reached after a few photospheric times, displaying a broadband power spectrum and a dissipation rate consistent with the energy loss rates of the plasma confined in these loops. Also, the functional dependence of the stationary heating rate with the physical parameters of the problem is obtained, which might be useful for an observational test of this theoretical framework.     

UU CNC and VZ PSC,contact systems before the common envelope phase?

We have analyzed the existing photoelectric light curves of twoK-type binary systems: UU Cnc, with a period of about 100 days, and VZ Psc, with a period of about 6 hours. Both show a large overcontact (38% for UU Cnc, 56% for VZ Psc) and a large temperature difference between components (T1500 K and 1100 K, respectively). In the case of VZ Psc, the variability is due only to the non-spherical shape, i.e., no eclipse occurs, but the determination of the photometric solution is made possible by the existence of a spectroscopic mass ratio. We find that UU Cnc is now probably undergoing Case C mass transfer in a dynamical time-scale, with the mass ratio reversal having already occurred; the system is in contact, and is likely to evolve to a 100% filling factor, that is the so-called pre-common envelope phase, a unique case never observed before. The situation for VZ Psc is more uncertain, but a similar, although not identical, possibility exists.Associated with the Istituto Nazionale Fisica Nucleare, Italy.On leave from N. Copernicus Astronomical Center, Polish Academy of Sciences, Warsaw, Poland.     

Continental collision and basin opening in Southern Italy: a new plate subduction in the Tyrrhenian Sea?

An analysis of the spatial distribution of the seismicity of the southern Tyrrhenian Sea is presented with the aim of putting constraints on the geometry of the complex Benioff zone of this area by relocating the earthquakes that occurred in the period 1985–1990. The data set used in this analysis is based on information from ING, ISC, and NEIS databases.

In order to ensure the quality of epi/hypocentral locations, we based our selection of earthquakes on both the available number of P- and S-readings (at least eight P- and two S-pickings) and the epicentral distances of the stations reporting the event (< 5°). Such a selection enabled us to obtain a catalogue of 450 well-located events with focal depths of up to 500 km.

The seismogenetic volumes estimated from the distribution of hypocentres of the whole seismicity analysed were interpreted according to a recent geodynamic model proposed for this area. This has led us to the hypothesis of an active NW-SE-oriented subduction of the lithosphere generated and stressed by the opening of the Tyrrhenian Basin.