Deglaciation of the younger dryas or Loch Lomond Stadial ice-field in the northern Highlands,Scotland

When viewed from the air, Scottish ‘hummocky moraine’ can be resolved into a series of linear ridges that resemble those found at the margins of actively retreating glaciers today. Recent work has supported the interpretation of these linear ridges as ice-marginal landforms and the authors believe that the majority of ‘hummocky moraine’ deposits can be interpreted in this way. Consequently the pattern of deglaciation can be established fairly precisely from the pattern of linear ridges. This approach is applied to the landforms of the northern part of the Loch Lomond Stadial ice-field in order to reconstruct the regional pattern of deglaciation. This leads to important inferences about the significance of topographic control during deglaciation and more importantly it provides fresh insight into the environment of the British Isles during the Loch Lomond Stadial.     

The dissolution of opaline silica of diatom tests in sea water

Two different series of measurements have been made of the solubilities and rates of solution in sea water of acid-washed siliceous tests of the diatomsThalassiosira decipiens andRhizosolenia hebetata. The kinetic approach was carried out on the assumption that the tests behave as identical solid spheres. If the tests were present in considerable excess over that required for saturation of the water with respect to silica, the dissolution obeyed first order reaction kinetics and its rate was proportional to the surface area of the exposed tests. When the tests were not in excess the kinetics of dissolution appeared to be more complex. This was considered to be due to a decrease in specific surface area as dissolution proceeded. An expression developed to allow for the change of surface area as a sphere dissolves offers a partial explanation of the kinetics when the tests are not present in excess.     

Rates of Deglaciation during the Last Glaciation and Holocene in the Cordillera Vilcanota-Quelccaya Ice Cap Region, Southeastern Perú

Moraine chronology is combined with digital topography to model deglacial rates of paleoglacier volumes in both the Huancané Valley on the west side of the Quelccaya Ice Cap and the Upismayo Valley on the northwest side of the Cordillera Vilcanota. The fastest rates of deglaciation (39×10⁻⁵ to 114×10⁻⁵ km³ yr⁻¹ and 112×10⁻⁵ to 247×10⁻⁵ km³ yr⁻¹ for each valley, respectively) were calculated for the most recent paleoglaciers, corresponding to the last few centuries. These results are consistent with observations in the Venezuelan Andes showing high rates of deglaciation since the Little Ice Age. These rates also fall within the range of 20th century rates of deglaciation measured on the Quelccaya Ice Cap (29×10⁻⁵ to 220×10⁻⁵ km³ yr⁻¹, Brecher and Thompson, 1993; Thompson, 2000). These results imply that rates of deglaciation may fluctuate significantly over time and that high rates of deglaciation may not be exclusive to the late 20th century. Equilibrium line altitude (ELA) depressions for the ice volumes of the last glaciation modeled here were computed as 230 m for the Quelccaya Ice Cap and 170 m for the Cordillera Vilcanota. Maximum ELA depressions are lower than previously published: <500 m for the Cordillera Vilcanota and <400 m for the Quelccaya Ice Cap. These lower values could imply a topographic control over paleoglacier extent.     

Building Web-Based Spatial Information Solutions around Open Specifications and Open Source Software

Geographic Information Systems (GIS) are moving from isolated, standalone, monolithic, proprietary systems working in a client‐server architecture to smaller web‐based applications and components offering specific geo‐processing functionality and transparently exchanging data among them. Interoperability is at the core of this new web services model. Compliance with Open Specifications (OS) enables interoperability. Web‐GIS software's high costs, complexity and special requirements have prevented many organizations from deploying their data and geo‐processing capabilities over the World Wide Web. There are no‐cost Open Source Software (OSS) alternatives to proprietary software for operating systems, web servers, and Relational Database Management Systems. We tested the potential of the combined use of OS and OSS to create web‐based spatial information solutions. We present in detail the steps taken in creating a prototype system to support land use planning in Mexico with web‐based geo‐processing capabilities currently not present in commercial web‐GIS products. We show that the process is straightforward and accessible to a broad audience of geographic information scientists and developers. We conclude that OS and OSS allow the development of web‐based spatial information solutions that are low‐cost, simple to implement, compatible with existing information technology infrastructure, and have the potential of interoperating with other systems and applications in the future.     

Temperature and Salinity Effects on Alkenone Ratios Measured in Surface Sediments from the Indian Ocean

We compare alkenone unsaturation ratios measured on recent sediments from the Indian Ocean (20°N–45°S) with modern sea oceanographic parameters. For each of the core sites we estimated average seasonal cycles of sea surface temperature (SST) and salinity, which we then weighted with the seasonal productivity cycle derived from chlorophyll satellite imagery. The unsaturation index (U₃₇^K′) ranges from 0.2 to 1 and correlates with water temperature but not with salinity. TheU₃₇^K′versus SST relationship for Indian Ocean sediments (U₃₇^K′= 0.033 SST + 0.05) is similar to what has been observed for core tops from the Pacific and Atlantic oceans and the Black Sea. A global compilation for core tops givesU₃₇^K′= 0.031 T + 0.084 (R= 0.98), which is close to a previously reported calibration based on particulate organic matter from the water column. For temperatures between 24° and 29°C, however, the slope seems to decrease to about 0.02U₃₇^K′unit/°C. For Indian Ocean core tops, the ratios of total C₃₇alkenones/total C₃₈alkenones and the slope of theU₃₇^K′-SST relationship are similar to those previously observed for cultures ofEmiliania huxleyibut different from those previously published forGephyrocapsa oceanica.EitherE. huxleyiis a major producer of alkenones in the Indian Ocean or strains ofG. oceanicaliving in the northern Indian Ocean behave differently from the one cultured. In contrast with coccolithophorid assemblages, the ratios of C₃₇alkenones to total C₃₈alkenones lack clear geographic pattern in the Indian Ocean.     

Effects of temperature on the crystal structure of epidote: a neutron single-crystal diffraction study at 293 and 1,070 K

The effects of temperature on the crystal structure of a natural epidote [Ca_1.925 Fe_0.745Al_2.265Ti_0.004Si_3.037O₁₂(OH), a = 8.890(6), b = 5.630(4), c = 10.150(6) Å and β = 115.36(5)°, Sp. Gr. P2₁ /m] have been investigated by means of neutron single-crystal diffraction at 293 and 1,070 K. At room conditions, the structural refinement confirms the presence of Fe³⁺ at the M₃ site [%Fe(M3) = 73.1(8)%] and all attempts to refine the amount of Fe at the M(1) site were unsuccessful. Only one independent proton site was located. Two possible hydrogen bonds, with O(2) and O(4) as acceptors [i.e. O(10)–H(1)···O(2) and O(10)–H(1)···O(4)], occur. However, the topological configuration of the bonds suggests that the O(10)–H(1)···O(4) is energetically more favourable, as H(1)···O(4) = 1.9731(28) Å, O(10)···O(4) = 2.9318(22) Å and O(10)–H(1)···O4 = 166.7(2)°, whereas H(1)···O(2) = 2.5921(23) Å, O(10)···O(2) = 2.8221(17) Å and O(10)–H(1)···O2 = 93.3(1)°. The O(10)–H(1) bond distance corrected for “riding motion” is 0.9943 Å. The diffraction data at 1,070 K show that epidote is stable within the T-range investigated, and that its crystallinity is maintained. A positive thermal expansion is observed along all the three crystallographic axes. At 1,070 K the structural refinement again shows that Fe³⁺ share the M(3) site along with Al³⁺ [%Fe(M3)_1,070K = 74(2)%]. The refined amount of Fe³⁺ at the M(1) is not significant [%Fe(M1)_1,070K = 1(2)%]. The tetrahedral and octahedral bond distances and angles show a slight distortion of the polyhedra at high-T, but a significant increase of the bond distances compared to those at room temperature is observed, especially for bond distances corrected for “rigid body motions”. The high-T conditions also affect the inter-polyhedral configurations: the bridging angle Si(2)–O(9)–Si(1) of the Si₂O₇ group increases significantly with T. The high-T structure refinement shows that no dehydration effect occurs at least within the T-range investigated. The configuration of the H-bonding is basically maintained with temperature. However, the hydrogen bond strength changes at 1,070 K, as the O(10)···O(4) and H(1)···O(4) distances are slightly longer than those at 293 K. The anisotropic displacement parameters of the proton site are significantly larger than those at room condition. Reasons for the thermal stability of epidote up to 1,070 K observed in this study, the absence of dehydration and/or non-convergent ordering of Al and Fe³⁺ between different octahedral sites and/or convergent ordering on M(3) are discussed.     

Landscape and prehistoric chronology of West-Central Jordan

Remnant lake and stream terraces of the Wadi el Hasa (west-central Jordan) are associated with in situ prehistoric sites spanning > 100,000 years. Eighteen radiocarbon dates from cultural and geological deposits on the terraces facilitate the first comprehensive prehistoric landscape chronology for the southern Levant east of the Jordan Rift. In the eastern Hasa basin, the uppermost of three cut and fill surfaces (>20 m) is linked to massive fossil spring deposits and an early Middle Paleolithic occupation (100,000–70,000 B. P.), suggestive of considerably wetter climates. A later Middle Paleolithic occupation may be synchronous with the emergence of Pleistocene Lake Hasa (ca. 70,000 B. P.). Peak lake levels were attained 40,000 years ago. Dates proliferate after 25,000 B. P. and register recession of Lake Hasa (ca. 20,000 B. P.), an intervening erosional phase, and the initiation of complex humid-desiccation cycles for the terminal Pleistocene—Holocene (17,000–9,000 B. P.). The contemporary Wadi el Hasa channel began aggrading its floodplain after 8000 B. P. and was incised to its present depths 1000–500 years ago. The prehistoric landscape history of the Hasa drainage is broadly synchronous with sequences in the Rift Valley and Negev desert and offers baseline chronologies for the Late Quaternary of eastern Jordan and the Arabian peninsula. © 1994 John Wiley & Sons, Inc.