Prediction of the calcium carbonate budget in a sedimentary basin: A “source-to-sink” approach applied to Great Salt Lake,Utah, USA

Most source-to-sink studies typically focus on the dynamics of clastic sediments and consider erosion, transport and deposition of sediment particles as the sole contributors. Although often neglected, dissolved solids produced by weathering processes contribute significantly in the sedimentary dynamics of basins, supporting chemical and/or biological precipitation. Calcium ions are usually a major dissolved constituent of water drained through the watershed and may facilitate the precipitation of calcium carbonate when supersaturating conditions are reached. The high mobility of Ca²⁺ ions may cause outflow from an open system and consequently loss. In contrast, in closed basins, all dissolved (i.e. non-volatile) inputs converge at the lowest point of the basin. The endoreic Great Salt Lake basin constitutes an excellent natural laboratory to study the dynamics of calcium on a basin scale, from the erosion and transport through the watershed to the sink, including sedimentation in lake's waterbody. The current investigation focused on the Holocene epoch. Despite successive lake level fluctuations (amplitude around 10 m), the average water level seems to have not been affected by any significant long-term change (i.e. no increasing or decreasing trend, but fairly stable across the Holocene). Weathering of calcium-rich minerals in the watershed mobilizes Ca²⁺ ions that are transported by surface streams and subsurface flow to the Great Salt Lake (GSL). Monitoring data of these flows was corrected for recent anthropogenic activity (river management) and combined with direct precipitation (i.e. rain and snow) and atmospheric dust income into the lake, allowing estimating the amount of calcium delivered to the GSL. These values were then extrapolated through the Holocene period and compared to the estimated amount of calcium stored in GSL water column, porewater and sediments (using hydrochemical, mapping, coring and petrophysical estimates). The similar estimate of calcium delivered (4.88 Gt) and calcium stored (3.94 Gt) is consistent with the premise of the source-to-sink approach: a mass balance between eroded and transported compounds and the sinks. The amount of calcium deposited in the basin can therefore be predicted indirectly from the different inputs, which can be assessed with more confidence. When monitoring is unavailable (e.g. in the fossil record), the geodynamic context, the average lithology of the watershed and the bioclimatic classification of an endoreic basin are alternative properties that may be used to estimate the inputs. We show that this approach is sufficiently accurate to predict the amount of calcium captured in a basin and can be extended to the whole fossil record and inform on the storage of calcium.     

Paleolimnological assessment of human impacts in Lake Blanca, SE Uruguay

Paleolimnological techniques were used to assess human impacts onLake Blanca, a small (0.6 km²), coastal fresh waterbodyin southern Uruguay, which is the drinking water source for 100,000 localresidents. We retrieved a core that extends to about 1100 ¹⁴Cyr BP. ²¹⁰Pb ages, organic mater, CO₃, totalcarbon, nutrients, fossil pigments and diatoms allowed us to establishlimnological conditions before and after cultural impacts. Soil removal(1880–1960) and intensive cattle and sheep grazing (1943–1966) ledto gully formation in the catchment. This watershed erosion resulted inincreased sedimentation rates. The aquatic system appeared to be mesotrophicwith dominance of epibenthic diatoms until 1966, at which timeeutrophication intensified with forestry activities. Increases in nutrients, aswell as blooms of planktonic diatoms, were observed. During the last decade,tourist/urban development as well as high drinking water demand caused areduction in lake area. Subsequent marked increases in rainfall led to furtherphytoplankton blooms and macrophyte proliferation.     

Chemostratigraphy of the Tamengo Formation (Corumbá Group,Brazil): A contribution to the calibration of the Ediacaran carbon-isotope curve

The Corumbá Group, cropping out in the southern Paraguay Belt in Brazil, is one of the most complete Ediacaran sedimentary archives of palaeogeographic, climatic, biogeochemical and biotic evolution in southwestern Gondwana. The unit hosts a rich fossil record, including acritarchs, vendotaenids (Vendotaenia, Eoholynia), soft-bodied metazoans (Corumbella) and skeletal fossils (Cloudina, Titanotheca). The Tamengo Formation, made up mainly of limestones and marls, provides a rich bio- and chemostratigraphic record. Several outcrops, formerly assigned to the Cuiabá Group, are here included in the Tamengo Formation on the basis of lithological and chemostratigraphical criteria. High-resolution carbon isotopic analyses are reported for the Tamengo Formation, showing (from base to top): (1) a positive δ¹³C excursion to +4‰ PDB above post-glacial negative values, (2) a negative excursion to −3.5‰ associated with a marked regression and subsequent transgression, (3) a positive excursion to +5.5‰, and (4) a plateau characterized by δ¹³C around +3‰. A U-Pb SHRIMP zircon age of an ash bed interbedded in the upper part of the δ¹³C positive plateau yielded 543 ± 3 Ma, which is considered as the depositional age ( Babinski et al., 2008a). The positive plateau in the upper Tamengo Formation and the preceding positive excursion are ubiquitous features in several successions worldwide, including the Nama Group (Namibia), the Dengying Formation (South China) and the Nafun and Ara groups (Oman). This plateau is constrained between 542 and 551 Ma, thus consistent with the age of the upper Tamengo Formation. The negative excursion of the lower Tamengo Formation may be correlated to the Shuram–Wonoka negative anomaly, although δ¹³C values do not fall beyond −3.5‰ in the Brazilian sections. Sedimentary breccias occur just beneath this negative excursion in the lower Tamengo Formation. One possible interpretation of the origin of these breccias is a glacioeustatic sea-level fall, but a tectonic interpretation cannot be completely ruled out.     

The lacustrine microbial carbonate factory of the successive Lake Bonneville and Great Salt Lake,Utah, USA

The Bonneville Basin is a continental lacustrine system accommodating extensive microbial carbonate deposits corresponding to two distinct phases: the deep Lake Bonneville (30 000 to 11 500 ¹⁴C bp ) and the shallow Great Salt Lake (since 11 500 ¹⁴C bp ). A characterization of these microbial deposits and their associated sediments provides insights into their spatio‐temporal distribution patterns. The Bonneville phase preferentially displays vertical distribution of the microbial deposits resulting from high‐amplitude lake level variations. Due to the basin physiography, the microbial deposits were restricted to a narrow shoreline belt following Bonneville lake level variations. Carbonate production was more efficient during intervals of relative lake level stability as recorded by the formation of successive terraces. In contrast, the Great Salt Lake microbial deposits showed a great lateral distribution, linked to the modern flat bottom configuration. A low vertical distribution of the microbial deposits was the result of the shallow water depth combined with a low amplitude of lake level fluctuations. These younger microbial deposits display a higher diversity of fabrics and sizes. They are distributed along an extensive ‘shore to lake’ transect on a flat platform in relation to local and progressive accommodation space changes. Microbial deposits are temporally discontinuous throughout the lake history showing longer hiatuses during the Bonneville phase. The main parameters controlling the rate of carbonate production are related to the interaction between physical (kinetics of the mineral precipitation, lake water temperature and runoff), chemical (Ca²⁺, Mg²⁺ and HCO₃^? concentrations, Mg/Ca ratio, dilution and depletion) and/or biological (trophic) factors. The contrast in evolution of Lake Bonneville and Great Salt Lake microbial deposits during their lacustrine history leads to discussions on major chemical and climatic changes during this interval as well as the role of physiography. Furthermore, it provides novel insights into the composition, structure and formation of microbialite‐rich carbonate deposits under freshwater and hypersaline conditions.     

Earthquake detection probability within a seismically quiet area: application to the Bruchsal geothermal field

In applications such as oil and gas production, deep geothermal energy production, underground storage, and mining, it is common practice to implement local seismic networks to monitor and to mitigate induced seismicity. For this purpose, it is crucial to determine the capability of the network to detect a seismic event of predefined magnitude in the target area. The determination of the magnitude of completeness of a network is particularly required to properly interpret seismic monitoring results. We propose a method to compute the detection probability for existing local seismic networks, which (i) strictly follows the applied detection sequence; (ii) estimates the detection capability where seismicity has not yet occurred; and (iii) delivers the results in terms of probabilities. The procedure includes a calibration of a local magnitude scale using regional earthquakes recorded by the network and located outside the monitored area. It involves pre‐processing of the seismograms recorded at each station as performed during the triggering sequence, which is assumed based on amplitude thresholds. Then, the calibrated magnitude–distance–amplitude relations are extrapolated at short distances and combined to reproduce the network detection sequence. This generates a probability to detect a seismic event of a given magnitude at a specified location. This observation‐based approach is an alternative to a fully theoretical detection capability modelling and includes field conditions. Seismic wave attenuation by geometrical spreading and intrinsic attenuation, site effect, and instrumental responses are partly accounted for by the calibration. We apply this procedure on the seismic network deployed in the Bruchsal geothermal field (Germany). Although the system was in good working order, no induced seismicity was identified in the area between June 2010, when monitoring started, and November 2012. The recording of distant seismicity during this time period, however, allowed the application of the proposed procedure. According to the applied network detection parameters, the results indicate that the absence of seismicity can be interpreted as a 95% probability that no seismic event with M_L ≥ 0.7 occurred below the network at 2.4‐km depth, i.e., in the geothermal reservoir.     

Biogeochemical processes in a clay formation in situ experiment: Part E - Equilibrium controls on chemistry of pore water from the Opalinus Clay, Mont Terri Underground Research Laboratory, Switzerland

The chemistry of pore water (particularly pH and ionic strength) is an important property of clay rocks being considered as host rocks for long-term storage of radioactive waste. Pore waters in clay-rich rocks generally cannot be sampled directly. Instead, their chemistry must be found using laboratory-measured properties of core samples and geochemical modelling. Many such measurements have been made on samples from the Opalinus Clay from the Mont Terri Underground Research Laboratory (URL). Several boreholes in that URL yielded water samples against which pore water models have been calibrated. Following a first synthesis report published in 2003, this paper presents the evolution of the modelling approaches developed within Mont Terri URL scientific programs through the last decade (1997-2009). Models are compared to the composition of waters sampled during dedicated borehole experiments. Reanalysis of the models, parameters and database enabled the principal shortcomings of the previous modelling efforts to be overcome. The inability to model the K concentrations correctly with the measured cation exchange properties was found to be due to the use of an inappropriate selectivity coefficient for Na-K exchange; the inability to reproduce the measured carbonate chemistry and pH of the pore waters using mineral-water reactions alone was corrected by considering clay mineral equilibria. Re-examination of the measured Ca/Mg activity ratios and consideration of the mineralogical composition of the Opalinus Clay suggested that Ca/Mg cation exchange rather than dolomite saturation may control the ratio of these ions in solution. This re-examination also suggests that the Ca/Mg ratio decreases with increasing pore-water salinity. Several possible reasons for this are proposed. Moreover, it is demonstrated that feldspar equilibria must not be included in Opalinus Clay modelling because feldspars are present only in very small quantities in the formation and because Na/K ratios measured in pore water samples are inconsistent with feldspar saturation. The principal need to improve future modelling is additional or better data on rock properties, in particular: (i) a more detailed identification of phases in the Opalinus Clay that include redox-sensitive elements together with evaluation of their thermodynamic properties; (ii) an improved understanding of the distribution of celestite throughout the Opalinus Clay for Sr/SO₄ concentrations control; (iii) improvements in analytic and thermodynamic data for Ca-Mg rock cation exchange and mineral chemical properties and (iv) the measurement of composition and stability constants of clay minerals actually present in the formation.     

Analysis and automatic processing in near-field of eight 1992–1994 tsunamigenic earthquakes: Improvements towards real-time tsunami warning

We study eight tsunamigenic earthquakes of 1992–1994 with data from single near-field 3-component long-period stations. The analysis is made from the standpoint of tsunami warning by an automatic process which estimates the epicentral location and the seismic moment through the variable-period mantle magnitudeM _m . Simulations of early warning based on the real-time computation of the seismic moment are also tested with this system, which would give a justified warning in each region of tsunami potentiality. By exploiting the dependence of moment rate release with frequency, the system has the capability of recognizing both tsunami earthquakes such as the 1992 Nicaragua and 1994 Java events, as well as instances of the opposite case of low-frequency deficiency, interpreted as indicating a deeper than normal source (1993 Guam event). We report both the results of delayed-time processing of the near-field stations, and the actual real-time warnings at PPT, which confirm the former.     

C-, Sr-isotope and Hg chemostratigraphy of Neoproterozoic cap carbonates of the Sergipano Belt,Northeastern Brazil

Two cap carbonates overlying glaciogenic diamictites crop out extensively in the eastern Vaza Barris Domain of the Sergipano Belt, northeastern Brazil. They are represented by carbonates of the Jacoca Formation, resting on top of diamictite of the Ribeiropolis Formation, and by the Olhos D’Agua Formation (carbonates, organic-rich towards the top), which overlies diamictite of the Palestina Formation. These two sequences were deformed and metamorphosed at sub-greenschist facies-conditions during the Brasiliano cycle (650–600 Ma).