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Jean‐Michel Brazier Anne‐Dsire Schmitt Eric Pelt Damien Lemarchand Sophie Gangloff Tho Tacail Vincent Balter 《Geostandards and Geoanalytical Research》2020,44(2):331-348
This work presents new 87Sr/86Sr and δ88/86SrSRM987 isotopic values of thirteen mineral, vegetal and animal reference materials. Except for UB‐N, all our results are consistent with previously published data. Our results highlight intermediate precisions among the best presently published and a non‐significant systematic shift with the calculated δ88/86SrSRM987 mean values for the three most analysed reference materials in the literature (i.e., IAPSO, BCR‐2 and JCp‐1). By comparison with the literature and between two distinct digestions, a significant bias of δ88/86SrSRM987 values was highlighted for two reference materials (UB‐N and GS‐N). It has also been shown that digestion protocols (nitric and multi‐acid) have a moderate impact on the δ88/86SrSRM987 isotopic values for the Jls‐1 reference materials suggesting that a nitric acid digestion of carbonate can be used without significant bias from partial digestion of non‐carbonate impurities. Different δ88/86SrSRM987 values were measured after two independent Sr/matrix separations, according to the same protocol, for a fat‐rich organic reference material (BCR‐380R) and have been related to a potential post‐digestion heterogeneity. Finally, the δ88/86SrSRM987 value differences measured between animal‐vegetal and between coral‐seawater reference materials agree with the previously published results, highlighting an Sr isotopic fractionation along the trophic chain and during carbonate precipitation. 相似文献
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Determination of the Concentration of Carbonic Species in Natural Waters: Results from a World‐Wide Proficiency Test
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Mahendra P. Verma Enrique Portugal Sophie Gangloff María Aurora Armienta Dornadula Chandrasekharam Mayela Sanchez Roberto E. Renderos Miguel Juanco Robert van Geldern 《Geostandards and Geoanalytical Research》2015,39(2):233-255
The results of an international interlaboratory proficiency test for the determination of carbonic species are presented. Eight laboratories analysed twelve water samples (four synthetic waters, one lake water, four geothermal waters, one seawater and two petroleum waters) by two methods: (a) individual laboratory analytical procedure and (b) acid–base titration curves in tabular form following a standardised protocol. In case (b), the concentrations of carbonic species were calculated by the organiser using the (1) Hydrologists' method, (2) Geochemists' method and/or (3) initial pH and total alkalinity method. For synthetic waters, the averaged % trueness and precision of measurement of the two methods were (trueness = 7.6, precision = 9.4) and (9.0, 3.4) for total alkalinity, and (6.6, 31.0) and (7.8, 6.1) for carbonic alkalinity, respectively. This indicates that the total alkalinity calculation procedure is in general correct in the individual laboratory method, but the carbonic alkalinity calculation procedure has serious problems. The measurements of total alkalinity for lake and seawaters were in agreement in both the methods; however, the individual laboratory measurement method for geothermal and petroleum waters was conceptually incorrect. Thus, the analytical procedures for the determination of carbonic species were reviewed. To apply the Hydrologists' and/or Geochemists' methods, the location of NaHCO3EP and H2CO3EP is necessary, even for samples with pH lower than that of NaHCO3EP, and a backward titration curve after complete removal of CO2 must be performed. The initial pH and total alkalinity method is appropriate where a complete analysis of species that contribute to the alkalinity is known. 相似文献
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Christopher C. Harvey Michel Gangloff Todd King Christopher H. Perry D. Aaron Roberts James R. Thieman 《Earth Science Informatics》2008,1(1):5-13
As soon as the first data became available online over the Internet, it was obvious that different sites holding related datasets
should appear to the end user as a single data system, even if the data itself is stored at multiple locations. To achieve
this objective in the context of continuing parallel development of multiple data centres, in 2003 several actors in the realm
of space plasmas created the international consortium Space Physics Archive Search and Extract (SPASE). Since 2005 US participation
in SPASE has been supported by NASA, and early in 2006 NASA funded five new Virtual Observatories to cater for different aspects
of solar system plasma science. This paper outlines the current status of the SPASE effort, the opportunities it offers, its
specificities with respect to other parts of the astronomical virtual observatory, and the possibilities it offers for space
weather.
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Christopher C. HarveyEmail: |
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Peter Stille Anne-Désirée Schmitt François Labolle Marie-Claire Pierret Sophie Gangloff Florian Cobert Eric Lucot Florence Guéguen Laure Brioschi Marc Steinmann François Chabaux 《Comptes Rendus Geoscience》2012,344(5):297-311
The combination of the Sr, Nd and Pb isotope systems, recognized as tracers of sources, with the Ca isotope system, known to reveal biology-related fractionations, allowed us to test the reliability of spruce (Picea abies) growth rings as environmental archives through time (from 1916 to 1983) in a forest ecosystem affected by acid atmospheric deposition. Sr and Pb isotopes have already been applied in former tree-ring studies, whereas the suitability of Nd and Ca isotope systems is checked in the present article. Our Sr and Nd isotope data indicate an evolution in the cation origin with a geogenic origin for the oldest rings and an atmospheric origin for the youngest rings. Ca isotopes show, for their part, an isotopic homogeneity which could be linked to the very low weathering flux of Ca. Since this flux is weak the spruces’ root systems have pumped the Ca mainly from the organic matter-rich top-soil over the past century. In contrast, the annual growth rings studied are not reliable and suitable archives of past Pb pollution. 相似文献
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Pierre Gangloff 《Geoforum》1981,12(3):273-280
Evidence of villafranchian permafrost has been found at the southern end of the Rhine graben, 20km west of Basel. Two syngenetic ice-wedge casts were discovered in the “alluvions du Sundgau”. From a stratigraphical point of view, these coarse gravels were deposited after the Miocene and before the Günz glaciation. The occurrence of syngenetic periglacial structures shows that they must be of Pleistocene (Villafranchian) age. A SEM study of sand from the infilling of one of the cryogenic structures showed numerous marks of glacial origin on the quartz grains. They are indicative of a pre-Günz glaciation in the Alps. It is suggested that permafrost in villafranchian time developed only on the fringe of the alpine glaciation, but further studies will be needed for a better picture of villafranchian palaeogeography. 相似文献
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