Preferential leaching and the age of radiation damage from alpha decay in minerals

Preferential release into solution of radionuclides that result from alpha decay is a contributor to natural isotopic disequilibrium. Such release is critical to geochemical understanding of alpha-decay products and would be an undesirable characteristic of solidified nuclear waste in deep geological formations. Spontaneous annealing of the radiation damage that is responsible for the preferential release is shown to diminish the effect in thorianite and uraninite which we have found to be 550 to 1000 M.y. old, respectively. Leaching experiments and measurements of the thorium and uranium isotopes show that there is strongly enhanced release of short-lived ²²⁸Th relative to ²³²Th, but only slight enhancement of long-lived ²³⁴U and ²³⁰Th relative to ²³⁸U and ²³²Th. These results are interpreted in terms of natural annealing of damage occurring on a time scale between the ~10 and 10⁵ years of the alpha-decay products. With a simple assumption actual times for the survival of the enhanced leaching in these minerals are ~ 15,000 years.     

Association of subsurface radon changes in Alaska and the northeastern United States with earthquakes

Changes of radon concentration in the ground have been reported to correlate with seismic activity in many places over widely varying distances from the earthquake epicenters, sometimes over 100's and occasionally over 1000's of km depending on the magnitude M of the earthquakes. For proper use of such correlations in forecasting the location and size of impending earthquakes, it would be useful to establish a relation between M and the maximum distance x_M at which radon can be significantly altered by preseismic effects.We have monitored radon in the ground continuously at Blue Mountain Lake, NY starting Dec. 3. 1975 and at three locations in Alaska—Icy Bay, Yakataga, and Sand Point (starting Nov. 12, 1979; March 5, 1980; and June 29, 1980 respectively). Sample correlations from visual examination of the recent radon record and tentative use of a proposed scaling relation show a number of possible earthquake-related signals at these locations. The data are compatible with scaling relations that were derived from two separate models of premonitory elastic strains. In this work x_M = 10^0.48M, where x_M is in units of km and M ≥ 3. Since tilt and strain signals correlate similarly with magnitude and distance, it is likely that most earthquake-related radon signals are mechanically induced.     

Particle track record in Apollo 15 deep core from 54 to 80 cm depths

Particle track measurements have been made in nearly 500 individual grains from 13 levels in the 54–80 cm depth range of the Apollo 15 deep core. They reveal a wide range of track densities at all depths and some systematic variations within layers, indicating that both predepositional mixing and subsequent layering are present and that separate sub-layers exist within larger regions where no sub-layers are visible. Minimum track densities are inferred to be useful measures of maximum residence times for undisturbed layers. Using the observed minimum track densities we conclude that the average deposition rate in this section of soil column was ≥ 0.4 cm/million years.     

Recoiling alpha-emitting nuclei. Mechanisms for uranium-series disequilibrium

High-sensitivity experiments with particles that are strongly enriched in alpha-emitting nuclei show that damaged regions are produced that can be eroded by subsequent exposure to water. Direct ejection of recoil nuclei from solid grains is also observed. These observations appear to supply a basis for understanding disequilibria between ²³⁸U and ²³⁴U in natural samples that have been exposed to water. The two mechanisms observed are expected to act under different natural conditions.     

Surface history of some Apollo 17 lunar soils

Cosmic ray track densities in Apollo 17 soil samples are used to infer surface exposure times of soils from a trench at Van Serg Crater, from on and near a boulder at Camelot Crater, and from the position of the heat flow and neutron flux experiments (the ALSEP site). The topmost 2 cm of soil at Van Serg was exposed for 11 m.y., the top cm at Camelot for 36 m.y. A layering chronology and average deposition rate are proposed for the trench. For all soils the median track densities imply predispositional irradiation in the top 15 cm of the lunar surface for times that were long compared with the actual residence in the stratigraphic positions from which the soils were collected. Van Serg crater is inferred to have been formed approximately 24 m.y. ago.     

Archeoseismic study of damage in Roman and Medieval structures in the center of Cologne, Germany

The causes of damage observed in archeological records or preserved monuments are often difficult to be determined unequivocally, particularly when the possibility of secondary earthquake damage exists. Such secondary damage has been previously proposed for the Roman Praetorium, the governor’s palace in the center of Cologne. Ongoing excavations since 2007 revealed additional damage. The existing ground that has been uncovered and documented extends the affected area to 175?×?180 m. We present a comprehensive virtual model of the excavation area based on 200 3D laserscans together with a systematic analysis of the damage patterns and an improved model of the terrain during Roman/Medieval times including geotechnical parameters of the subsurface. Five locations with different damage patterns, including a Roman sewer, the octagonal central part of the Praetorium, a section with strongly inclined massive walls, a 13 m deep deformed well, a collapsed hypocaust, and damages in the Medieval mikveh are analyzed in detail. We use site-specific synthetic strong ground motion seismograms to test the possibility of earthquake-induced ground failures as a cause for the observed damage. This subsurface model is also used to test the possibility of hydraulically-induced damages by seepage and erosion of fine-grained material from stray sand. Heavy rainstorms can induce a direct stream of surface water through the fine sand layers to the ground water table. Simulated ground motion for assumed worst-case earthquake scenarios do not provoke slope instability at the level necessary to explain the structural damages.     

Investigating hydrological drivers of nitrate export dynamics in two agricultural catchments in Germany using high-frequency data series

In this study near-continuous time series of nitrate, electrical conductivity, and discharge were used to identify the dominating hydrological mechanisms that control nitrate export dynamics in two agricultural catchments. The main goal was to assess relationships between contrasting event based as well as long-term nitrate transport behaviour and catchment hydrology. Data records were obtained from online probes that allow field based high-frequency analyses over long time periods. The catchments of the Ammer River (southwestern Germany) and the Weida River (eastern Germany) are similar with respect to size (~100 km²), morphology, and climate and are dominated by agricultural use. Main differences are the stronger urbanization and the occurrence of karstic rocks in the Ammer catchment. Nitrate concentrations are high in water of both streams and range mostly between 20 and 50 mg l^?1. Nitrate export in the Ammer catchment is dominated by baseflow and a minor second, diluting runoff component generated in urbanized areas. In contrast, nitrate dynamics of the Weida catchment is governed by the interplay of at least three runoff components, while the largest amount of nitrate is mobilized intermittently by a delayed fast component generated in the catchment’s soils during wet conditions. These interpretations, derived with one online probe at the outlet of each catchment, are well in line with the former modeling results. This study shows that high-resolution data obtained by online techniques offers a large potential to improve the conceptualization of dominating flow and transport processes at catchment scales at relatively low costs and effort.     

Heavy-mineral variability in bottom sediments of the lower Chesapeake Bay,Virginia

Heavy minerals in bottom-sediment samples of the lower Chesapeake Bay show distribution patterns and interrelationships that denote characteristic mineral suites associated with defined geographic provinces. The Baymouth province has a garnet—hornblende—pyroxene suite, which is largely attributed to the influx of littoral and shelf sediments; the Eastern Shore province has a similar suite, derived largely from coastal erosion of the Eastern Shore peninsula. The Northern and Combined River provinces have a zircon—tourmaline—staurolite assemblage, which reflects derivation from an Appalachian Piedmont—Atlantic Coastal Plain sourceland. The Western Shore province is associated with a zircon—epidote—staurolite assemblage, apparently derived jointly from tributary influx and coastal erosion of the western shore. Factor analysis identified two major factors that account for 63% of the total variation in the relative amounts of the seven most common heavy minerals. The dominant factor (44%) is based on a zircon—hornblende—staurolite—pyroxene relationship, which indicates that mineral stability, as influenced by sediment maturity, is a major contributing factor. The second factor (19%) based on a tourmaline—epidote—staurolite—garnet relationship indicates that provenance is another major cause of heavy-mineral variability within the lower bay.     

Performance comparison of two biotic indices measuring the ecological status of water bodies in the Southern Baltic and Gulf of Lions

Two biotic indices, ATZI Marine Biotic Index (AMBI) and Benthic Quality Index (BQI) have been recently introduced within the EC Water Framework Directive to assess the quality of marine habitats: both are based on sensitivity/tolerance classification and quantitative information on the composition of soft-bottom macrofauna. Their performance, especially with regard to sampling effort was assessed based on two data sets collected in Southern Baltic and one from the Gulf of Lions Mediterranean. AMBI was not affected by sampling effort but BQI was. Two modifications were proposed for BQI (i.e., BQI) (1) the removal of the scaling term (i.e., BQI(W)), and (2) the replacement of the scaling term by different scaling term (i.e., BQI(ES)). Both modified BQIs were largely independent of sampling effort. Variability was slightly lower for BQI(W) than for BQI(ES). BQI was highly correlated with BQI(W) and with BQI(ES) both in the Southern Baltic and in the Gulf of Lions. However, the proportions of stations, which were not attributed the same ecological quality status (EcoQ) when using BQI and its two modified forms were always high. Differences in ecological classification were mostly due to the scales used to infer EcoQ. Based on this study we recommend to use BQI(ES) in future studies because it apparently constitutes the best compromise in (1) being independent of sampling effort, (2) limiting the variability in computation in relation with sampling effort, (3) being correlated with BQI and corresponding EcoQ.     

The miniaturized Möessbauer spectrometer MIMOS II for the Phobos-Grunt mission

Möessbauer spectroscopy is a powerful tool for the mineralogical analysis of Fe-bearing materials. The miniaturized Möessbauer spectrometer MIMOS II has already been working on the surface of Mars for 6 years as part of the NASA Mars Exploration Rovers mission. The improved version of the instrument is a component of the scientific payload of the Phobos-Grunt mission. The scientific objectives of the instrument are the following: to identify the iron-bearing phases, to determine the quantitative distribution of iron among these phases, and to determine the distribution of iron among its oxidation states.