Experimental abiotic alteration of igneous and manufactured glasses

Pits in ocean basalt glass are often attributed to the activity of microorganisms, however, neither the mechanism of formation of pits in glass nor the involvement of microorganisms have been confirmed by experimentation. Experimental abiotic corrosion of basalt glass with 1% hydrofluoric acid (HF), a proxy for more slowly acting organic acids, produces pits that are similar in size, shape, and distribution to pits found in basalt glass collected from the ocean floor and basalt glass incubated with microorganisms. This pit formation by HF etching was demonstrated by comparing secondary electron images taken before and after the acid treatment. The formation of pits by abiotic corrosion of basalt glass is an alternate hypothesis for the origin of these features, and the interpretation of these features as biomarkers may require a resolution of these alternative hypotheses.     

Seasonally and spatially referenced estimates of recreational shore-angling effort,catch composition,catch rates and total catch in the Goukamma Marine Protected Area,South Africa

A roving creel survey of the recreational shore fishery along the 16.4-km coastline in the Goukamma Marine Protected Area on the south coast of South Africa was conducted from 2009 to 2011. Some 838 patrols were stratified equally among months, areas and years, but intentionally biased towards weekends. Angler densities at Buffalo Bay and Groenvlei were 0.59 and 0.28 anglers km?1, respectively. Weekend densities were double to quadruple weekday densities and fishing during winter was more popular than during summer. Area, habitat and distance to access points explained variation in angler densities. Shannon–Wiener diversity in catches declined from 2.18 in an earlier (1993–2002) survey to 1.79. Although the order of species abundance in the catches remained largely unchanged, blacktail Diplodus capensis dominance increased to 57.3% by number, at the expense of galjoen Dichistius capensis. Habitat explained 27% of the variance in catch composition. The catch per unit effort (CPUE) for the top nine species ranged from 0.19 to 6.35 fish 100-h?1. The CPUE of all species, except spotted grunter Pomadasys commersonnii, declined. Blacktail and galjoen CPUE declined by 17% and 77%, respectively. The total catch estimate was 2 986 fish y?1. Transgressions of size limits were common. The results suggest that the fishery is overexploited and that catch rates are declining.     

Major element chemistry of Galapagos Rift Zone magmas and their phenocrysts

Basalts dredged from the Galapagos Rift Zone between 85°W and 100°W were analyzed by electron microprobe to determine the chemistry of the glass exteriors and included phenocrysts, microphenocrysts and quench minerals. The basalts come from both “normal” mid-ocean ridge segments and from ridge segments that cross the Galapagos Platform. The basalts fall into two chemical and geographical groups. Group A basalts come from outside the central region of the Galapagos Platform (i.e., outside 89–92.5°W) and are chemically similar to basalts from “normal” ocean ridge segments. Group B basalts come from the center of the Galapagos Platform (89–92.5°W) and are enriched in incompatible elements like “plume-influenced” basalts from the Mid-Atlantic Ridge. The spinel, olivine, plagioclase and clinopyroxene phenocrysts in both groups of basalts are low-pressure, equilibrium phases, but the chemical difference among basalts from within each group indicates high-pressure fractional crystallization is also responsible for the chemical evolution of some of these basalts. Presently, no crystallization or partial melting model can relate the chemistry of the two groups of basalts and the compositional influence of a large-ion-lithophile elements and water-rich mantle beneath the Galapagos Platform is a viable alternate hypothesis. The eruption temperature of magmas from the “normal” ridge segments, as determined by olivine-liquid thermometry is 1217±10°C, suggesting steady-state conditions but on the Galapagos Platform the eruption temperatures are lower and more variable than on the “normal” ridge (1186°C±30°C) suggesting a more complex plumbing system and the absence of a steady-state magma chamber beneath the platform.     

Persistent organic pollutants (POPs) in a small, herbivorous, arctic marine zooplankton (Calanus hyperboreus): trends from April to July and the influence of lipids and trophic transfer

Samples of Calanus hyperboreus, a herbivorous copepod, were collected (n = 20) between April and July 1998, and water samples (n = 6) were collected in May 1998, in the Northwater Polynya (NOW) to examine persistent organic pollutants (POPs) in a high Arctic marine zooplankton. Lipid content (dry weight) doubled, water content (r2 = 0.88) and delta15N (r2 = 0.54) significantly decreased, and delta13C significantly increased (r2 = 0.30) in the C. hyperboreus over the collection period allowing an examination of the role of these variables in POP dynamics in this small pelagic zooplankton. The rank and concentrations of POP groups in C. hyperboreus over the entire sampling was sum of PCB (30.1 +/- 4.03 ng/g, dry weight) > sum of HCH (11.8 +/- 3.23) > sum of DDT (4.74 +/- 0.74), sum of CHLOR (4.44 +/- 1.0) > sum of CIBz (2.42 +/- 0.18), although these rankings varied considerably over the summer. The alpha- and gamma-HCH and lower chlorinated PCB congeners were the most common POPs in C. hyperboreus. The relationship between bioconcentration factor (BCF) and octanol-water partition coefficient (Kow) observed for the C. hyperboreus was linear and near 1:1 (slope = 0.72) for POPs with a log Kow between 3 and 6 but curvilinear when hydrophobic POPs (log Kow > 6) were included. Concentrations of sum of HCH. Sum of CHLOR and sum of CIBz increased over the sampling period, but no change in sum of PCB or sum of DDT was observed. After removing the effects of time, the variables lipid content, water content, delta15N and delta13C did not describe POP concentrations in C. hyperboreus. These results suggest that hydrophobic POP (log Kow = 3.86.0) concentrations in zooplankton are likely to reflect water concentrations and that POPs do not biomagnify in C. hyperboreus or likely in other small, herbivorous zooplankton.     

Anisotropy of magnetic susceptibility variations in a single icelandic columnar basalt

Measurements of the anosotropy of magnetic susceptibility in 34 specimens drilled from a single Icelandic columnar basalt segment reveal a preferred, long-axis alignment of magnetic minerals normal to the long axis of the column and well grouped. Maximum elongation of these minerals occurs in regions which crystallized late, as independently indicated by relative samarium concentrations. We propose that the variations in magnetic mineral elongation are controlled by variations in thermal stress in the cooling column, before complete solidification. An upper limit of 75–100 bars is suggested for these stresses.     

Mitigating Risks From Fracking-Related Earthquakes: Assessing State Regulatory Decisions

Public concern about earthquakes linked to wastewater injection from fracking operations is rising. However, few have examined how “induced seismicity” is acted upon by state officials. For some, an incremental response to smaller quakes can be viewed as an acceptable risk policy orientation because of the sizeable economic benefits that accompany drilling activities while others prefer risk mitigation policies (such as the use of “threshold policies”) as a better way to address quake-related problems. To account for state response to induced seismicity impacts, we examine three factors: the emergence of quakes as focusing events, the economic importance of oil and gas to state jobs and revenue, and selected characteristics of earthquakes as a policy issue, i.e., complexity and categorical precedence. Using information drawn from documentary sources, we consider which factors are most helpful in accounting for agency decisions aimed at reducing seismic risks linked to nearby injection wells.     

Harmonization of land-use scenarios for the period 1500�C2100: 600?years of global gridded annual land-use transitions, wood harvest, and resulting secondary lands

In preparation for the fifth Assessment Report (AR5) of the Intergovernmental Panel on Climate Change (IPCC), the international community is developing new advanced Earth System Models (ESMs) to assess the combined effects of human activities (e.g. land use and fossil fuel emissions) on the carbon-climate system. In addition, four Representative Concentration Pathway (RCP) scenarios of the future (2005?C2100) are being provided by four Integrated Assessment Model (IAM) teams to be used as input to the ESMs for future carbon-climate projections (Moss et al. 2010). The diversity of approaches and requirements among IAMs and ESMs for tracking land-use change, along with the dependence of model projections on land-use history, presents a challenge for effectively passing data between these communities and for smoothly transitioning from the historical estimates to future projections. Here, a harmonized set of land-use scenarios are presented that smoothly connects historical reconstructions of land use with future projections, in the format required by ESMs. The land-use harmonization strategy estimates fractional land-use patterns and underlying land-use transitions annually for the time period 1500?C2100 at 0.5°?×?0.5° resolution. Inputs include new gridded historical maps of crop and pasture data from HYDE 3.1 for 1500?C2005, updated estimates of historical national wood harvest and of shifting cultivation, and future information on crop, pasture, and wood harvest from the IAM implementations of the RCPs for the period 2005?C2100. The computational method integrates these multiple data sources, while minimizing differences at the transition between the historical reconstruction ending conditions and IAM initial conditions, and working to preserve the future changes depicted by the IAMs at the grid cell level. This study for the first time harmonizes land-use history data together with future scenario information from multiple IAMs into a single consistent, spatially gridded, set of land-use change scenarios for studies of human impacts on the past, present, and future Earth system.     

AN EMPIRICAL STUDY OF THE ELECTRON TEMPERATURE AND HEAVY ION VELOCITIES IN THE SOUTH POLAR CORONAL HOLE

The solar wind ions flowing outward through the solar corona generally have their ionic fractions freeze-in within 5 solar radii. The altitude where the freeze-in occurs depends on the competition between two time scales: the time over which the wind flows through a density scale height, and the time over which the ions achieve ionization equilibrium. Therefore, electron temperature, electron density, and the velocity of the ions are the three main physical quantities which determine the freeze-in process, and thus the solar wind ionic charge states. These physical quantities are determined by the heating and acceleration of the solar wind, as well as the geometry of the expansion. In this work, we present a parametric study of the electron temperature profile and velocities of the heavy ions in the inner solar corona. We use the ionic charge composition data observed by the SWICS experiment on Ulysses during the south polar pass to derive empirically the electron temperature profile in the south polar coronal hole. We find that the electron temperature profile in the solar inner corona is well constrained by the solar wind charge composition data. The data also indicate that the electron temperature profile must have a maximum within 2 solar radii. We also find that the velocities of heavy ions in their freeze-in regions are small (<100 km s^-1) and different elements must flow at different velocities in the inner corona.     

An experimental investigation of Iceland and Reykjanes Ridge tholeiites: I. Phase relations

Tholeiite basalts from 60° N to 65° N on the Mid-Atlantic Ridge were melted and recrystallized at atmospheric pressure in a CO₂-H₂ gas mixture. Seven basalts are from the Langjokull-Thingvellir volcanic zone and the Reykjanes Peninsula of Iceland and nine are from the Reykjanes Ridge. The crystallization sequence in both Iceland and Reykjanes Ridge basalts with (Total Fe as FeO)/(Total Fe as FeO+ MgO) [F/F + M] less than 0.6 is olivine, plagioclase, clinopyroxene. Chromian spinel crystallizes before plagioclase in one Iceland and one Reykjanes Ridge basalt with F/F+M less than 0.57. Chemical differences of the two groups of basalts (lower SiO₂ and higher alkalis in Iceland basalts) can not simply be a result of low pressure fractional crystallization. Liquidus temperatures of the seven Iceland basalts decreases from 1,230° C to 1,170° C as the F/F+M of the rock increases from 0.52 to 0.70. The liquidus temperatures of the Reykjanes Ridge basalts are about 10° C lower than those of the Iceland basalts for the same F/F+M value. The profile of measured liquidus temperatures from 65° N on Iceland to 60° N on the Reykjanes Ridge has a minimum value at 63.2° N on the Reykjanes Ridge just south of Iceland. Model calculations of the pressure of phenocryst crystallization indicate that olivine and plagioclase in Langjokull basalts could have equilibrated between 2.0 and 6.2 kb (200 to 620 MPa). Phenocryst assemblages in Reykjanes Ridge basalts at 60° N could have crystallized together at greater than 2 kb (200 MPa) and probably less than 8 kb (800 MPa). A minimum in the equilibrium pressure of phenocryst crystallization occurs between 62.9° and 64° N and coincides with the minimum in the experimentally determined liquidus temperatures. The more extensive fractionation at low pressure in this area could be related to the shift of the Mid-Atlantic Ridge axis along the leaky transform fault from the Reykjanes Ridge to the Thingvellir volcanic zone.