Chemical leaching and specific surface area measurements of marine sediments in the evaluation of mercury contamination near cinnabar deposits

This paper investigates mercury contamination in recent marine sediment of the Tyrrhenian continental shelf near the mouths of three rivers draining an area with cinnabar deposits (M. Amiata, Italy). By means of chemical leaching, two fractions of the total mercury were distinguished: a ‘non-leachable’ fraction, consisting of mercury held in relatively stable forms and a ‘leachable’ fraction, composed of forms that are more weakly bound to the sediments. The two Hg fractions are correlated to the organic matter content, the distribution of which is strictly dependent on the sediment surface area.In order to eliminate the effects of grain size variations among the samples, the Hg concentrations were normalized to the unit of surface area (ng/m²). Following this procedure, the ‘non-leachable’ Hg was found to be concentrated mostly in a belt along the coast, while the ‘leachable’ Hg fraction was shown to accumulate largely in the zones with high depositional dynamics near the mouths of the rivers.Hypotheses to account for the discrepancy between the low concentrations of ‘leachable’ Hg in the sediment of the outer continental shelf and the high concentrations in the fauna of the same area, reported in previous papers, are presented.     

A calibration system for superconducting gravimeters

A new method for the calibration of a superconducting gravity meter is described, in which a 273 Kg annular mass is placed around the meter and is moved up and down. The geometry of the apparatus is easy to model and the accuracy in the computation of the gravity variation induced by the mass, 6.7µgal, is limited only by the accuracy in the knowledge of value of the gravitational constant. Measurements done in 91 and 92 for the calibration of the instrument GWR-T015 are described. The calibration factor has been determined with a precision of about 0.3%.     

Rock magnetic evidence of inflation of a flood basalt lava flow

The anisotropy of magnetic susceptibility (AMS) of lava flows is an innovative method which has been proved to be directly related to the shear history of lava. One of the advantages of this method is that it can be used in the absence of other morphological features commonly employed to study the mechanism of emplacement of lava flows. This feature of the AMS method makes it very attractive to gain insight into the mechanism of emplacement of massive, relatively featureless, long lava flows such as those forming flood basalt provinces. In this work, we report the results of the measurement of AMS as a function of vertical position within the Birkett lava flow, one of the Columbia River Basalt Group flows. The observed variation of AMS allows us to identify at least 16 discrete events of lava injection and to estimate the thickness of individual injection events. The AMS-estimated thickness of each injection event (in the range of 0.5-4.0 m) coincides with the range inferred for injected lava pulses in modern Hawaiian lava flows. Thus, the evidence provided by the AMS method supports the notion that at least some flood basalt lava flows were emplaced by the same mechanism as many present-day inflated pahoehoe flows. Regarding the orientation of the principal susceptibilities, in the central part of the flow they define a preferred orientation along an E-W trend, whereas in the outer parts of the flow they have a NNE-SSW trend. This difference in the orientation of the principal susceptibilities is interpreted as the result of a change of flow direction of the lava as emplacement progressed. Electronic supplementary material to this paper can be obtained by using the Springer LINK server located at http://dx.doi.org/10.1007/s00445-002-0203-8.     

A Cambrian mixed carbonate–siliciclastic platform in SW Gondwana: evidence from the Western Sierras Pampeanas (Argentina) and implications for the early Paleozoic paleogeography of the proto-Andean margin

International Journal of Earth Sciences - The Western Sierras Pampeanas (WSP) of Argentina record a protracted geological history from the Mesoproterozoic assembly of the Rodinia supercontinent to...     

Anisotropy of magnetic susceptibility parameters: Guidelines for their rational selection

Twenty-eight parameters used to characterize measurements of the anisotropy of magnetic susceptibility are compared theoretically in this work by introducing the concept of the field of susceptibility tensors, which allows the representation of parameters as families of lines in a plane. It is demonstrated that the foliation and lineation parameters are but a special case of the shape parameters, implying that the resolution of these two rock fabric elements using AMS measurements alone is more an artifact of the numerical range of definition of some parameters than a quantification of two physically independent features. Also, it is shown that parameters presumably of the same type do not necessarily yield equivalent interpretation of results in a qualitative sense, and therefore, caution should be strongly exercised when parameters are to be selected. Paramters quantifying the degree of anisotropy are, in general, equivalent to each other because of the very small departure observed in natural rocks from the isotropic case. However, a final consideration of the possible ability to differentiate rock types and a convenient range of values allowing expression of the degree of anisotropy in a well-defined percentage are pointed out as the main factors to be considered before selecting one parameter within this class.     

Diatom quantification and their distribution with salinity brines in coastal sediments of Terra Nova Bay (Antarctica)

Benthic diatoms represent an important element of global nutritional productivity; to raise attention on their role, which is often neglected due to analytical difficulties, surface (1 cm top layer) coastal sediments from Gerlache inlet to Penguin Bay at Terra Nova Bay were collected and stored at -20 °C. DNA amplification by real-time PCR, based on diatom-specific oligonucleotide primers designed on small-subunit rRNA (SSU rRNA), was performed in addition to diatom conventional cell counting and spectrophotometric determination of photo-pigments. Moreover, cations and anions were determined in sediments with the aim to identify factors involved in the control of diatom abundance. Diatom distribution was found quite heterogeneous displaying significant differences from site to site. The salinity in sediments ranged from 45.1 at Gerlache inlet to 76.2 at Penguin Bay and it was correlated with cell abundance, biodiversity, amount of pigments and amplified DNA. The dominant species, Fragilariopsis curta, was associated to sediment salinity brines.     

Modeling coseismic displacements resulting from SAR interferometry and GPS measurements during the 1997 Umbria-Marche seismic sequence

In this study we analyse coseismic GPS displacements and DInSAR data to constrain a dislocation model for the three largest earthquakes of the 1997 Umbria-Marche seismic sequence. The first two events, which occurred on September 26 at 00:33 GMT (Mw 5.7) and 09:40 GMT (Mw 6.0) respectively, are investigated using both GPS displacements and DInSAR interferograms. We discuss and compare the results of previous studies which separately modeled a smaller subset of geodetic data. We provide a dislocation model for these two earthquakes which fits well both GPS and DInSAR data and agrees with the results of seismological and geological investigations. The first event consists of a unilateral rupture towards the southeast with a uniform dislocation. The strike, rake and dip angles are those resulting from the CMT solution. The second event consists of an unilateral rupture towards the northwest and a variable slip distribution on the fault plane. The strike and the rake are consistent with the CMT solution, but the dip angle has been slightly modified to improve the simultaneous fit of GPS and DInSAR data. While the second rupture (09:40 GMT) arrived very close to the surface, the fit to geodetic data shows that the first rupture (00:33 GMT) is deeper (2 km), despite the more evident surface geological effects. The analysis of new SAR interferograms allows the identification of a 5–6 cm additional displacement caused by the October 3 (Mw 5.2) and 6 (Mw 5.4) seismic events.We use data from a new DInSAR interferogram to model the displacement field of the Sellano earthquake of October 14, 1997. For this event significant GPS measurements were not available. We tested two different fault plane geometries: a blind, planar fault (top depth = 2.4 km), and a curved (listric) fault reaching the surface. The two models provide a generally similar fit to the data, and show that most of the slip was released at depths greater than 2.4 km along a gently dipping (40^°–45^°) fault surface. They also show that a unilateral rupture does not allow fitting the interferometric fringes since there is evident surface deformation to the northwest of the hypocenter. Moreover, we suggest that the concentration of high residuals in the southern part of our uniform slip model may in fact indicate a certain slip variability in this area.We conclude that, despite the moderate magnitudes and the lack of significant surface faulting, the space geodetic data allowed to constrain dislocation models giving new insights in the rupture process of the three largest events of the sequence.     

NGC 6404 and 6583: two neglected intermediate-age open clusters located in the Galactic Centre direction

We report on VI charge-coupled device photometry of two fields centred in the region of the open clusters NGC 6404 and 6583 down to   V = 22.0  . So far these clusters have never been studied, and we provide for the first time estimates of their fundamental parameters, namely, radial extent, age, distance and reddening. We find that the radius of NGC 6404 is 2.0 arcmin, as previously proposed, while the radius of NGC 6583 is 1.0 arcmin, significantly lower than previous estimates. Both clusters turn out to be of intermediate age (0.5–1.0 Gyr old), and located inside the solar ring, at a Galactocentric distance of about 6.5 kpc. These results make these objects very interesting targets for spectroscopic follow-up to measure their metallicity. In fact, they might allow us to enlarge by more than 1 kpc the baseline of the radial abundance gradient in the Galactic disc towards the Galactic Centre direction. This baseline is currently rather narrow especially for clusters of this age.     

Recent crustal deformations and tectonics of the Messina Strait area

Summary. The tectonics of the region at the convergence of the Tyrrhenian and Ionian basins is very complicated. The seismicity is particularly interesting in the area 38°–39° 30'N, 14° 30'–16° 30'E, where both deep events occur with compressive mechanism and crustal events with predominant normal faulting in excess of magnitude 7.0. The tectonic origin of this apparently contradictory behaviour can be traced to a remanent downgoing slab in the southern Tyrrhenian basin which is now inactive but is still undergoing considerable horizontal bending. Sedimentological studies suggest the bending to be accompanied by a marked uplift of Calabira reaching its highest rates in the area of the Strait of Messina. We performed a spirit levelling campaign in the Strait and found that a differential uplift of the inner lands with respect to coastlines took place in the period 1970–82. he question regarding the possibilities of either an absolute uplift of inner lands or a subsidence of coastlines can only be resolved after detailed tidal studies; the available tidal data seem to support the uplift hypothesis but they are substantially incomplete. The apparent pattern of vertical deformations seems to be a marked steady uplift with episodic subsidence periods in connection with large normal faulting earthquakes. Furthermore, our measurements and the results of a recently completed trilateration campaign tend to confirm the hypothesis of the existence of an angular graben in the Strait and a south–north right lateral slip of Sicily with respect to Calabria.