Porewater pressure increases in soil and rock from underground chemical and nuclear explosions

A review and analysis of chemical and nuclear explosive-induced porewater pressure increases and induced rise in groundwater table elevations (groundwater mounding) is presented. Our analysis indicates that residual pore pressure increases and groundwater mounding can be induced by underground chemical and nuclear explosions to scaled distances of 879 m/(kt)^1/3. This relationship is linear over seven orders of magnitude of explosive energy ranging from a 0.01 kg chemical explosion to a 100 kt nuclear explosion and is valid for a wide variety of saturated geological profiles. Underground chemical explosions, and probably underground nuclear explosions have the potential to induce liquefaction of water-saturated soils to scaled distances of about 260 m/(kt)^1/3.     

Analytical model for aquifer response incorporating distributed stream leakage

An analytical model of stream/aquifer interaction is proposed that predicts drawdown in an aquifer with leakage from a finite-width stream induced by pumping from a well. The model is formulated based on the assumptions of stream partial penetration, a semipervious streambed, and distributed recharge across a finite-width stream. Advantages of the analytical solution include its simple structure, consisting of the Theis well function with integral modifications. The solution is derived for the semi-infinite domain between the stream and pumping well, which is of primary interest to hydrogeologists. Previous stream/aquifer analytical models are compared to the analytical solution based on dimensionless drawdown profiles. Drawdown in the aquifer near a wide stream was found to be less than that predicted by a solution that ignored stream width. Deviations between the proposed analytical solutions and previous solutions increase as stream width increases. For a hypothetical stream/aquifer system, the proposed analytical solution was equivalent to prior solutions when the ratio of the distance between the stream and aquifer to the stream width was greater than 25. This analytical solution may provide improved estimates of aquifer and streambed leakage parameters by curve fitting experimental field drawdown data.     

Assessing the South African sardine resource: two stocks rather than one?

Sardine Sardinops sagax distributed off the west and south coasts of South Africa have traditionally been assumed to comprise a single well-mixed stock for assessment and management purposes. New research, however, lends weight to the possibility of two stocks in this region. A precautionary management approach thus needs to consider the impact of management decisions on the hypothesised two individual stocks as well as on the resource as a whole. As a first step in this process, Bayesian assessments of South African sardine are presented, which compare results for the traditional single-stock hypothesis with those that follow from a new two-mixing-stock hypothesis. Recruits from the west stock are assumed to move to and remain part of the south stock in annual pulses of varying size. This movement is estimated to be appreciable, and to take place from a substantially more productive west stock to the south stock. This immigration makes a greater contribution to the south-stock biomass than do years of above-average south-stock recruitment. Importantly, this two-mixing-stock hypothesis is shown to be consistent with the data available. Further alternative sardine stock-structure hypotheses suggested by the most recent data are discussed.     

Classification of marine bioregions on the east coast of South Africa

Marine bioregional planning requires a meaningful classification and spatial delineation of the ocean environment using biological and physical characteristics. The relative inaccessibility of much of the ocean and the paucity of directly measured data spanning entire planning regions mean that surrogate data, such as satellite imagery, are frequently used to develop spatial classifications. However, due to a lack of appropriate biological data, these classifications often rely on abiotic variables, which act as surrogates for biodiversity. The aim of this study was to produce a fine-scale bioregional classification, using multivariate clustering, for the inshore and offshore marine environment off the east coast of South Africa, adjacent to the province of KwaZulu-Natal and out to the boundary of the exclusive economic zone (EEZ), 200 nautical miles offshore. We used remotely sensed data of sea surface temperature, chlorophyll a and turbidity, together with interpolated bathymetry and continental-slope data, as well as additional inshore data on sediments, seabed oxygen and bottom temperature. A multivariate k-means analysis was used to produce a fine-scale marine bioregionalisation, with three bioregions subdivided into 12 biozones. The offshore classification was primarily a pelagic bioregionalisation, whereas the inshore classification (on the continental shelf) was a coupled benthopelagic bioregionalisation, owing to the availability of benthic data for this area. The resulting classification was used as a base layer for a systematic conservation plan developed for the province, and provided the methods for subsequent planning conducted for the entire South African EEZ. Validation of the classification is currently being conducted in marine research programmes that are sampling benthic biota and habitats in a sampling design stratified according to the biozones delineated in this study.     

Stratigraphic and structural evolution of the Blue Nile Basin,Northwestern Ethiopian Plateau

The Blue Nile Basin, situated in the Northwestern Ethiopian Plateau, contains ∼1400 m thick Mesozoic sedimentary section underlain by Neoproterozoic basement rocks and overlain by Early–Late Oligocene and Quaternary volcanic rocks. This study outlines the stratigraphic and structural evolution of the Blue Nile Basin based on field and remote sensing studies along the Gorge of the Nile. The Blue Nile Basin has evolved in three main phases: (1) pre‐sedimentation phase, include pre‐rift peneplanation of the Neoproterozoic basement rocks, possibly during Palaeozoic time; (2) sedimentation phase from Triassic to Early Cretaceous, including: (a) Triassic–Early Jurassic fluvial sedimentation (Lower Sandstone, ∼300 m thick); (b) Early Jurassic marine transgression (glauconitic sandy mudstone, ∼30 m thick); (c) Early–Middle Jurassic deepening of the basin (Lower Limestone, ∼450 m thick); (d) desiccation of the basin and deposition of Early–Middle Jurassic gypsum; (e) Middle–Late Jurassic marine transgression (Upper Limestone, ∼400 m thick); (f) Late Jurassic–Early Cretaceous basin‐uplift and marine regression (alluvial/fluvial Upper Sandstone, ∼280 m thick); (3) the post‐sedimentation phase, including Early–Late Oligocene eruption of 500–2000 m thick Lower volcanic rocks, related to the Afar Mantle Plume and emplacement of ∼300 m thick Quaternary Upper volcanic rocks. The Mesozoic to Cenozoic units were deposited during extension attributed to Triassic–Cretaceous NE–SW‐directed extension related to the Mesozoic rifting of Gondwana. The Blue Nile Basin was formed as a NW‐trending rift, within which much of the Mesozoic clastic and marine sediments were deposited. This was followed by Late Miocene NW–SE‐directed extension related to the Main Ethiopian Rift that formed NE‐trending faults, affecting Lower volcanic rocks and the upper part of the Mesozoic section. The region was subsequently affected by Quaternary E–W and NNE–SSW‐directed extensions related to oblique opening of the Main Ethiopian Rift and development of E‐trending transverse faults, as well as NE–SW‐directed extension in southern Afar (related to northeastward separation of the Arabian Plate from the African Plate) and E–W‐directed extensions in western Afar (related to the stepping of the Red Sea axis into Afar). These Quaternary stress regimes resulted in the development of N‐, ESE‐ and NW‐trending extensional structures within the Blue Nile Basin. Copyright © 2008 John Wiley & Sons, Ltd.     

Selected topics in arctic atmosphere and climate

This paper summarizes the main elements of four IPY projects that examine the Arctic Atmosphere. All four projects focus on present conditions with a view to anticipating possible climate change. All four investigate the Arctic atmosphere, ocean, ice, and land interfacial surfaces. One project uses computer models to simulate the dynamics of the Arctic atmosphere, storms, and their interactions with the ocean and ice interface. Another project uses statistical methods to infer transports of pollutants as simulated in large-scale global atmospheric and oceanic models verifying results with available observations. A third project focuses on measurements of pollutants at the ice-ocean?Catmosphere interface, with reference to model estimates. The fourth project is concerned with multiple, high accuracy measurements at Eureka in the Canadian Archipelago. While these projects are distinctly different, led by different teams and interdisciplinary collaborators, with different technical approaches and methodologies, and differing objectives, they all strive to understand the processes of the Arctic atmosphere and climate, and to lay the basis for projections of future changes. Key findings include: ? Decreased sea ice leads to more intense storms, higher winds, reduced surface albedo, increased surface air temperature, and enhanced vertical mixing in the upper ocean. ? Arctic warming may affect toxic chemicals by remobilizing persistent organic pollutants and augmenting mercury deposition/retention in the environment. ? Changes in sea ice can dramatically change processes in and at the ice surface related to ozone, mercury and bromine oxide and related chemical/physical properties. ? Structure and properties of the Arctic atmospheric??troposphere to stratosphere??and tracking of transport of pollution and smoke plumes from mid-latitudes to the poles.     

LNAPL Distribution in a Cohesionless Soil: A Field Investigation and Cryogenic Sampler

Lighter-than-water Non-Aqueous Phase Liquids (LNAPLs), such as jet fuels or gasolines, are common contaminants of soils and ground water. However, the total volume and distribution of an LNAPL is difficult to accurately determine during a site investigation. LNAPL that is entrapped in the saturated zone due to fluctuating water table conditions is particularly difficult to quantify. Yet, the amount of entrapped product in the saturated zone is theoretically higher, per volume of soil, than the residual product in the unsaturated zone, and small amounts of LNAPL in the saturated zone can contaminate large volumes of ground water.
The only method currently available to quantify the amount of LNAPL is direct soil-core sampling combined with laboratory analysis of the fluid extracted from the soil cores. However, direct sampling of saturated ground water systems with conventional samplers presents a number of problems. In this study, a new sampler was developed that can be used to retrieve undisturbed soil and pore fluid samples from below the water table in cohesionless soils. The sampler uses carbon dioxide to cool the bottom of a saturated soil sample in situ to near freezing. Results of a field study where a prototype sampler was tested demonstrate the usefulness of a cryogenic sampler and show that the amount of LNAPL entrapped below the water table can be a significant part of the total LNAPL in the soil.     

Stream depletion in alluvial valleys using the SDF semianalytical model

A semianalytical method commonly used for quantifying stream depletion caused by ground water pumping was reviewed for applicability in narrow alluvial aquifers. This stream depletion factor (SDF) method is based on the analytic Glover model, but uses a numerical model-derived input parameter, called the SDF, to partly account for mathematically nonideal conditions such as variable transmissivity and nearby aquifer boundaries. Using the SDF can improve and simplify depletion estimates. However, the method's approximations introduce error that increases with proximity to the impermeable aquifer boundary. This article reviews the history of the method and its assumptions. New stream depletion response curves are presented as functions of well position within bounded aquifers. A simple modification to modeled SDF values is proposed that allows the impermeable boundary to be accounted for with image wells, but without overaccounting for boundary effects that are already reflected in modeled SDFs. It is shown that SDFs for locations closer to the river than to the aquifer boundary do not reflect impermeable-boundary effects, and thus need no modification, and boundary effects in the other portion of the aquifer follow a predictable removable pattern. This method is verified by comparing response curves using modified SDFs with response curves from an extensively calibrated numerical model of a managed ground water recharge site. The modification improves SDF-based stream depletion estimates in bounded aquifers while still benefiting from the additional information contained in SDF maps and retaining their value as standardized references for water rights administration.     

应用高分辨率质谱分析苏丹高酸值原油成因

苏丹Muglad和Melut盆地是苏丹乃至整个中、西非剪切带最富含油气的盆地,所发现的原油主要为中质油(重度为20°～34°API),其次为重质油(重度小于20°API),普遍高含沥青质、高含蜡、高酸值、低含硫。为了探讨高酸值原油的成因,选择了苏丹地区18个不同酸值的原油样品,尝试高分辨率质谱分析上述原油有机酸的组成。结果表明,高酸值原油的有机酸主要由环烷酸组成;环烷酸的平均相对分子质量随降解作用程度增加而增大,分子碳原子数分布范围变宽;环烷酸以一环、二环、三环环烷酸为主。生物降解作用是形成高酸值原油的主要原因。