Long term monitoring for oil in the Exxon Valdez spill region

In the aftermath of the 1989 Exxon Valdez oil spill, a Long Term Environmental Monitoring Program (LTEMP) has been regularly sampling mussels (and some sediments) for polycyclic aromatic and saturated hydrocarbons (PAH and SHC) at sites in Port Valdez, Prince William Sound, and the nearby Gulf of Alaska region. After 1999, a decreasing trend appears in total PAH (TPAH) in tissues at all sites with current values below 100 ng/g dry weight (many below 50 ng/g). Currently, most samples reflect a predominantly dissolved-phase signal. This new low in TPAH likely represents ambient background levels. Synchrony in TPAH time-series and similarities in the hydrocarbon signatures portray regional-scale dynamics. The five inner Prince William Sound sites show similar composition and fluctuations that are different from the three Gulf of Alaska sites. The two Port Valdez sites represent a unique third region primarily influenced by the treated ballast water discharge from the Alyeska Marine Terminal. Prince William Sound has reverted to a stable environment of extremely low level contamination in which local perturbations are easily detected.     

西藏丁青弧前蛇绿岩的地球化学特征

丁青蛇绿岩位于班化湖－丁青－怒江蛇绿岩带的东段，其地幔岩出露规模是该带中最大的。本文报道的丁青蛇绿岩主要由地幔橄榄岩、堆晶岩、辉长岩和斜长花岗岩组成。蛇绿岩剖面上覆硅岩中的放射虫化石是早株罗世和晚三叠世诺利克期的，中侏罗统砂岩和砾岩不整合覆盖在蛇绿岩之上，由此确定丁青蛇绿岩是晚三叠－早侏罗世的，在中株罗世之前侵位，丁青蛇绿岩属于玻安岩系，玻安岩的特点是富Si、Mg和大离子亲石元素（LILE），贫高场强元素（Ti、P、Zr、Y、Yb和Nb）。丁青蛇绿岩的堆晶岩、辉长岩和辉绿岩均具“U”型REE分布，暗示丁青玻安岩是由于亏损的地幔源岩和来自消减带的水和流体两组分的混合形成的。丁青玻安岩的地球化学特征类似西太平洋第三纪玻安岩，而明显不同于MORB的地球化学性质， 表明丁青玻安岩应当形成于洋内岛弧的弧前环境，属于弧前蛇绿岩。