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1.
Partitioning of polycyclic aromatic hydrocarbons between water and particles compared to bioaccumulation in mussels: a harbour case 总被引:3,自引:0,他引:3
Hellou J Steller S Leonard J Langille MA Tremblay D 《Marine environmental research》2005,59(2):101-117
Water and particles from three sites located in Halifax Harbour, near and further away from combined municipal sewage effluents (CMSE) were analysed for parental and alkylated polycyclic aromatic hydrocarbons (par and alkPAH). Bioavailability of PAH was compared for inter-tidal mussels collected at the same sites in April and November. The PAH fingerprint determined over 9 sampling times covering a period of 19 months differed more between phases (water and particles) and seasons, than between sites. In the spring, more alkPAH associated with diesel and gasoline were detected in the soluble phase, along with more bioaccumulation of alkPAH in inter-tidal mussels. A broader number of parPAH were detected in mussels collected in the fall. The mean sum of dissolved alkPAH concentrations was higher in water at the site closer to raw CMSE than at the other two sites and particles of that site. However, lowest bioconcentration factors (BCF) were determined in mussels of this more contaminated site. Similar biota-particle accumulation factors (BPAF) were determined for parPAH in mussels from the three sites, all lower than the BCF of alkPAH. The study indicates that sewage treatment plants will reduce the amount of parPAH especially larger than fluoranthene and pyrene from being deposited in the harbour; that alk naphthalenes and fluorenes present in water will continue to be discharged; that the disturbance of sediments can make particle-bound PAH available to mussels. 相似文献
2.
3.
Adsorption of Copper, Nickel, and Cadmium on Goethite in the Presence of Organic Ligands 总被引:2,自引:0,他引:2
Adsorption of copper, cadmium and nickel at low concentrations on goethite was studied in the presence of the simple organic
ligands oxalate, salicylate, and pyromellitate. The experimental metal adsorption behavior was compared to calculations with
a surface complexation model to evaluate the most important interactions. Oxalate mostly decreased Cu and Ni adsorption at
high pH-values by competition between solution and surface complexation but had no effect on Cd adsorption. Cu adsorption
in the presence of oxalate below pH 6 could best be described by defining a ternary complex of type A (surface-metal-ligand).
Salicylate had only minor effects on metal adsorption. The adsorption of Cu in the presence of salicylate above pH 5 could
be explained by a ternary complex of type A. Pyromellitate increased the adsorption of Cu and Cd in the acidic pH-range, likely
by formation of ternary surface complexes of type B (surface-ligand-metal). 相似文献
4.
Sedimentary marine systems are often highly productive and perform important nutrient regeneration functions as they efficiently decompose organic material. In recent years the role of habitat effects and of species composition in ecosystem functioning has become of interest. Estuarine environments are frequently subject to considerable anthropogenic pressures whilst supporting a variety of habitats ranging from well sorted soft muds through biogenically stable sediments to highly mobile coarse sands. There is therefore considerable spatial complexity in habitat type and faunal composition. This study set out to observe the effects of altering the topographical habitat features of an estuarine mudflat on a range of porewater nutrient concentrations (NH4 + , NO3 − , NO2 − , PO4 3− and SiO) collected from four depths (3, 5, 9, and 12 cm) and on faunal composition. Two treatments (Shelled Nets and Net Controls) were used to alter the topography from simple mud to a mussel shell crumble and were compared to un-manipulated Control areas. Sediment granulometry and organic matter content analyses alongside biological traits analysis of the fauna were also conducted.
Differences were observed in porewater nutrient concentrations between the Control and both netted treatments at 5 cm depth only; the species diversity and abundance were also different in the netted treatments compared to the Controls, although no difference between the two manipulated treatments were observed. The changes in faunal composition were attributed solely to the altered topography and the observed nutrient changes were attributed to the faunal alteration rather than the topographical manipulation. 相似文献
Differences were observed in porewater nutrient concentrations between the Control and both netted treatments at 5 cm depth only; the species diversity and abundance were also different in the netted treatments compared to the Controls, although no difference between the two manipulated treatments were observed. The changes in faunal composition were attributed solely to the altered topography and the observed nutrient changes were attributed to the faunal alteration rather than the topographical manipulation. 相似文献
5.
Exhumation in a convergent orogen: the western Tauern window 总被引:1,自引:0,他引:1
6.
Direct observations of aluminosilicate weathering in the hyporheic zone of an Antarctic Dry Valley stream 总被引:1,自引:0,他引:1
Patricia A. Maurice Diane M. McKnightLaura Leff Julia E. FulghumMichael Gooseff 《Geochimica et cosmochimica acta》2002,66(8):1335-1347
This study focused on chemical weathering and bacterial ecology in the hyporheic zone of Green Creek, a McMurdo Dry Valley (Antarctica) stream. An in situ microcosm approach was used to observe dissolution features on the basal-plane surface of muscovite mica. Four mica chips were buried in December 1999 and dug up 39 d later. Atomic force microscopy (AFM) of the basal-plane surfaces revealed small, anhedral ∼10-Å-deep etch pits covering ∼4% of the surfaces, from which an approximate basal-plane dissolution rate of 8.3 × 10−18 mol muscovite cm−2 s−1 was calculated (on the basis of the geometric surface area) for the study period. This is an integrated initial dissolution rate on a fresh surface exposed for a relatively brief period over the austral summer and should not be compared directly to other long-term field rates. The observation of weathering features on mica agrees with previous stream- and watershed-scale studies in the Dry Valleys, which have demonstrated that weathering occurs where liquid water is present, despite the cold temperatures.AFM imaging of mica surfaces revealed biofilms including numerous small (<1 μm long), rounded, oblong bacteria. The AFM observations agreed well with X-ray photoelectron microscopy results showing increased organic C and N. Bacteriologic analysis of the hyporheic zone sediments also revealed <1-μm-long bacteria. α-Proteobacteria were observed, consistent with the oligotrophic conditions of the hyporheic zone. Nitrate-reducing bacteria were found, in agreement with a previous tracer test at Green Creek that suggested nitrate reduction occurs in the hyporheic zone. The results of this study thus provide direct evidence of dynamic geochemical and microbial processes in the hyporheic zone of a Dry Valley stream despite the extreme conditions; such processes were inferred previously from stream-scale hydrogeochemical studies. 相似文献
7.
Matthew J. Genge Luke Alesbrook Natasha V. Almeida Helena C. Bates Phil A. Bland Mark R. Boyd Mark J. Burchell Gareth S. Collins Luke T. Cornwell Luke Daly Hadrien A. R. Devillepoix Matthias van Ginneken Ansgar Greshake Daniel Hallatt Christopher Hamann Lutz Hecht Laura E. Jenkins Diane Johnson Rosie Jones Ashley J. King Haithem Mansour Sarah McMullan Jennifer T. Mitchell Gavyn Rollinson Sara S. Russell Christian Schröder Natasha R. Stephen Martin D. Suttle Jon D. Tandy Patrick Trimby Eleanor K. Sansom Vassilia Spathis Francesca M. Willcocks Penelope J. Wozniakiewicz 《Meteoritics & planetary science》2024,59(5):948-972
Fusion crusts form during the atmospheric entry heating of meteorites and preserve a record of the conditions that occurred during deceleration in the atmosphere. The fusion crust of the Winchcombe meteorite closely resembles that of other stony meteorites, and in particular CM2 chondrites, since it is dominated by olivine phenocrysts set in a glassy mesostasis with magnetite, and is highly vesicular. Dehydration cracks are unusually abundant in Winchcombe. Failure of this weak layer is an additional ablation mechanism to produce large numbers of particles during deceleration, consistent with the observation of pulses of plasma in videos of the Winchcombe fireball. Calving events might provide an observable phenomenon related to meteorites that are particularly susceptible to dehydration. Oscillatory zoning is observed within olivine phenocrysts in the fusion crust, in contrast to other meteorites, perhaps owing to temperature fluctuations resulting from calving events. Magnetite monolayers are found in the crust, and have also not been previously reported, and form discontinuous strata. These features grade into magnetite rims formed on the external surface of the crust and suggest the trapping of surface magnetite by collapse of melt. Magnetite monolayers may be a feature of meteorites that undergo significant degassing. Silicate warts with dendritic textures were observed and are suggested to be droplets ablated from another stone in the shower. They, therefore, represent the first evidence for intershower transfer of ablation materials and are consistent with the other evidence in the Winchcombe meteorite for unusually intense gas loss and ablation, despite its low entry velocity. 相似文献
8.
Comets and the chondritic porous interplanetary dust particles (CP IDPs) that they shed in their comae are reservoirs of primitive solar nebula materials. The high porosity and fragility of cometary grains and CP IDPs, and anomalously high deuterium contents of highly fragile, pyroxene-rich Cluster IDPs imply these aggregate particles contain significant abundances of grains from the interstellar medium (ISM). IR spectra of comets (3–40 μm) reveal the presence of a warm (near-IR) featureless emission modeled by amorphous carbon grains. Broad andnarrow resonances near 10 and 20 microns are modeled by warm chondritic (50% Feand 50% Mg) amorphous silicates and cooler Mg-rich crystalline silicate minerals, respectively. Cometary amorphous silicates resonances are well matched by IRspectra of CP IDPs dominated by GEMS (0.1 μm silicate spherules) that are thought to be the interstellar Fe-bearing amorphous silicates produced in AGB stars. Acid-etched ultramicrotomed CP IDP samples, however, show that both the carbon phase (amorphous and aliphatic) and the Mg-rich amorphous silicate phase in GEMS are not optically absorbing. Rather, it is Fe and FeS nanoparticles embedded in the GEMS that makes the CP IDPs dark. Therefore, CP IDPs suggest significant processing has occurred in the ISM. ISM processing probably includes in He+ ion bombardment in supernovae shocks. Laboratory experiments show He+ ion bombardment amorphizes crystalline silicates, increases porosity, and reduces Fe into nanoparticles. Cometary crystalline silicate resonances are well matched by IR spectra of laboratory submicron Mg-rich olivine crystals and pyroxene crystals. Discovery of a Mg-pure olivine crystal in a Cluster IDP with isotopically anomalous oxygen indicates that a small fraction of crystalline silicates may have survived their journey from AGB stars through the ISM to the early solar nebula. The ISM does not have enough crystalline silicates (<5%), however, to account for the deduced abundance of crystalline silicates in comet dust. An insufficient source of ISMMg-rich crystals leads to the inference that most Mg-rich crystals in comets are primitive grains processed in the early solar nebula prior to their incorporation into comets. Mg-rich crystals may condense in the hot (~1450 K), inner zones of the early solar nebula and then travel large radial distances out to the comet-forming zone. On the other hand, Mg-rich silicate crystals may be ISM amorphous silicates annealed at ~1000 K and radially distributed out to the comet-forming zone or annealed in nebular shocks at ~5-10 AU. Determining the relative abundance of amorphous and crystalline silicatesin comets probes the relative contributions of ISM grains and primitive grains to small, icy bodies in the solar system. The life cycle of dust from its stardust origins through the ISM to its incorporation into comets is discussed. 相似文献
9.
Analysis of Fog Probability from a Combination of Satellite and Ground Observation Data 总被引:1,自引:0,他引:1
The Cloud Type product, developed by the Satellite Application Facility to support to nowcasting and very short-range forecasting
(SAFNWC) of EUMETSAT and based on Météosat-8/SEVIRI, identifies cloud categories, and especially low and very low clouds which
are first estimates of areas where fog is likely to occur. This cloud type is combined with precipitation information from
radar data and with hourly diagnostic analyses of 2-metre relative humidity and 10-metre wind to elaborate an hourly analysis
of fog probability. This analysis provides four levels of fog probability with a 3-kilometre horizontal resolution: No risk,
low-level risk, medium-level risk and high-level risk. An evaluation of such fog probability analyses versus a one-year set
of French hourly SYNOP reports shows encouraging results (potential of detection = 0.73 for low and medium and high-level
risks), even if false alarm ratios remain high. Most of the non-detections occur at twilight and are due to satellite non-detections.
Eventually, we show case studies that clearly illustrate the high potential of the method. 相似文献
10.
The spatial and temporal consistency of seasonal air temperature and precipitation in eight widely used gridded observation-based climate datasets (CANGRD, CRU-TS3.1, CRUTEM4.1, GISTEMP, GPCC, GPCP, HadCRUT3, and UDEL) and eight reanalyses (20CR, CFSR, ERA-40, ERA-Interim, JRA25, MERRA, NARR, and NCEP2) was evaluated over the Canadian Arctic for the 1950–2010 period. The evaluation used the CANGRD dataset, which is based on homogenized temperature and adjusted precipitation from climate stations, as a reference. Dataset agreement and bias were observed to exhibit important spatial, seasonal, and temporal variability over the Canadian Arctic with the largest spread occurring between datasets over mountain and coastal regions and over the Canadian Arctic Archipelago. Reanalysis datasets were typically warmer and wetter than surface observation-based datasets, with CFSR and 20CR exhibiting biases in total annual precipitation on the order of 300?mm. Warm bias in 20CR exceeded 12°C in winter over the western Arctic. Analysis of the temporal consistency of datasets over the 1950–2010 period showed evidence of discontinuities in several datasets as well as a noticeable increase in dataset spread in the period after approximately 2000. Declining station networks, increased automation, and the inclusion of new satellite data streams in reanalyses are potential contributing factors to this phenomenon. Evaluation of trends over the 1950–2010 period showed a relatively consistent picture of warming and increased precipitation over the Canadian Arctic from all datasets, with CANGRD giving moistening trends two times larger than the multi-dataset average related to the adjustment of the station precipitation data. The study results indicate that considerable care is needed when using gridded climate datasets in local or regional scale applications in the Canadian Arctic. 相似文献