Application of environmental groundwater tracers at the Sulphur Bank Mercury Mine, California, USA

Boron, chloride, sulfate, δD, δ¹⁸O, and ³H concentrations in surface water and groundwater samples from the Sulphur Bank Mercury Mine (SBMM), California, USA were used to examine geochemical processes and provide constraints on evaporation and groundwater flow. SBMM is an abandoned sulfur and mercury mine with an underlying hydrothermal system, adjacent to Clear Lake, California. Results for non-³H tracers (i.e., boron, chloride, sulfate, δD, and δ¹⁸O) identify contributions from six water types at SBMM. Processes including evaporation, mixing, hydrothermal water input and possible isotopic exchange with hydrothermal gases are also discerned. Tritium data indicate that hydrothermal waters and other deep groundwaters are likely pre-bomb (before ~1952) in age while most other waters were recharged after ~1990. A boron-based steady-state reservoir model of the Herman Impoundment pit lake indicates that 71–79% of its input is from meteoric water with the remainder from hydrothermal contributions. Results for groundwater samples from six shallow wells over a 6–month period for δD and δ¹⁸O suggests that water from Herman Impoundment is diluted another 3% to more than 40% by infiltrating meteoric water, as it leaves the site. Results for this investigation show that environmental tracers are an effective tool to understand the SBMM hydrogeologic regime.

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Résumé Les concentrations en bore, chlorure, sulfate, δD, δ¹⁸O, et ³H d’échantillons d’eaux de surface et souterraine prélevés dans le banc de soufre de la mine de mercure (SBMM en anglais) en Californie, USA, ont été utilisées pour étudier les processus géochimiques et pour fournir des contraintes à l’évaporation et à l’écoulement des eaux souterraines. La SBMM est une mine de soufre et de mercure abandonnée, adjacente au lac Clear en Californie et sous laquelle se trouve un système hydrothermal.Les résultats des traceurs autres que le tritium (bore, chlorure, sulfate, δD, et δ¹⁸O) ont permis d’identifier des contributions de six types d’eaux à SBMM. Des processus tels que l’évaporation, le mélange, l’entrée d’eau hydrothermale et de possibles échanges isotopiques avec des gaz hydrothermaux ont également été identifiés. Les données de tritium montrent que les eaux hydrothermales et d’autres eaux profondes sont probablement d’age antérieure à la bombe (avant ~1952), alors que la plupart des autres eaux sont issues de la recharge après ~1990. Un modèle de réservoir représentant le lac situé dans la partie Herman Impoundment de l’ancienne mine, en régime permanent et basé sur le bore, montre que 71–79% de l’eau provient des précipitations, le reste provenant de contributions hydrothermales. Les résultats de δD et δ¹⁸O pour des échantillons d’eau souterraine de six puits peu profonds sur une période de 6 mois suggèrent que l’eau de Hermann Impoundment est encore diluée entre 3% jusqu’à plus de 40% lorsqu’elle quitte le site du fait de l’infiltration d’eau météorique. Les résultats de cette étude montrent que les traceurs environnementaux constituent un outil efficace pour comprendre le régime hydrogéologique de la SBMM.

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Resumen Se han utilizado datos de concentraciones de boro, cloruros, sulfatos, δD, δ¹⁸O, y ³H en muestras de aguas superficiales y subterráneas procedentes de la Mina de Mercurio Sulphur Bank (SBMM), California, USA, para estudiar los procesos geoquímicos y caracterizar la evaporación y el flujo del agua subterránea. SBMM es una mina abandonada de azufre y mercurio con un sistema hidrotermal subyacente, cercano al Lago Clear, California.Los resultados de los trazadores que no son ³H (por ejemplo, boro, cloruros, sulfatos δD, y δ¹⁸O) identifican las contribuciones de seis tipos de agua en la SBMM. Se han identificado diversos procesos, como evaporación, mezcla, entrada de agua hidrotermal y la posibilidad de intercambios isotópicos con gases hidrotermales. Los datos de tritio indican que las aguas hidrotermales y otras aguas subterráneas profundas son probablemente pre-bombas (previas a ~1952) en edad mientras que la mayoría de las otras aguas se han recargado después de ~1990. Un modelo estacionario basado en el boro de la fosa del lago Herman Impoundment indica que el 71–79% de su entrada procede de agua meteórica con restos de contribución hidrotermal. Los resultados para las muestras de aguas subterráneas procedentes de seis pozos superficiales en un periodo de 6 meses para δD y δ¹⁸O sugieren que el agua procedente de Herman Impoundment se diluye en otro 3% hasta más del 40% debido a la infiltración de agua meteórica., que sale del sitio. Los resultados de esta investigación muestran que los trazadores ambientales son una herramienta efectiva para entender el régimen hidrogeológico de la SBMM.

     

Hyper Redundancy for Accuracy Enhancement in Automated Close Range Photogrammetry

A generic network design in close range photogrammetry is one where optimal multi-ray intersection geometry is obtained with as few camera stations as practicable. Hyper redundancy is a concept whereby, once the generic network is in place, many additional images are recorded, with the beneficial impact upon object point precision being equivalent to the presence of multiple exposures at each camera position within the generic network. The effective number of images per station within a hyper redundant network might well be in the range of 10 to 20 or more. As is apparent when it is considered that a hyper redundant network may comprise hundreds of images, the concept is only applicable in practice to fully automatic vision metrology systems, where it proves to be a very effective means of enhancing measurement accuracy at the cost of minimal additional work in the image recording phase. This paper briefly reviews the network design and accuracy aspects of hyper redundancy and illustrates the technique by way of the photogrammetric measurement of surface deformation of a radio telescope of 26 m diameter. This project required an object point measurement accuracy of σ  = 0·065 mm, or 1/400 000 of the diameter of the reflector.     

Method of Data Reduction and Uncertainty Estimation for Platinum-Group Element Data Using Inductively Coupled Plasma-Mass Spectrometry

A data reduction method is described for determining platinum-group element (PGE) abundances by inductively coupled plasma-mass spectrometry (ICP-MS) using external calibration or the method of standard addition. Gravimetric measurement of volumes, the analysis of reference materials and the use of procedural blanks were all used to minimise systematic errors. Internal standards were used to correct for instrument drift. A linear least squares regression model was used to calculate concentrations from drift-corrected counts per second (cps). Furthermore, mathematical manipulations also contribute to the uncertainty estimates of a procedure. Typical uncertainty estimate calculations for ICP-MS data manipulations involve: (1) Carrying standard deviations from the raw cps through the data reduction or (2) calculating a standard deviation from multiple final concentration calculations. It is demonstrated that method 2 may underestimate the uncertainty estimate of the calculated data. Methods 1 and 2 do not typically include an uncertainty estimate component from a regression model. As such models contribute to the uncertainty estimates affecting the calculated data, an uncertainty estimate component from the regression must be included in any final error calculations. Confidence intervals are used to account for uncertainty estimates from the regression model. These confidence intervals are simpler to calculate than uncertainty estimates from method 1, for example. The data reduction and uncertainty estimation method described here addresses problems of reporting PGE data from an article in the literature and addresses both precision and accuracy. The method can be applied to any analytical technique where drift corrections or regression models are used.     

Determination of the REE in Geological Reference Materials DTS-1 (Dunite) and PCC-1 (Peridotite) by Ultrasonic and Microconcentric Desolvating Nebulisation ICP-MS

Inductively coupled plasma-mass spectrometry is well suited for the precise, accurate and rapid determination of rare earth elements in most geological samples. However, determination of rare earth elements in certain mantle-derived materials, without applying preconcentration techniques, remains problematical due to low natural concentrations (generally < 1 ng g⁻¹). Consequently, USGS reference materials DTS-1 (a dunite) and PCC-1 (a partially serpentinized harzburgite) have only suggested rather than recommended values for the rare earth elements in reference material compilations. We compared results obtained using two ICP-MS instruments: a U-5000AT ultrasonic nebuliser coupled to a PQ2+ quadrupole ICP-MS and an ELEMENT sector field ICP-MS equipped with a MCN-6000 microconcentric desolvating nebuliser, with the suggested literature values for these two reference materials. Precision and accuracy of analytical methods employed by both instruments were demonstrated by excellent relative standard deviations (< 2%) and inter-laboratory agreement (< 5%) for numerous analyses of BHVO-1 and BIR-1, which are well established with rare earth elements contents at the μg g⁻¹ level. Repeat analyses of DTS-1 and PCC-1 at each laboratory indicate that each method is generally precise to better than 5% at sub-g g⁻¹ levels. Furthermore, values from both instruments generally agree to within 10%. Our DTS-1 and PCC-1 values agree reasonably well with selected data reported in the literature (except for Ce and Sm in DTS-1) but exhibit poorer agreement with reported compilation values. With the demonstrated level of precision and accuracy, we contend that these new values for DTS-1 and PCC-1, generated by two different instruments, are the best estimates of the true whole-rock composition of these samples reported to date.     

Characterisation of Memory Effects and Development of an Effective Wash Protocol for the Measurement of Petrogenetically Critical Trace Elements in Geological Samples by ICP-MS

High sensitivity and low detection limits would seem to make inductively coupled plasma-mass spectrometry (ICP-MS) an ideal analytical tool for determining low (sub-μg g^-1) concentrations of the rare earth elements (REE), Y, Zr, Nb, Hf, Ta, Sn, W, Mo, Th, and U in most mafic materials (e.g. Hall and Plant 1992). However, the generally "sticky" nature exhibited by most of the high field strength elements (HFSEs: Zr, Nb, Hf, Ta, Th and U) as well as Sn, W and Mo can result in spurious results due to memory effects transmitted between unknowns and calibration samples. This, in turn, can seriously compromise the sensitivity, accuracy, and precision of ICP-MS analyses for these elements in geological materials. Data resulting from analyses with poor accuracy and precision can lead to erroneous interpretation and misleading petrogenetic modelling. To resolve this problem, we propose an effective wash protocol for these critical trace elements.     

Structural and stratigraphic problems of the Argylla Formation near Mary Kathleen,Queensland

Rocks formerly mapped as Lower Proterozoic Argylla Formation near Mary Kathleen in northwest Queensland consist of parallel lenses of very deformed schist, quartzite and various types of metaporphyry. Completely intermingled with these are bands of amphibolite and lenses of the adjacent Wonga Granite. Finite ductile strains of 65–80% maximum shortening have been measured; these have produced transposition on both a mesoscopic and macroscopic scale. It is shown that the major stratigraphic boundaries are much shallower than the steeply dipping, constantly oriented unit boundaries. Intrusive relationships and structural criteria indicate that all the lithologies found within the mapped boundaries of the Argylla Formation are chronologically separate. This is confirmed by mapping in the much less deformed area near Winston Churchill Mine to the north. It is concluded that an original sedimentary pile was intruded first by dolerite dyke swarms and then by acid porphyry sills followed by granitic sill‐like instrusions of the Wonga Granite. Subsequent deformation and macroscopic transposition produced the present parallel‐layered structure.

These conclusions differ from currently accepted relationships of the Argylla Formation. Various possibilities are suggested; we favour the view that none of these rock types is equivalent to the defined Argylla Formation, and that the acid porphyries are younger than at Jeast some of the metasediments of the Mary Kathleen Group and may be a precursor of the Wonga Granite intrusion.     

A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).     

The Moon 35 years after Apollo: What's left to learn?

With the cancellation of the Apollo program after Apollo 17 returned from the Moon in 1972, the focus of NASA switched to other areas of the Solar System. Study of the Moon did continue through analysis of the returned samples and remotely sensed data sets (both orbital and surface), as well as through Earth-based telescopic studies. In the 1990s, new orbital data were obtained from several missions (fly-by and orbital), the first being Galileo that allowed the lunar farside to be mapped, followed by global mapping by the Clementine and Lunar Prospector missions.Interest in the Moon started to increase at the beginning of the 21st century as other nations focused their space exploration programs on the Moon. The speech by President Bush in January 2004 put the Moon back into the critical exploration path for NASA, paving the way for humans to return to the lunar surface by 2020. This return will be critical for developing technologies and protocols for the eventual human exploration of other parts of the solar system. At the time of writing (June 2008), the SELENE/Kaguya mission (Japan and Chang’e-1 (China) are orbiting the Moon, with Chandrayaan-1 (India) and Lunar Reconnaissance Orbiter (USA) being scheduled to launch later in 2008.The past (and present) exploration of the Moon begs the question “what's left to be done?” With the renewed focus on the Moon, now that it is on the pathway for the exploration of Mars (and beyond) a similar question has been raised - what should the astronauts do on the Moon? The publication of the New Views of the Moon book [Jolliff et al., 2006. New Views of the Moon, Reviews in Mineralogy, vol. 60. American Mineralogical Society, 721pp] highlighted a number of important scientific questions that remain unanswered as well as posing many more on the basis of the currently available data. These questions resonated in three Lunar Exploration Analysis Group (LEAG) reports pertinent to this discussion, which were also published (on line) during 2006 (http://www.lpi.usra.edu/leag), and in the National Research Council of the National Academies [2007. The Scientific Context for Exploration of the Moon. National Academies Press, Washington, DC, 112pp] report entitled “The Scientific Context for Exploration of the Moon”. This paper synthesizes these recent studies, along with those from the 1980s and 1990s, to emphasize the lunar science questions that remain unanswered. In addition, it summarizes the missions already flown to the Moon along with those that are planned in order to give the reader an idea of exactly what lunar science has been and will be conducted in the hope that it will inspire proposals for missions to address the outstanding science questions.     

The dependence of the climate sensitivity on convective parametrization: statistical evaluation

Two sensitivity experiments, in which CO₂ is instantaneously doubled, have been performed with a general circulation model to determine the influence of the convective parametrization on simulated climate change. We have examined the spatial structure of changes in the annual mean and annual cycle for surface temperature and precipitation for both experiments; similarly we have examined changes in the variance for these two fields. We have also computed a range of test statistics in order to obtain reliable measures of the signal-to-noise ratio in the climate change signal from each experiment. We have computed test statistics for the entire globe and for five different region and we contrast the global response with the response in the Australian region taken as a representative sample.We find that the highest signal-to-noise ratios in the change from 1 * CO₂ to 2 * CO₂ are for the change in surface temperature for both experiments with little difference in the global averages between the experiments. Globally averaged precipitation shows a greater noise level but perhaps the greatest contrast between experiments. There are generally significant increases in the temporal and spatial variability of precipitation in the change from the 1 * CO₂ to 2 * CO₂ and with some differences apparent between the two experiments. The temporal variability of surface temperature does not change significantly in any of the 2 * CO₂ cases, and there is little difference between the experiments. There is a significant decrease in the spatial variability of surface temperature in all 2 * CO₂ experiments in all cases and with significant differences in the seasonal variations between different experiments. The spatial variability of precipitation increases in all 2 * CO₂ cases and also with substantial differences in the seasonal variations between the experiments. There are accompanying significantly different spatial pattern correlations for both surface temperature and precipitation. In general we find that the global changes are fairly robust with the differences associated with convective parametrization schemes being very small. However, at the regional level, there are marked differences between experiments with changes both in the means and in the spatial and temporal variances but often with low levels of significance.