Mineralogical and chemical characterization of historical mortars from military fortifications in Lisbon harbour (Portugal)

Historical mortars from sixteenth to seventeenth century military forts located at the mouth of the Tagus River in Lisbon have been characterized by polarized light microscopy (PLM), thermal analysis (TG/DTA), X-ray diffractometry (XRD) and scanning electron microscopy + energy dispersive spectroscopy (SEM + EDS). The results indicate that the mortars used were all hydraulic lime-based. The presence of well-rounded lime lumps indicates a limited use of water during the lime hydration process. The detection of hydrated calcium chloroaluminate and carboaluminate compounds mostly at binder-aggregate interfaces provides evidence for the onset of pozzolanic reactions during mortar production as further confirmed by the presence of ceramic fragments in the aggregate fractions intentionally added by the fort builders to increase the hydraulic properties of the mortars. The higher mechanical strength and greater resistance to degradation processes imparted by these pozzolanic compounds could explain why, despite the extreme proximity of the investigated sites to the sea, salt weathering processes do not appear to have significantly affected the studied mortars.     

The use of multivariate statistical analysis of geochemical data for assessing the spatial distribution of soil contamination by potentially toxic elements in the Aljustrel mining area (Iberian Pyrite Belt,Portugal)

Aljustrel mine is located in SW Portugal, in the western sector of the Iberian Pyrite Belt. The Aljustrel village was developed around the exploitations of massive polymetallic sulphides that occur in the area (4 orebodies mined, 2 in exploration phase). The pyrite ore was extensively exploited from 1850 to 1993, when production was discontinued. A mining restart occurred in 2008, only during a few months. The objectives of the study were to assess the levels of soil contamination, to determine associations between the different chemical elements and their spatial distribution, as well as to identify possible sources of contamination that can explain the spatial patterns of soil pollution in the area. Principal component analysis combined with spatial interpretation successfully grouped the elements according to their sources and provided evidence about their geogenic or anthropogenic origin. From this study, it is possible to conclude that soils around Algares/Feitais tailing deposits, Estéreis and Águas Claras mine dams and S. João mine show severe contamination. The highest concentrations of As (up to 3,936 mg kg^?1) and certain heavy metals (up to 321.7 mg kg^?1 for Bi, 5,414 mg kg^?1 for Cu, 20,000 mg kg^?1 for Pb, 980.6 mg kg^?1 for Sb, and 22 mg kg^?1 Cd) were obtained near Algares area while the highest concentration of Cd (up to 61.6 mg kg^?1) and Zn (up to 20,000 mg kg^?1) were registered in samples collected in the S. João area. The highest pollution load index (>4.0) was recorded at the Algares area where the metal concentrations exceed typical soil background levels by as much as two orders of magnitude.     

Seismic vulnerability assessment and fragility analysis of pre-code masonry buildings in Portugal

Bulletin of Earthquake Engineering - Despite the fact that in recent years Portugal has not seen the occurrence of high-magnitude earthquakes, it remains threatened by these events due to its...     

Effect of Void Ratio on <Emphasis Type="Italic">K</Emphasis><Subscript>0</Subscript> of a Sand by Means of Triaxial Stress-Path Testing

This paper presents an experimental technique using a computer controlled triaxial test to evaluate K ₀, not requiring the use of any radial measurement transducers. It uses commercial software that applies a ramp of radial stress with back volume measurement and control. The method is applicable only to saturated specimens in drained conditions. The equipment used is briefly described, as well as the testing procedures. Results of laboratory tests on Toyoura sand specimens, with four different initial void ratios, are presented. For the preparation of all specimens tested, a dry funnel deposition method with undercompaction was used. It was concluded that, for the initial void ratios tested and for the stress level induced, stress-strain behavior fell in a narrow range the \(K_{0}^{NC}\) values were slightly higher for looser specimens, although lower than predicted by Jaky’s equation.     

Shaking table testing for masonry infill walls: unreinforced versus reinforced solutions

Several factors influence the behaviour of infilled frames, which have been a subject of research in the past with moderate success. The new generation of European design standards imposes the need to prevent brittle collapse of the infills and makes the structural engineer accountable for this requirement, yet it fails to provide sufficient information for masonry infills design. Therefore, the present work aims at understanding the seismic behaviour of masonry infill walls within reinforced concrete frames, using both unreinforced and reinforced solutions (bed joint reinforcement and reinforced plaster). For this purpose, three reinforced concrete buildings with different infill solutions were constructed at a scale of 1:1.5, all with the same geometry, and were tested on the shaking table of the National Laboratory for Civil Engineering, Portugal. All solutions performed adequately for the design earthquake, with no visible damage. Still, the experimental tests show that the double‐leaf‐unreinforced infill walls underperformed during a large earthquake, collapsing out of plane by rotating as rigid bodies with multiple configurations. Also the reinforced concrete buildings collapsed, because of the adverse interaction with the infill walls. The infill walls with bed joint reinforcement and reinforced plaster did not collapse out of plane, because of their connection to the concrete frame, which is an essential requirement. Copyright © 2016 John Wiley & Sons, Ltd.