A seasonal climate model of the atmospheres of the giant planets at the voyager encounter time: I. Saturn's stratosphere

A radiative seasonal model which incorporates a multilayer radiative transfer treatment at wave-lengths longward of 7 μm is presented and applied to Saturn's stratosphere. Opacities due to H₂-He, CH₄, C₂H₂, and C₂H₆ are included. Season-dependent insolation is shown to produce a strong hemispheric asymmetry decreasing with depth at the Voyager encounter times, and seasonal amplitudes of 30°K at the poles are predicted in the high stratosphere. The ring-modulated dependence of the insolation and the orbital eccentricity are shown to have a significant effect. Calculations agree closely with the Voyager 1 and 2 radio occultation ingress profiles recorded at 76°S and 36.5°S for CH₄/H₂ = 3.5 + 1.4/? 1.0 × 10^?3;the estimated errors include modeling systematic errors and uncertainties in the occultations profiles. The possible role of aerosols in the stratospheric heating is analyzed. The Voyager 2 egress profile recorded at 31°S cannot be reproduced by calculations. Some constraints on the C₂H₂ and C₂H₆ abundances are derived. The upper portion of the occultation profiles (p < 3mbar) can be matched for C₂H₂/H₂ = 1.0 + 1.3/?0.6 × 10^?7, C₂H₆/H₂ = 1.5 + 1.8/?0.9 × 10^?6 at 76°S and C₂H₂/H₂ = 4 + 6/?4 × 10^?8, C₂H₆/H₂ = 6 + 9/?6 × 10^?7 at 36.5°N. At the northern occultation latitude, the discrepancy with the concentrations derived from analysis of IRIS spectra by R. Courtin, D. Gautier, A. Marten, B. Bézard, and R. Hanel (1984, Astrophys. J.287) can be explained by a sharp variation of the mixing ratios of these gases with altitude in the upper stratosphere. Other interpretations are discussed.     

SARG: The High Resolution Spectrograph of TNG

SARG is a cross dispersed echelle spectrograph in operation since late spring 2000 at the Italian Telescopio Nazionale Galileo (TNG) 3.5 m telescope, La Palma. SARG offers both single object and long slit (up to 26 arcsec) observing modes covering a spectral range from λ = 0.37 up to1 μm, with resolution ranging from R = 29,000 up to R = 164,000. Cross dispersion is provided by means of a selection of four grisms; interference filters may be used for the long slit mode (up to 26 arcsec). A dioptric camera images the cross dispersed spectra onto a mosaic of two 2048 × 4096 EEV CCDs (pixel size: 13.5 μm) allowing complete spectral coverage at all resolving power for λ < 0.8 μm. In order to reach a high wavelength calibration precision an iodine-absorbing cell is provided. A Distributed Active Temperature Control System (DATCS) maintains constant the temperature of all spectrograph components at a preset value. Early results show that SARG works according to original specifications in terms of wavelength coverage, efficiency (measured peak efficiency is about 13%),resolution (maximum resolution R = 164,000 using a 0.3 arcsec slit, R ∼144,000 using an image slicer), and stability (preliminary estimates of radial velocity accuracy is ∼3 m/s using the iodine cell and ±150 m/s without the iodine cell). This revised version was published online in July 2006 with corrections to the Cover Date.     

Late Hercynian–Mesozoic thinning in the Alboran domain: metamorphic data from the northern Rif, Morocco

In the Alboran domain, two crustal-thickening late-orogenic extension cycles are superposed. The importance of the late Alpine thinning of the Alpujarride-Sebtide crustal section on top of the Beni Bousera peridotites is discussed here in metamorphic petrological terms. The Alpine metamorphism operated first under a HP–LT gradient, and reached the eclogite facies in the Permian–Triassic phyllites, before retrogression under a high geothermal gradient. A contrasting, higher temperature metamorphism characterizes the pre-Permian section, reaching the HP-granulite facies at the bottom of the crustal section. By reference to the western European setting, the granulites relate to the Hercynian orogeny, as supported by the isotopic ages of the enclosed, armoured monazite crystals. Thus, thinning of an overthickened crust might have occurred there during the late Hercynian extension and Tethyan opening, before being reactivated during the late Oligocene.     

Flare stars and solar bursts: High resolution in time and frequency

Coronal loops on the Sun and nearby stars are investigated using observations at 20 cm wavelength with high resolution in time and frequency. Observations of the dwarf M star AD Leonis with high time resolution using the Arecibo Observatory have resulted in the discovery of a quasi-periodic train of circularly polarized spikes with a mean periodicity of 32 ± 5 ms and a total duration of 150 ms. The individual spikes had rise times of 5 ms, leading to an upper limit to the linear size L 1.5 × 10⁸ cm for the spike emitter. This size is only 0.005 of the estimated radius of AD Leonis. Provided that the emitter is symmetric, it has a brightness temperature of T _B 10¹⁶ K, suggesting a coherent burst mechanism such as an electron-cyclotron maser. Coronal oscillations might modulate the maser output, producing the quasi-periodic spikes. Observations at closely spaced wavelengths, or high frequency resolution, using the Very Large Array have revealed narrow-band structure (v/v 0.01) in solar bursts and in the slowly-varying radiation of the dwarf M star YZ Canis Minoris. The narrow-band emission cannot be explained by continuum emission processes, but it might be attributed to electron-cyclotron maser radiation. Maser action at the second or first harmonic of the gyrofrequency implies magnetic field strengths of 250 and 500 G, respectively. Thus, observations with high resolution in time and frequency suggest coherent processes in the coronae of the Sun and dwarf M stars. The scientific potential of these discoveries may be best fulfilled by the construction of a solar-stellar synthesis radiotelescope.Proceedings of the Workshop on Radio Continua during Solar flares, held at Duino (Trieste), Italy, 27–31 May, 1985.     

Development and morphometry of sinkholes in coastal plains of Apulia, southern Italy. Preliminary sinkhole susceptibility assessment

Evolution of coastlines in karst areas may be strongly controlled by dissolution processes which favour the development of surface and subsurface landforms. The generation of caves in these environments is commonly favoured by the mixing between fresh and brackish waters. The sinkholes resulting from the upward propagation of the caves may interfere with the anthropogenic environment and cause damage to human elements (property and activities). To highlight the often underestimated importance of karst phenomena in coastal areas, we have analyzed a coastal stretch of Apulia, in southern Italy. The study area, covering an extension of about 6 km², is situated in the Ionian coast, and presents several interesting karst landforms that are generally connected to caves. Tens of sinkholes were mapped through field surveys, multi-year aerial-photographs (dating back to the 1940s) and archival research. We have performed a morphometric analysis of the sinkholes. The analysis describes the main parameters of the sinkholes (area, length, width, and depth), and the control exerted by the main discontinuity systems in the area. The detrimental effects derived from interaction between human environment and these karst landforms is also under consideration. A sinkhole susceptibility map, which may provide useful information for planners, developers and the insurance industry has eventually been produced through application of a decision tree model.     

Formation of Zn–Ca phyllomanganate nanoparticles in grass roots

It is now well established that a number of terrestrial and aquatic microorganisms have the capacity to oxidize and precipitate Mn as phyllomanganate. However, this biomineralization has never been shown to occur in plant tissues, nor has the structure of a natural Mn(IV) biooxide been characterized in detail. We show that the graminaceous plant Festuca rubra (red fescue) produces a Zn-rich phyllomanganate with constant Zn:Mn and Ca:Mn atomic ratios (0.46 and 0.38, respectively) when grown on a contaminated sediment. This new phase is so far the Zn-richest manganate known to form in nature (chalcophanite has a Zn:Mn ratio of 0.33) and has no synthetic equivalent. Visual examination of root fragments under a microscope shows black precipitates about ten to several tens of microns in size, and their imaging with backscattered and secondary electrons demonstrates that they are located in the root epidermis. In situ measurements by Mn and Zn K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy and X-ray diffraction (XRD) with a micro-focused beam can be quantitatively described by a single-phase model consisting of Mn(IV) octahedral layers with 22% vacant sites capped with tetrahedral and octahedral Zn in proportions of 3:1. The layer charge deficit is also partly balanced by interlayer Mn and Ca. Diffracting crystallites have a domain radius of 33 Å in the ab plane and contain only 1.2 layers (8.6 Å) on average. Since this biogenic Mn oxide consists mostly of isolated layers, basal 00l reflections are essentially absent despite its lamellar structure. Individual Mn layers are probably held together in the Mn–Zn precipitates by stabilizing organic molecules. Zinc biomineralization by plants likely is a defense mechanism against toxicity induced by excess concentrations of this metal in the rhizosphere.     

Effectiveness of sulfate-reducing passive bioreactors for treating highly contaminated acid mine drainage: I. Effect of hydraulic retention time

Sulfate-reducing passive bioreactors have proved to be an effective technology for the treatment of acid mine drainage (AMD) contaminated waters over relatively short periods of time (1–5 a). However, long-term efficiency can be limited by several factors including problems related to the hydraulic properties of the reactive mixture. In this study, the effect of two hydraulic retention times (HRTs) of 7.3 d and 10 d on the performance of passive bioreactors was evaluated over an 11-month period for the treatment of a highly contaminated AMD. Evolution of the porosity and hydraulic conductivity of the reactive mixture was also evaluated during the 15-month operation of two bioreactors. Results indicated that bioreactors were effective at both HRTs for increasing the pH and alkalinity of contaminated water and for SO₄ and metal removal (60–82% for Fe and up to 99.9% for Cd, Ni and Zn). Although the quality of treated effluent was significantly improved with the 10 d HRT compared to the 7.3 d HRT, results showed that the higher HRT reduced the porosity and the permeability of the reactive mixture which might lead to hydraulic related problems and, eventually, to limited efficiency in long-term operation compared to a shorter HRT. The choice of HRT for a passive bioreactor must therefore consider both the desired quality of treated effluent and the potential for deterioration of hydraulic properties in the reactive mixture.     

Effectiveness of sulfate-reducing passive bioreactors for treating highly contaminated acid mine drainage: II. Metal removal mechanisms and potential mobility

Column bioreactors were used for studying mechanisms of metal removal, assessment of long-term stability of spent reactive mixtures, as well as potential metal mobility after treating highly contaminated acid mine drainage (AMD; pH 2.9–5.7). Several physicochemical, microbiological, and mineralogical analyses were performed on spent reactive mixtures collected from 4 bioreactors, which were tested in duplicate for two hydraulic retention times (7.3d and 10d), with downward flow over an 11-month period. Consistent with the high metal concentrations in the AMD feed, and with low metal concentrations measured in the treated effluent, the physicochemical analyses indicated very high concentrations of metals (Fe, Mn, Cd, Ni, and Zn) in the top and bottom layers of the reactive mixtures from all columns. Moreover, the concentrations of Fe (50.8–57.8 g/kg) and Mn (0.53–0.70 g/kg) were up to twice as high in the bottom layers, whereas the concentrations of Cd (6.77–13.3 g/kg), Ni (1.80–5.19 g/kg) and Zn (2.53–13.2 g/kg) were up to 50-times higher in the top layers. Chemical extractions and elemental analysis gave consistent results, which indicated a low fraction of metals removed as sulfides (up to 15% of total metals recovered in spent reactive mixtures). Moreover, Fe and Mn were found in a more stable chemical form (residual fraction was 42–74% for Mn and 30–77% for Fe) relative to Cd, Ni or Zn, which seemed more weakly bound (oxidisable/reducible fractions) and showed higher potential mobility. Besides identifying (oxy)hydroxide and carbonate minerals, the mineralogical analyses identified metal sulfides containing Fe, Cd, Ni and Zn. Metal removal mechanisms were, therefore, mainly adsorption and other binding mechanisms with organic matter (for Cd, Ni and Zn), and the precipitation as (oxy)hydroxide minerals (for Fe and Mn). After 15 months, however, the column bioreactors did not lose their capacity for removing metals from the AMD. Although the metals were immobile during the bioreactor treatment, their mobility could increase from spent reactive mixtures, if stored inappropriately. Metal recovery by acidic leaching of spent substrates at the end of bioreactor operation could be an alternative.     

Hydrometeorologische Ergebnisse aus Abflußmessungen im Bereich des Hintereisferners (Ötztaler Alpen) in den Jahren 1957 bis 1959

Zusammenfassung Während der Internationalen Geophysikalischen Jahre 1957 bis 1959 wurde an einer Pegelmeßstelle bei 2287 m Höhe der Abfluß vom Hintereis- und Kesselwandferner registriert. Im vorliegenden Arbeitsbericht sollen spezifischen Merkmale des Abflusses aus dem zu 58% vergleitscherten Einzugsgebiet 26,6 km²) im Zusammenhang mit den meteorologischen Beidingungen dargestellt werden.Der Jahresabfluß betrug im Haushaltsjahr 1957/58 1848 mm und im Haushaltsjahr 1958/59 1770 mm; bedingt durch den stark negative massenhaushat der Gletscher was die Gletscherspende mit 24% bzw. 20% des Jahresabflusses außergewöhnlich hoch. Der winterabfluß (Oktober bis März) betrug nur 5% bzw. 10% des Jahresabflusses; die drei Sommermonate Juli bis September Lieferten dagegen 76% bzw. 72%. Der größte Monatsabfluß wurde im August 1958 mit 575 mm, im Juli 1959 mit 559 mm registriert.Die Häufigkeitsverteilung der Tagesabflußmengen für das Jahr 1957/58 ließ eine Andauer des Niedrigwassers mit Tages-Mittelwerten kleiner als 18,8 l/s km² (0,5 m³/s) von 217 Tagen (Oktober bis Mai, 59% des Jahres) erkennen. Größere Tagesabflüsse als 225 l/s km² (6,0 m³/s) kamen nur im Juli und August vor. Als Maximum wurden Abflußwerte bis zu 640 l/s km² Gletscherfläche im Tagesmittel erreicht, entsprechen 55m Abflußhöhe von den Schnee- und Eisflächen. Der exponentielle Abfall der Abflußganglinie vom Herbst zum Minimum im Frühjahr deutet an, daß es sich bei Winterwasser vorwiegend um das verzögerte Abfließen von in den Gletschern zurückgehaltenem Schmelzwasser aus der vorangegangenen Ablationsperiode handelt. Das Ansteigen der Wasserführung nach dem Beiginn der Schneeschmelze im Frühjahr erfolgt wegen des Wiedergefrierens von Schmelzwasser und wegen des Retentionsvermögens der Schneedecke mit einiger Verzörgerung.Die unperiodischen Schwankungen im Abflußgang stehen in engem Zusammenhang mit Wettervorgängen, wobei Schneeniederschlägen die Größte Bedeutung zukommt, weil die hohe Albedo einer Neuschneedecke die Ablation auf den Gletschern tagelang fast völlig unterbrechen kann. Aus zweistündigen Mittelwerten wurde für die Monate Juni bis September der mittlere Tagesgang der Wasserführung ermittelt. Die Ursache für das frühere Eintreten des taglichen Abflußmaximums im Spätsommer durfte verminderte Abflußverzögerung sein. Die Beziehung zwischen den Abflußwerten der Pegel Steg-Hospiz und Vent läßt einen Jahresgang erkennen.

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Summary During the International Geophysical Years 1957–1959 the run-off from Hintereisferner and Kesselwandferner was recorded by a stream gauge installed at an altitude of 2287 m. a. s. 1. The annual run-off in relation to mass budget and precipitation has already been reported in [10, 11]. In the present report characteristic features of run-off from a catchment area (26.6 km²) glaciated to 58 per cent shall be discussed with regard to the meteorological conditions.In the budget years 1957/58 and 1958/59 the yearly run-off was 1848 mm and 1770 mm, respectively. Owing to the strongly negative mass budget of the glaciers the glacier quota of 24 per cent and of 20 per cent, respectively, of the annual run-off was exceptionally high. Winter run-off (October to March) amounting to 5 per cent and to 10 per cent, respectively, of the yearly run-off was only small while July to September supplied 76 per cent and 72 per cent, respectively. The maximum monthly run-off was recorded in August 1958 with 575 mm, and in July 1959 with 559 mm.The frequency distribution of the daily run-off in 1957/58 showed a period of low run-off during 217 days (October to May, 59 per cent of the year) with daily means below 18.8 l/s km² (0.5 m³/s). Daily run-off exceeding 225 l/s km² (6.0 m³/s) occurred only in July and August. Daily means exceeding 338 l/s km² (9.0 m³/s) were recorded only three times in July. The maximum daily means of run-off were up to 640 l/s km² of glacier surface which corresponds to 55 mm of run-off from the snow and ice surfaces. The highest two hourly mean value was 950 l/s km² of the glacier surface. The exponential decrease of the run-off curve from fall to the minimum in spring indicates that winter water consists mainly of the delayed run-off of melt water stored in the glaciers during the preceding ablation period. Owing to the refreezing of the melt water and to the storage capacity of the snow cover run-off is somewhat delayed after the snow melt has set in.The aperiodic variations in the run-off are closely related to weather conditions. Snow falls are of primary importance as the high albedo of a fresh snow cover may interrupt ablation on glaciers almost completely for days. The mean daily variation of run-off was determined from two-hourly mean values for the period June to September. The early occurrence of the daily run-off. The relation between the run-off values recorded at the water gauges Steg-Hospiz and Vent indicates and annual variation.

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Résumé Pendant les Années Géophysiques Internationales de 1957 à 1959 l'écoulement du Hintereisferner et du Kesselwandferner a été enregistré par un limnigraphe installé à une altitude 2287 m. Un rapport a déjà été présenté dans [10, 11] sur l'écoulement annuel en rapport avec le bilan hydrologique du bassin. Dans le présent rapoort il sera traité des caractères spécifiques de l'écoulement d'un bassin dont 58% sont recouverts par le glacier, les quels seront mis en rapport avec les conditions météorologiques.L'écoulement annuel au cours de l'année hydrologique 1957/58 a été de 1848 mm et dans l'année hydrologique 1958/59 de 1770 mm. L'eau libérée par la perte de substance glacière représente 24% pour 1957/58 et 20% pour 1958/59 de l'écoulement annuel. Les pourcentages extrêmement élevés doivent être attribués au bilan fortement négatif des glaciers. L'écoulement d'hiver (Octobre à Mars) représentant 5% pour l'année 1957/58 et 10% pour 1958/59 de l'écoulement annuel a été petit tandis que les trois mois d'été (Juillet–Septembre) fournissaient 76% (1957/58) et 72% (1958/59). L'écoulement mensuel le plus élevé a été enregistré en Aôut 1958 avec 575 mm, et, en Juillet 1959 avec 559 mm.La répartition des fréquences des écoulements journaliers pour l'année 1957/58 indique une période d'étiage de 217 jours (Octobre à Mai, 59% de l'année) avec valeurs journalières en dessous de 18.8 l/s km² (0.5 m³/s). Des écoulements dépassant 225 l/s km² (6.0 m³/s) n'ont été enregistrés qu'en Juillet et Aôut. Les moyennes journalières n'ont dépassé les 338 l/s km² (9.0 m³/s) que trois fois en Juillet. Les valeurs maximums des moyennes journalières d'écoulement se sont élevées à 640 l/s km² de la surface des glaciers, correspondant à 55 mm d'écoulement des surfaces de neige et de glace. La valeur maximum d'une moyenne de deux heures a été de 950 l/s km² de la surface des glaciers. La chute exponentielle de la courbe d'écoulement allant de l'automne au minimum enregistré au printemps indique que dans les cas d'étiage il s'agit de l'écoulement retardé des aux de fonte refenues dans les glaciers pendant la période d'ablation précédente. L'accroissement de l'écoulement après le comencement de la fonte de neige au printemps est retardé dans une certaine mesure par le regel des aux de fonte et la capacité de rétention de la couche de neige. Les variations apériodiques dans l'écoulement sont en relations étroites avec les conditions atmospheriques dont les chutes de neige sont de la plus grade importance car l'albédo élevé d'une couche de neige fraîche interrompt parfois et presque complétement l'ablation sur les glaciers pour des jours entiers.L'amplitude moyenne de la variation journalière de l'écoulement a été, pour les mois de Juin à Septembre, détérminée à la base des valeurs moyennes de deux heures. L'apparition précoce du maximum d'écoulement journalier en fin d'été est probablement due à la diminution du retardement de l'écoulement en cette période. La relation entre le valeurs d'écoulement des limnigraphes de Steg-Hospiz et de Vent met en évidence une variation annuelle.

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Die für diesen Bericht erforderliche weitere Bearbeitung der Abflußdaten und die Fertigstellung des Manuskriptes wurde dem Verfasser im Rahmen seiner Tätigkeit bei der Kommission für Glaziologie an der Bayerischen Akademie der Wissenschaften ermöglicht, wofür an dieser Stelle gedankt sei.     

Reliability-based comparative study for mooring lines design criteria

The characteristic environmental load effect for the design of mooring systems of floating units can be defined by means of three procedures: (a) the one associated to an extreme sea state with a given return period, (b) the worst one from a set of sea states on a contour line associated to a return period or (c) the extreme one based on response statistics for a long-term period. This work presents the result of a reliability-based partial safety factor calibration study for a LRFD mooring line design criteria considering the three approaches mentioned above. The calibration exercise is applied to three FPSOs considering North Sea environmental conditions and different water depths: 200, 800 and 3000 m. The mooring systems investigated take into account mooring lines made up of chains and polyester ropes. It is shown that, among all cases investigated, the design procedure based on the long-term response is the one that presents less scattered reliability indices around the target level.