Trace elements and polycyclic aromatic hydrocarbons (PAHs) concentrations in deep Gulf of Mexico sediments

The concentrations of polycyclic aromatic hydrocarbons (PAHs) and trace elements were determined for surface (top 2 cm) sediment samples collected during the deep Gulf of Mexico benthos (DGoMB) study .These elements and compounds are known to be toxic to organisms at high concentrations and may affect biological communities. There is no indication of major anthropogenic input of the elements Be, Co, Cr, Fe, Si, Tl, V, K, Mg, Ca, Sr and Zn, based on normalization to Al. The concentrations of these metals in the sediment are a function of the relative amounts of trace-metal-rich Mississippi River-derived silicate material and trace-metal-poor plankton-derived carbonate. This is not true for the elements Ba, Ni, Pb, Cd, As, Cu and Mn, whose concentrations show considerable scatter when normalized to Al and a general enrichment. On a normalized basis, Mn is enriched 5–10 fold, Cu and Ni 2–3 fold and Pb 2 fold over Mississippi River-derived material. These enrichments are likely the result of remobilization of metals from depths in the sediment column where reducing conditions exist. The Ba concentrations at selected sites are higher than those of average clay-rich sediments, but are typical of sediments from near oil well platforms in the northern Gulf of Mexico. In the case of Ba, it seems likely that the enrichments, as high as a factor of 10, are due to disposal of oil well drilling mud. The Ba-enriched samples are from the three shallowest water sites in the Mississippi Trough (sites MT1, 2 and 3) and from site C1 and WC5. All are in an area of intense petroleum exploration and development. PAH concentrations are also elevated at MT1, MT3 and C1. The total PAH concentration ranged from not detected (ND) to 1033 ng/g with a mean of 140 ng/g. Even at the sites most enriched in PAHs and trace elements, the concentrations are not at the levels expected to adversely affect the biota. However, these predicted non-effects are based on research using mostly near-shore estuarine species, not on the indigenous species at the sampling sites.     

夏季对马暖流区黑潮水与陆架水的相互作用──兼论对马暖流的起源

根据1994年8月28日至9月7日韩国“Onnuri”号海洋调查船获得的CTD资料及在调查期间投放的11个卫星跟踪漂流浮标资料,分析研究了东海东北部黑潮水的分离及其与陆架水的相互作用,进而探讨了夏季的对马暖流的形成过程。     

Contribution to the origin of the Serguza lead-zinc-pyrite deposit,Northern Iraq

The origin of the Serguza lead-zinc deposit of the Northern Thrust Zone has been suggested to be epigenetic, hydrothermal, structurally controlled by a post Tertiary major fault zone. Reinterpretation of previously obtained data and the evaluation of the present results have provided enough evidence to argue for a different mode of formation. Based upon trace element content of the ore minerals, dating of galena, ore and country rock texture, and the results of the detailed geochemical and geophysical prospecting in the area, it seems that the deposit is strata-bound, stratigraphically controlled within the Triassic dolomites. Its simple mineralogy, chemistry, and other features are comparable with other early Alpine strata-bound leadzinc deposits of the Mediterranean Belt.     

Postbellum race relations in commodity exchange

A structural imperative of capital is to expand commodity exchange. To realize surplus value, capitalists not only have to exploit workers in the production process, but also make workers buy what they produce. This paper examines how this imperative of capital shaped race relations from the end of slavery through the Jim Crow era. The racism that sustained black slavery was highly exclusionary––a fixed racism that undermined this imperative of capital to expand commodity exchange. A more flexible racism would resolve this contradiction. Reconstruction was a move to erase all vestiges of the fixed racism that sustained slavery from relations of commodity exchange. Jim Crow countered with a more flexible racism that maintained the racial status quo but was less of a barrier to blacks participating in commodity exchange in the consumption process.     

New 1982 — 1990 photometry of λ Andromedae and its 11-year cycle

We present photoelectric photometry of λ And never before published, obtained between February 1982 and December 1990 at 29 different observatories. Then we combine it with all other photometry available to us (previously published, contained in the I.A.U. Commission 27 Archives, and obtained with the Vanderbilt 16-inch automatic telescope but not yet published), to yield a 14.8-year data base. Analysis reveals a long-term cycle in mean brightness, with a full range of 0^m.15 and a period of 11.4 ± 0.4 years. Because most of our new photometry was concentrated in the 1983-84 observing season, we analyze that one well-defined light curve with a two-spot model. Spot A keeps a 0^m.04 amplitude throughout four rotation cycles whereas the amplitude of spot B diminishes from 0^m.09 down almost to 0^m.03. The spot rotation periods were 55^d.9 ± 0^d.6 and 520^d.8 ± 1^d.0, respectively.     

Cracking in clays: Solutions to problems in earth structures

Methods are presented for analysing earth structures subjected to tensile stresses that may produce cracking. The linear elastic fracture mechanics approach is emphasized. Methods of solution are proposed for cracking of a clay layer above the water table due to desiccation; cracking of layered earth structures subjected to external loads; cracking of clay caps for landfills due to differential settlement; and radial cracking in pressurized boreholes. Causes and mechanisms of cracking are discussed for each problem and models pertinent to each problem are proposed. Solutions have been developed by synthesizing analytical and numerical methods. Published experimental data have been incorporated in modelling matric suction and cracked beams on elastic foundations. Finite element analyses were employed to obtain solutions for cracking due to differential settlement and radial cracking in boreholes. The solutions presented herein can be used to assess the soundness of existing structures or to assess the risk of cracking for the design of new structures.     

Analysis of resistivity data obtained from cone penetrometer in contaminated soil layers

In horizontally layered soils of different electrical properties, electrical potential distribution becomes complex and the obtained resistivity data may be limited in reflecting the actual soil profile. Thus the objective of this study was to identify the factors that affect resistivity measurement on the cone penetrometer and further investigate the sensitivity of measured resistivity to different types and concentrations of contaminants at the subsurface level. First, a theoretical resistivity equation was derived to provide a means of computing the geometric factor. The effective volume of measurement on the cone penetrometer was investigated and laboratory soil box tests verified the dominance of partially high resistivity regions within the effective volume of measurement over the apparent resistivity. Such effect was found to lead to possible discrepancies between the recorded resistivity data and the actual depth of measurement. Measurements on contaminated soil layers indicated that resistivity cones are efffective in delineating inorganic contaminants in soils of high water contents, and detecting NAPLs floating above the groundwater table provided that soils adjacent to the plume are not dry of water. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Migration for velocity and attenuation perturbations

Migration maps seismic data to reflectors in the Earth. Reflections are not only caused by small‐scale variations of the velocity and density but also of the quality factor that describes attenuation. We investigated scattering due to velocity and attenuation perturbations by computing the resolution function or point‐spread function in a homogeneous background model. The resolution function is the migration image of seismic reflection data generated by a point scatterer. We found that the resolution function mixes velocity and attenuation parameter perturbations to the extent that they cannot be reconstructed independently. This is true for a typical seismic setting with sources and receivers at the surface and a buried scatterer. As a result, it will be impossible to simultaneously invert for velocity and attenuation perturbations in the scattering approach, also known as the Born approximation. We proceeded to investigate other acquisition geometries that may resolve the ambiguity between velocity and attenuation perturbations. With sources and receivers on a circle around the scatterer, in 2D, the ambiguity disappears. It still shows up in a cross‐well setting, although the mixing of velocity and attenuation parameters is less severe than in the surface‐to‐surface case. We also consider illumination of the target by diving waves in a background model that has velocity increasing linearly with depth. The improvement in illumination is, however, still insufficient to remove the ambiguity.     

Analysis of adobe wall composition at the Chaves‐Hummingbird Site,New Mexico,by diffuse reflectance spectrophotometry

This article investigates adobe wall construction materials utilized by prehistoric inhabitants of Chaves‐Hummingbird Pueblo, an ancestral Pueblo village located ˜20 miles west of Albuquerque, New Mexico. The walls were constructed with native clay‐rich soils some time between approximately 1275–1450 A.D. Samples were analyzed with a diffuse reflectance spectrophotometer from the near ultraviolet (NUV) through the visible (VIS) and into the near infrared (NIR) region of the electromagnetic spectrum. Cluster analysis of samples from 275 adobe walls and 36 soil locations surrounding the pueblo room blocks indicates four clusters. Comparison of typical samples from the four clusters indicates that they are very similar and are distinguished by minor variations in the three primary spectrally determined components, Na‐Ca montmorillonite, bentonite, and goethite. In general, clusters correspond with room construction episodes that are discernible through patterns of wall bonding and abutment recorded during the archaeological investigation of the site. This suggests that during different phases of construction the source of the wall adobe changed. Many of the soil samples are included in wall clusters and therefore reveal a potential source of material used for adobe, adjacent soils. However, not all the soil surrounding the pueblo grouped with wall clusters indicating a preference for certain soil types and that some soils were probably unsuitable for making adobe. Therefore, diversity in spectrally identified construction materials provides insights into source locations and possible construction preferences of the site inhabitants. © 2007 Wiley Periodicals, Inc.