Interpretation of LANDSAT MSS imagery of the Nigerian federal capital territory,for soil survey purposes

A soil survey of the Federal Capital Territory was carried out, the results of which, in combination with those of the LRD (1975) and VALETTE (1976), were compared with those produced by the visual interpretation of LandSAT MSS imagery of the same area. The major landtypes were correctly demarcated. The subdivisions of the landtypes, while not being as detailed as that obtained by aerial photo interpretation, correspond to a high degree. It was also found possible to identify geological structures through their landform characteristics. On the basis of the results obtained in this investigation, visual interpretation of LANDSAT MSS imagery for reconnaissance soil survey is strongly recommended, especially in developing countries.     

Greenhouse gases abatement by catalytic dry reforming of methane to syngas over samarium oxide-supported cobalt catalyst

Anthropogenic activities often result in the emissions of methane (CH₄) and carbon dioxide (CO₂) which are the principal components of greenhouse gases. The mitigation of these gases to avert further occurrence of global warming has attracted a lot of research interest. In this study, the potential of greenhouse gases abatement via catalytic CO₂ (dry) reforming of methane to syngas over samarium oxide-supported cobalt (20 wt% Co/80 wt% Sm₂O₃) catalyst was investigated. The 20 wt% Co/80 wt% Sm₂O₃ material was synthesized via wet impregnation method and characterized using different instrument techniques. The methane dry reforming reaction, as well as its kinetics over the catalyst, was studied in a stainless steel fixed-bed continuous flow reactor at feed (CH₄:CO₂) ratios range of 0.1–1.0, temperature range of 923–1023 K and gas hourly space velocity (GHSV) of 30,000 h^?1. The 20 wt% Co/80 wt% Sm₂O₃ catalyst showed promising catalytic activity evident from the highest CH₄ and CO₂ conversion of ~71 and ~74% as well as the highest hydrogen (H₂) and carbon monoxide (CO) yield of ~62 and ~73%, respectively. Moreover, the methane dry reforming over the 20 wt% Co/80 wt% Sm₂O₃ catalyst produces H₂/CO ratio close to unity hence suitable for use as a chemical intermediate for synthesis of oxygenated fuels. The kinetic data obtained from the methane dry reforming were fitted to power law model. Apparent activation energies of 88.62, 80.12, 108.12 and 100.91 kJ mol^?1 were obtained for CH₄, CO₂, H₂ and CO, respectively. The characterization of the spent 20 wt% Co/80 wt% Sm₂O₃ catalyst after 4 h of time-on-stream has confirmed the presence of amorphous carbon which can easily be gasified.     

Field application of a numerical method for the derivation of baseflow recession constant

In an earlier paper (Bako and Hunt, 1988), a method for the derivation of the baseflow recession constant (K) using one-way analysis of variance was presented. This paper presents the results of the field application of this method. The K values obtained by using the numerical equation of Bako and Hunt (1988) were inserted in the exponential recession equation (Barnes, 1939) to generate a series of baseflows. The fit between the model and the historical flows was found to be greater than 99 per cent thus confirming the applicability of the numerical method under field situation. The main advantage of this technique is its amenability for computerized application thus making it relatively faster than any of the existing techniques of fitting the recession equation. For this reason, the subjectivity inherent in most of the existing techniques is eliminated and a measure of procedural consistency can be guaranteed. Consistency is necessary if intercatchment comparison or interpolation of K values is to be meaningful.     

Diamond exploitation in Sierra Leone 1930 to 2010: a resource curse?

This paper uses the resource curse hypothesis to explore diamond exploitation in Sierra Leone during the period 1930–2010. Focusing on national and local level analysis, it examines whether the net impact of diamond exploitation was a ‘resource curse’ or ‘blessing’ during four time periods: colonial and early post-independence era, the APC era, the civil war period, and post-war era. The paper argues that the net impact of diamond exploitation in Sierra Leone has not been constant; rather it has changed between resource blessing and curse over different major periods of Sierra Leone’s history and at local and national scales since inception of diamond exploitation. This paper illustrates that during the period 1968–1992 patrimonial politics undermined official diamond exploitation and significantly contributed to a pendulum shift in the net effects of diamond exploitation from resource blessing to curse. The study shows that the net effect of diamond exploitation was: a resource blessing (especially at the national level) prior to 1968; more of a resource curse during the APC era; a full blown manifestation of the curse during the civil war period; and that governance of the diamond sector has improved sufficiently in post-civil war Sierra Leone to start the gradual transformation of diamonds to resource blessing, at national and local levels.     

The potential for minimizing drawdowns in groundwater wells in tropical aquifers

Aquifer systems in tropical hard rock catchments generally comprise a sequence of three layers — an upper layer of weathered material (regolith), an intermediate zone of semi-weathered material and a basal zone of fresh, but often fractured, rocks. There is evidence that all three are hydraulically connected and for the purpose of this paper the three zones are referred to as ‘regolith-fractures aquifer’ (RFA). Field evidence is presented which shows that the bulk of the drawdown in boreholes in RFA systems is generally incurred during the early period of pumping — usually within 200 minutes of pump start-up. Well losses are an important part of this early drawdown and a judicious management of the pumping scheme during the early period could result in a reduction in the drawdown. One way of managing the pumping scheme is through phased pumping, whereby a desired total discharge (Q) is imposed in incremental steps (Q₁, Q₂, …, Q) during the early period of pumping (generally the first 200 to 300 minutes). This paper presents field data which shows reductions in drawdons arising from phased pumping during the early period.     

A numerical model for simulating Hortonian overland flow on tropical hillslopes with vegetation elements

This paper describes a two‐dimensional hydrodynamic model that characterizes surface runoff process resulting from a varying rainfall intensity event, on an infiltrating soil surface. The soil surface has spatially varied soil physical, hydraulic and microtopographic characteristics. Infiltration process is modelled with the Philip two‐term equation and the time before ponding approximated with the time compression algorithm. Vegetation is modelled as a dynamic component with the modified Gash model. The equation is solved with a modified second order Leapfrog explicit finite difference scheme with centred time and space derivatives. The model was validated with standard analytical solutions. Evaluation with results from field campaigns in the Volta Basin of West Africa during the 2002 rainfall season indicates good agreement, with r² values ranging from 0·89 to 0·96. The developed method will be useful in studying the dynamics of surface runoff generation under complex microtopographic conditions, spatially varying soil hydraulic characteristics and temporally dynamic rainfall intensity, as found in many tropical catchments. Copyright © 2007 John Wiley & Sons, Ltd.