Revised age of proximal deposits in the Zagros foreland basin and implications for Cenozoic evolution of the High Zagros

The regionally extensive, coarse-grained Bakhtiyari Formation represents the youngest synorogenic fill in the Zagros foreland basin of Iran. The Bakhtiyari is present throughout the Zagros fold-thrust belt and consists of conglomerate with subordinate sandstone and marl. The formation is up to 3000 m thick and was deposited in foredeep and wedge-top depocenters flanked by fold-thrust structures. Although the Bakhtiyari concordantly overlies Miocene deposits in foreland regions, an angular unconformity above tilted Paleozoic to Miocene rocks is expressed in the hinterland (High Zagros).

The Bakhtiyari Formation has been widely considered to be a regional sheet of Pliocene–Pleistocene conglomerate deposited during and after major late Miocene–Pliocene shortening. It is further believed that rapid fold growth and Bakhtiyari deposition commenced simultaneously across the fold-thrust belt, with limited migration from hinterland (NE) to foreland (SW). Thus, the Bakhtiyari is generally interpreted as an unmistakable time indicator for shortening and surface uplift across the Zagros. However, new structural and stratigraphic data show that the most-proximal Bakhtiyari exposures, in the High Zagros south of Shahr-kord, were deposited during the early Miocene and probably Oligocene. In this locality, a coarse-grained Bakhtiyari succession several hundred meters thick contains gray marl, limestone, and sandstone with diagnostic marine pelecypod, gastropod, coral, and coralline algae fossils. Foraminiferal and palynological species indicate deposition during early Miocene time. However, the lower Miocene marine interval lies in angular unconformity above ~ 150 m of Bakhtiyari conglomerate that, in turn, unconformably caps an Oligocene marine sequence. These relationships attest to syndepositional deformation and suggest that the oldest Bakhtiyari conglomerate could be Oligocene in age.

The new age information constrains the timing of initial foreland-basin development and proximal Bakhtiyari deposition in the Zagros hinterland. These findings reveal that structural evolution of the High Zagros was underway by early Miocene and probably Oligocene time, earlier than commonly envisioned. The age of the Bakhtiyari Formation in the High Zagros contrasts significantly with the Pliocene–Quaternary Bakhtiyari deposits near the modern deformation front, suggesting a long-term (> 20 Myr) advance of deformation toward the foreland.     

Detrital zircon provenance of Neoproterozoic to Cenozoic deposits in Iran: Implications for chronostratigraphy and collisional tectonics

Ion-microprobe U–Pb analyses of 589 detrital zircon grains from 14 sandstones of the Alborz mountains, Zagros mountains, and central Iranian plateau provide an initial framework for understanding the Neoproterozoic to Cenozoic provenance history of Iran. The results place improved chronological constraints on the age of earliest sediment accumulation during Neoproterozoic–Cambrian time, the timing of the Mesozoic Iran–Eurasia collision and Cenozoic Arabia–Eurasia collision, and the contribution of various sediment sources of Gondwanan and Eurasian affinity during opening and closure of the Paleotethys and Neotethys oceans. The zircon age populations suggest that deposition of the extensive ~ 1 km-thick clastic sequence at the base of the cover succession commenced in latest Neoproterozoic and terminated by Middle Cambrian time. Comparison of the geochronological data with detrital zircon ages for northern Gondwana reveals that sediment principally derived from the East African orogen covered a vast region encompassing northern Africa and the Middle East. Although most previous studies propose a simple passive-margin setting for Paleozoic Iran, detrital zircon age spectra indicate Late Devonian–Early Permian and Cambrian–Ordovician magmatism. These data suggest that Iran was affiliated with Eurasian magmatic arcs or that rift-related magmatic activity during opening of Paleotethys and Neotethys was more pronounced than thought along the northern Gondwanan passive-margin. For a Triassic–Jurassic clastic overlap assemblage (Shemshak Formation) in the Alborz mountains, U–Pb zircon ages provide chronostratigraphic age control requiring collision of Iran with Eurasia by late Carnian–early Norian time (220–210 Ma). Finally, Cenozoic strata yield abundant zircons of Eocene age, consistent with derivation from arc magmatic rocks related to late-stage subduction and/or breakoff of the Neotethys slab. Together with the timing of foreland basin sedimentation in the Zagros, these detrital zircon ages help bracket the onset of the Arabia–Eurasia collision in Iran between middle Eocene and late Oligocene time.     

Late Tertiary tectonic evolution of northern Iran: A case for simple crustal folding

Here we present a crustal folding or buckling mechanism to explain the rootless 3–5 km high Alborz Mountains in northern Iran as well as  10 km of Late Miocene to recent subsidence in the south Caspian basin and  3–6 km of subsidence in the central Iranian basin in the context of the middle Miocene to recent Arabia–Eurasia collision. A key element of the mechanism is the presence of lateral and vertical lithospheric strength contrasts between the north Iranian continental and south Caspian oceanic crusts: when compression from the collision is applied across the region, the strong south Caspian oceanic crust, buried under > 10 km of premiddle Miocene sediment, interacts with the bottom of the mechanically strong continental upper crust of northern Iran, resulting in upward buckling of the continental crust and downward buckling of the oceanic crust. We test this mechanism using a finite-element numerical model with a Maxwell rheology and obtain results that are consistent with the geological and geophysical observations. The observations compiled here and the model results demonstrate the potential for using this region as a natural laboratory for studying the early stages of continent–oceanic collision, including processes like basin inversion, fault localization and, potentially, subduction initiation.     

Hydrogeology of northern Sierra de Chiapas,Mexico: a conceptual model based on a geochemical characterization of sulfide-rich karst brackish springs

Conspicuous sulfide-rich karst springs flow from Cretaceous carbonates in northern Sierra de Chiapas, Mexico. This is a geologically complex, tropical karst area. The physical, geologic, hydrologic and chemical attributes of these springs were determined and integrated into a conceptual hydrogeologic model. A meteoric source and a recharge elevation below 1,500 m are estimated from the spring-water isotopic signature regardless of their chemical composition. Brackish spring water flows at a maximum depth of 2,000 m, as inferred from similar chemical attributes to the produced water from a nearby oil well. Oil reservoirs may be found at depths below 2,000 m. Three subsurface environments or aquifers are identified based on the B, Li⁺, K⁺ and SiO₂ concentrations, spring water temperatures, and CO₂ pressures. There is mixing between these aquifers. The aquifer designated Local is shallow and contains potable water vulnerable to pollution. The aquifer named Northern receives some brackish produced water. The composition of the Southern aquifer is influenced by halite dissolution enhanced at fault detachment surfaces. Epigenic speleogenesis is associated with the Local springs. In contrast, hypogenic speleogenesis is associated with the brackish sulfidic springs from the Northern and the Southern environments.     

U-Pb zircon geochronology of late Neoproterozoic–Early Cambrian granitoids in Iran: Implications for paleogeography, magmatism, and exhumation history of Iranian basement

Eurasia has largely grown to its present enormous size through episodic addition of crustal blocks by recurring birth and demise of oceans such as Paleotethys and Neotethys. Excluding the Kopet Dagh Mountains in the northeast, crystalline basement rocks of various dimensions are exposed in all continental tectonic zones of Iran. These rocks have traditionally been viewed as continental fragments with Gondwanan affinity and summarily been assigned Precambrian or younger ages, despite the fact that evidence from isotopic dating has largely been lacking. This study presents new ion microprobe and thermal-ionization zircon U-Pb geochronological data from granitoids and orthogneisses from several locations in central Iran and the Sanandaj–Sirjan structural zones to determine crystallization ages and investigate the origin and continental affinity of these various crustal fragments. The resulting U-Pb crystallization ages for the granites and orthogneisses range from late Neoproterozoic to Early Cambrian, matching the mostly juvenile Arabian–Nubian shield and Peri-Gondwanan terranes constructed after the main phase of Pan-African orogenesis. TIMS analyses of zircons with inherited cores from western Iran suggest that the Neoproterozoic crust of Iran might not be entirely juvenile, pointing to the potential presence of inherited older Proterozoic components as is common in the eastern Arabian shield. More importantly, the new zircon U-Pb crystallization ages unequivocally demonstrate that crystalline basement underlying the Sanandaj–Sirjan zone, central Iran, and the Alborz Mountains is composed of continental fragments with Gondwanan affiliation, characterized by wide spread late Neoproterozoic subduction-related magmatism. The exposure of these late Neoproterozoic–Early Cambrian basement rocks in the Iranian regions north of the Zagros is structurally controlled and linked to both large-scale crustal extension and exhumation during Mesozoic and Tertiary time as well as Tertiary collisional tectonics associated with the closure of Neotethys.