Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.     

The origin of the Pedra Furada sandstone tubular structures (South of Lisbon, Portugal)

The Pedra Furada is a 12 m wide, 18 m high outcrop feature showing hundreds of ferruginised sandy tubes and looking in part like a giant organ. In this paper the origin of the tubes is explained on the basis of geochemical, petrographic and microscopic (optical and electronic) analytical data. The tubes are considered to represent vertical escape channels for overpressured water, exhibiting inward decreasing grain size due to water velocity gradients inside the escape channels. The ferruginisation is due to iron oxides associated with colloidal/clayey fine sediments and to goethite formed from solution. The overpressure of water may be due to seismically fluidised beds below the Pedra Furada outcrop or to artesian water ascent. In both cases, fault rupturing may have played a major role in the focussing of the ascending flow.     

Geochronological constraints on the evolution of the Embu Complex, São Paulo, Brazil

Petrologic and geochronological work was carried out on a roadside outcrop of amphibolite facies orthogneisses near São Lourenço da Serra, about 50 km southwest of São Paulo City. These orthogneisses belong to the Embu Complex, within the Neoproterozoic Brasiliano Orogenic Cycle mobile belts of SE Brazil. The outcrop consists of predominantly foliated biotite tonalites and granodiorites, which were cut by granitic veins and pegmatites prior to final deformation. SHRIMP U/Pb measurements on zircons from one granodioritic–tonalitic gneiss indicate magmatic crystallization of the protolith at 811±13 Ma (MSWD=1.0). Zircons with dates of ca. 2000 and ca. 1000 Ma in this rock are interpreted as inherited from older crust. One zircon analyzed from the gneiss and three zircons from a discordant pegmatitic vein indicate an event at 650–700 Ma, perhaps related to the intrusion of the pegmatites. A regression of Rb–Sr whole rock data for four biotite gneisses yielded an imperfect isochron, giving an apparent age of 821±68 Ma and an elevated initial ⁸⁷Sr/⁸⁶Sr ratio of 0.719±0.005. The elevated initial ⁸⁷Sr/⁸⁶Sr ratio and the inherited zircons indicate involvement of older crust in the genesis of the gneisses. Rb–Sr feldspar and whole rock pairs yield ca. 560 Ma tielines, giving the time of final cooling below 300–350 °C, and the cessation of medium-grade metamorphism and ductile deformation. These results document a series of tectono-thermal events spanning 250 million years during the Brasiliano Orogenic Cycle. They relate to ca. 800 Ma magmatic arc activity and later allochthonous terrane assembly during closure of the Adamastor Ocean, resulting in the accretion of Western Gondwana.     

Mechanisms of physico-chemical interaction of mercury with river sediments from a gold mining region in Brazil: Relative mobility of mercury species

Mercury accumulation in the food chain, as a consequence of gold recovery in Brazil, has been an issue of concern. Reactions of Hg in the environment are quite complex, and can involve various Hg chemical species. Laboratory experiments were carried out on Hg⁰ solubility, Hg complexation and sorption on river sediments from a gold mining region in Brazil. The reactivity and the mobility of Hg species were considered. Results indicate that methyl mercury is more mobile than ionic mercury, and that the presence of humic acid enhances drastically the solubility of Hg⁰. The soluble complex formed has a relatively lower interaction at the sediment/water interface and is more prone to spread through the aquatic environment.     

Taxonomic analysis of the Quaternary archaeofauna found at The Lapa do Santo site,Lagoa Santa region,Brazil

The Lapa do Santo archaeological site, located in the Lagoa Santa region, Brazil, represents an important hunter-gatherer occupation dated from the Early and Middle Holocene. Prior studies of archaeofauna dating to this period are few and most of them only provide basic faunal identification with limited information on taphonomic processes. The main goal of this study is to identify the archaeofauna, record the taphonomic processes, and make inferences about its natural (interpreted as the death of the animal in the rockshelter area due to natural causes or due to predation) or anthropic origins. No extinct species (including megamastofauna) were identified. Taxonomic analysis indicated that most faunal remains consist of taxa that may be of mixed origin (natural or anthropic), such as microvertebrates and carnivorous mammals. The Cervidae are the main vertebrate family found in the studied material and these are likely the result of hunting. The Cervidae Ozotoceros support the presence of a fauna that is typical of savannah environments, although the assemblage contains mostly generalist fauna that can thrive in a variety of environments. Very few remains showed clear evidence for taphonomic processes related to human interaction, such as burnt bones.     

The accuracy of standard enthalpies and entropies for phases of petrological interest derived from density-functional calculations

The internal energies and entropies of 21 well-known minerals were calculated using the density functional theory (DFT), viz. kyanite, sillimanite, andalusite, albite, microcline, forsterite, fayalite, diopside, jadeite, hedenbergite, pyrope, grossular, talc, pyrophyllite, phlogopite, annite, muscovite, brucite, portlandite, tremolite, and CaTiO₃–perovskite. These thermodynamic quantities were then transformed into standard enthalpies of formation from the elements and standard entropies enabling a direct comparison with tabulated values. The deviations from reference enthalpy and entropy values are in the order of several kJ/mol and several J/mol/K, respectively, from which the former is more relevant. In the case of phase transitions, the DFT-computed thermodynamic data of involved phases turned out to be accurate and using them in phase diagram calculations yields reasonable results. This is shown for the Al₂SiO₅ polymorphs. The DFT-based phase boundaries are comparable to those derived from internally consistent thermodynamic data sets. They even suggest an improvement, because they agree with petrological observations concerning the coexistence of kyanite?+?quartz?+?corundum in high-grade metamorphic rocks, which are not reproduced correctly using internally consistent data sets. The DFT-derived thermodynamic data are also accurate enough for computing the P–T positions of reactions that are characterized by relatively large reaction enthalpies (>?100 kJ/mol), i.e., dehydration reactions. For reactions with small reaction enthalpies (a few kJ/mol), the DFT errors are too large. They, however, are still far better than enthalpy and entropy values obtained from estimation methods.     

Stochastic response of rigid foundations

While the study of kinematic interaction (i.e. the dynamic response of massless foundations to seismic loads) calls, in general, for advanced analytical and numerical techniques, an excellent approximation was proposed recently by Iguchi.^1,2 This approximation was used by the authors to analyse embedded foundations subjected to spatially random SH-wave fields, i.e. motions that exhibit some degree of incoherence. The wave fields considered ranged from perfectly coherent motions (resulting from seismic waves arriving from a single direction) to chaotic motions, resulting from waves arriving simultaneously from all directions. Additional parameters considered were the shape of the foundation (cylindrical or rectangular) and the degree of embedment. It was found that kinematic interaction usually reduces the severity of the motions transmitted to the structure, and that incoherent motions do not exhibit the frequency selectivity (i.e. narrow valleys in the foundation response spectra) that coherent motions do.     

Icequakes and glacier motion: The hans glacier,spitsbergen

The recording of glacier icequakes has been carried out on the Hans glacier, Spitsbergen. The icequakes have been connected with the formation of open cracks. The energy of the main group of icequakes has ranged from 0.01 J to 6 J, their seismic moment being from 0.5 · 10¹⁴ dyne · cm to 26 · 10¹⁴ dyne · cm. The nonelastic volume increase corresponding to each crack has ranged from 0.2 · 10⁻² m³ to 8.8 · 10⁻² m³. The stresses released due to extensional faulting ranged from 25N/m² to 500 N/m²; these values are so small that they suggest an incomplete release of the medium. The contribution into the glacier flow rate of the deformation in the surface glacier layer due to extensional faulting is lower by 2 to 3 orders of magnitude than the total plastic deformation associated with the ice creeping.     

Geology, coal quality, and resources of the Antaramut–Kurtan–Dzoragukh coal field, north-central Armenia

The Antaramut–Kurtan–Dzoragukh (AKD) coal deposit is a previously unrecognized coal field in north-central Armenia. Coal has been known to exist in the general vicinity since the turn of the century, but coal was thought to be restricted to a small (1 km²) area only near the village of Antaramut. However, through detailed field work and exploratory drilling, this coal deposit has been expanded to at least 20 km², and thus renamed the Antaramut–Kurtan–Dzoragukh coal field, for the three villages that the coal field encompasses. The entire coal-bearing horizon, a series of tuffaceous sandstones, siltstones, and claystones, is approximately 50 m thick. The AKD coal field contains two coal beds, each greater than 1 m thick, and numerous small rider beds, with a total resource of approximately 31,000,000 metric tonnes. The coals are late Eocene in age, high volatile bituminous in rank, relatively high in ash yield (approximately 40%, as-determined basis) and moderate in sulfur content (approximately 3%, as-determined basis). The two coal beds (No. 1 and No. 2), on a moist, mineral-matter-free basis, have high calorific values of 32.6 MJ/kg (7796 cal/g) and 36.0 MJ/kg (8599 cal/g), respectively. Coal is one of the few indigenous fossil fuel resources occurring in Armenia and thus, the AKD coal field could potentially provide fuel for heating and possibly energy generation in the Armenian energy budget.