Reversibility of radiocaesium sorption on illite

Adsorption of trace amounts of radiocaesium on NH₄-, K-, and Na-saturated Fithian illite and subsequent desorption by 1 M NH₄ showed that a substantial amount of radiocaesium (44%, 46%, and 91% for NH₄-, K-, and Na-illite, respectively) cannot be desorbed after only 5 min of adsorption. Our results suggest that this instantaneous fixation is caused by the collapse of the frayed edges of the clay mineral and the relatively high concentration of radiocaesium building up in solution in the batch desorption experiments. Consequently, commonly applied high-NH₄ extractions underestimate truly exchangeable amounts of radiocaesium in soils and sediments containing illitic clay minerals. The rate of desorption of trace amounts of radiocaesium from the solids using high NH₄ or Cs concentrations has a half-life of about 2 yr, reflecting radiocaesium desorption from (partially) collapsed interlayers. Extraction of radiocaesium from illite after 5 min of contact time with a Cs-selective adsorbent or a 1 × 10^-6 M CsCl solution shows that 100% of the bound radiocaesium is readily available. The desorption rate in the presence of a Cs-selective adsorbent has a half-life of about 0.2 yr. Desorption of radiocaesium from illite using different ammonium concentrations shows that radiocaesium partitioning follows reversible ion-exchange theory if the NH₄ concentration is below 1 × 10^-4 M, and sufficient time (weeks) is allowed for the reaction to proceed. Thus, radiocaesium sorption reversibility in the natural environment is much higher than generally assumed, and equilibrium solid/liquid partitioning may be assumed for the long-term modelling of radiocaesium mobility in the natural environment. In the particular case of anoxic freshwater sediments with very high NH₄ concentrations in the pore waters (up to several mmol.L^-1), collapse of the frayed edges of illite may occur, influencing radiocaesium partitioning. If collapse occurs before radiocaesium adsorbs to illite, high caesium sorption reversibility as measured by high-NH₄ extraction can be expected because further collapse of the frayed edges during the extraction procedure will be limited. This effect has indeed been observed earlier in the extraction of radiocaesium from anoxic freshwater sediments with high-NH₄ solutions and was as yet unexplained.     

Understanding and managing the morphology of branches incising into sand-clay deposits in the Dutch Rhine Delta

In the Rhine-Meuse delta in the south-western part of the Netherlands,the morphology of the river branches is highly dependent on the erodibility of the subsoil.Erosion processes that were initiated after closure of the Haringvliet estuary branch by a dam(in 1970),caused a strong incision of several connecting branches.Due to the geological evolution of this area the lithology of the subsoil shows large variations in highly erodible sand and poorly erodible peat and clay layers.This study shows how the geological information can be used to create 3D maps of the erodibility of the sub-soil, and how this information can be used to schematize the sub-soil in computational models for morphological simulations.Local incisement of sand patches between areas with poorly erodible bed causes deep scour holes,hence increasing the risk on river-bank instability(flow slides) and damage to constructions such as groynes,quays,tunnels, and pipelines.Various types of mathematical models,ranging from 1D(SOBEK) to quasi-3D(Delft3D) have been applied to study the future development of the river bed and possible management options.The results of these approaches demonstrate that models require inclusion of a layer-bookkeeping approach for sub-soil schematization, non-uniform sediment fractions(sand-mud),tidal and river-discharge boundary conditions,and capacity-reduction transport modeling.For risk-reducing river management it has been shown how the development of the river bed can be addressed on a large scale and small scale.For instance,the use of sediment feeding and fixation of bed can be proposed for large-scale management,while monitoring and interventions at initiation of erosion can be proposed as response to small-scale developments that exceed predefined intervention levels.     

Source-specific variability in post-depositional DNA preservation with potential implications for DNA based paleoecological records

Recent studies have shown that genotyping preserved plankton DNA in marine and lacustrine sediment records using ancient DNA methods is a promising approach for refining paleoenvironmental information. However, the extent to which the preservation of fossil plankton DNA differs between species is poorly understood. Using a continuous 2700 year sediment record from Watts Basin in Ellis Fjord (Antarctica), we compared the level of preservation of fossil DNA derived from important plankton members with varying cellular architecture. The amount of preserved small subunit ribosomal DNA (SSU rDNA; ca. 500 base pair fragments) of dinoflagellates (as extracellular DNA rather than as preserved cysts) that could be amplified by way of PCR declined up to five orders of magnitude with increasing sediment depth and age. In contrast, the amount of similar-sized, PCR-amplifiable, diatom SSU rDNA (predominantly from a cyst-forming Chaetoceros sp.) declined only up to tenfold over 2700 years of deposition. No obvious decline in copy numbers with increasing sediment age was observed for similar-sized SSU rDNA of past chemocline-associated photosynthetic green sulfur bacteria (GSB), which do not have a protective resting stage. In good agreement with the quantitative data, the extent of post-depositional natural degradation to fragments too small to serve as a template for the quantitative PCR assays was greatest for dinoflagellates and lowest for GSB. An increase in the ratio between GSB-derived DNA and intact carotenoids with sediment depth implies that short GSB DNA fragments were better preserved than intact carotenoids and provide a more accurate view into paleoproductivity and the sediment flux of GSB in Watts Basin. We discuss the possible causes behind the variation in the level of DNA preservation among the plankton groups investigated, as well as consequences for the use of using fossil DNA records in paleoecology studies.     

Palaeoproterozoic (1.83 Ga) zircons in a Bajocian (169 Ma) granite within a Middle Jurassic ophiolite (Rubiku,central Albania): a challenge for geodynamic models

Two distinct zircon populations, 1,827 ± 17 and 169 ± 2 Ma in age, have been found in the Rubiku granite dyke in the Middle Jurassic Mirdita ophiolite in central Albania. The old inherited zircons represent a homogeneous population formed during a discrete Palaeoproterozoic, likely magmatic, zircon crystallization event. These older zircons were likely incorporated, in large part, into the granite magma that crystallized broadly at the time of the ophiolite emplacement (around 169 Ma). The limited data available do not allow for the construction of an unequivocal petrogenetic model, though several palaeotectonic scenarios are discussed as possible settings for the granite formation. The models refer to recent findings of old inherited zircons in rocks at recent mid-ocean ridge settings, but also consider likely contributions of crustal materials to primary basic ophiolitic magmas within supra-subduction settings and subsequent accretion/collision circumstances. The presence of old zircons in much younger rocks within ophiolite successions runs counter to geodynamic models of interaction between the oceanic lithosphere and continental crust, but constraining their genesis would require further systematic studies on these old inherited zircons, both in mafic (if present) and in felsic rocks of the ophiolites.     

Paleogeographic evolution of the Southern Pannonian Basin: 40Ar/39Ar age constraints on the Miocene continental series of Northern Croatia

The Pannonian Basin, originating during the Early Miocene, is a large extensional basin incorporated between Alpine, Carpathian and Dinaride fold-thrust belts. Back-arc extensional tectonics triggered deposition of up to 500-m-thick continental fluvio-lacustrine deposits distributed in numerous sub-basins of the Southern Pannonian Basin. Extensive andesitic and dacitic volcanism accompanied the syn-rift deposition and caused a number of pyroclastic intercalations. Here, we analyze two volcanic ash layers located at the base and top of the continental series. The lowermost ash from Mt. Kalnik yielded an ⁴⁰Ar/³⁹Ar age of 18.07?±?0.07?Ma. This indicates that the marine-continental transition in the Slovenia-Zagorje Basin, coinciding with the onset of rifting tectonics in the Southern Pannonian Basin, occurs roughly at the Eggenburgian/Ottnangian boundary of the regional Paratethys time scale. This age proves the synchronicity of initial rifting in the Southern Pannonian Basin with the beginning of sedimentation in the Dinaride Lake System. Beside geodynamic evolution, the two regions also share a biotic evolutionary history: both belong to the same ecoregion, which we designate here as the Illyrian Bioprovince. The youngest volcanic ash level is sampled at the Glina and Karlovac sub-depressions, and both sites yield the same ⁴⁰Ar/³⁹Ar age of 15.91?±?0.06 and 16.03?±?0.06?Ma, respectively. This indicates that lacustrine sedimentation in the Southern Pannonian Basin continued at least until the earliest Badenian. The present results provide not only important bench marks on duration of initial synrift in the Pannonian Basin System, but also deliver substantial backbone data for paleogeographic reconstructions in Central and Southeastern Europe around the Early–Middle Miocene transition.     

Architecture,structural and tectonic significance of the Seagap fault (offshore Tanzania) in the framework of the East African Rift

The Southeastern portion of the East African Rift System reactivates Mesozoic transform faults marking the separation of Madagascar from Africa in the Western Indian Ocean. Earlier studies noted the reactivation of the Davie Fracture Zone in oceanic lithosphere as a seismically active extensional fault, and new 3D seismic reflection data and exploration wells provide unprecedented detail on the kinematics of the sub-parallel Seagap fault zone in continental/transitional crust landward of the ocean-continent transition. We reconstruct the evolution of the seismically active Seagap fault zone, a 400-km-long crustal structure affecting the Tanzania margin, from the late Eocene to the present day. The Seagap fault zone is represented by large-scale localized structures affecting the seafloor and displaying growth geometries across most of the Miocene sediments. The continuous tectonic activity evident by our seismic mapping, as well as 2D deep seismic data from literature, suggests that from the Middle-Late Jurassic until 125 Ma, the Seagap fault acted as a regional structure parallel to, and coeval with, the dextral Davie Fracture Zone. The Seagap fault then remained active after the cessation of both seafloor spreading in the Somali basin and strike-slip activity on the Davie Fracture Zone, till nowaday. Its architecture is structurally expressed through the sequence of releasing and restraining bends dating back at least to the early Neogene. Seismic sections and horizon maps indicate that those restraining bends are generated by strike-slip reactivation of Cretaceous structures till the Miocene. Finally based on the interpretation of edge-enhanced reflection seismic surfaces and seafloor data, we shows that, by the late Neogene, the Seagap fault zone switched to normal fault behaviour. We discuss the Seagap fault's geological and kinematic significance through time and its current role within the microplate system in the framework of the East African rift, as well as implications for the evolution and re-activation of structures along sheared margins. The newly integrated datasets reveal the polyphase deformation of this margin, highlighting its complex evolution and the implications for depositional fairways and structural trap and seal changes through time, as well as potential hazards.     

Salt décollement and rift inheritance controls on crustal deformation in orogens

We investigate the factors that control the shortening distribution and its evolution through time in orogenic belts using numerical models. We present self‐consistent high‐resolution numerical models that simulate the inversion of a rift to generate an upper crustal antiformal stack, a wide outer pro‐wedge fold‐and‐thrust belt, characterised by a two‐phase evolution with early symmetric inversion followed by formation of an asymmetric doubly‐vergent orogen. We show that a weak viscous salt décollement promotes gravitational collapse of the cover. When combined with efficient erosion of the orogenic core and sedimentation in adjacent forelands, it ensures the thick‐skinned pro‐wedge taper remains subcritical, promoting formation of an upper crustal antiformal stack. Rift inheritance promotes a two‐phase shortening distribution evolution regardless of the shallow structure and other factors. Comparison to the Pyrenees strongly suggests that this combination of factors led to a very similar evolution and structural style.     

Timing of arrival of the Danube to the Black Sea: Provenance of sediments from DSDP site 380/380A

Estimates for the timing of the arrival of Danube sediment to the Black Sea range from Messinian to Pleistocene; the river is currently the largest sediment contributor, supplying 88 MT/yr. We identify two changes in siltstone provenance‐sensitive heavy mineral abundances at DSDP site 380/380A in the southwest Black Sea. Comparison with modern river sediment compositions indicates that siltstones above 571.5 mbsf (metres below sea floor) were supplied by the Danube, while sediments below 651.0 m were sourced by other supply systems. Palaeo‐magnetic, ⁴⁰Ar/³⁹Ar and biostratigraphic data reveal that the influx of Danube‐supplied sediment to the southwest Black Sea began between 4.36 ± 0.19 Ma and 1 Ma ago (Zanclean–Calabrian). Our results provide an independent time constraint on palaeogeographic reconstructions of the Pannonian and Dacian basins, which acted as upstream sediment sinks, and suggest that significant volumes of Danube‐supplied sediment only started to reach the Black Sea at least 1 Ma after the Messinian Salinity Crisis (5.971–5.33 Ma) had ended.     

Frame-based guide to situated decision-making on climate change

The present paper describes a frame-based approach to situated-decision-making on climate change. Building on the multidisciplinary literature on the relationship between frames and decision-making, it argues that decision-makers may gain from making frames more explicit and using them for generating different visions about the central issues. Frames act as organizing principles that shape in a “hidden” and taken-for-granted way how people conceptualize an issue. Science-related issues, such as climate change, are often linked to only a few frames, which consistently appear across different policy areas. Indeed, it appears that there are some very contrasting ways in which climate change may be framed. These frames can be characterized in terms of a simple framework that highlights specific interpretations of climate issues. A second framework clarifies the built-in frames of decision tools. Using Thompson's two basic dimensions of decision, it identifies the main uncertainties that should be considered in developing a decision strategy. The paper characterizes four types of decision strategy, focusing on (1) computation, (2) compromise, (3) judgment, or (4) inspiration, and links each strategy to the appropriate methods and tools, as well as the appropriate social structures. Our experiences show that the frame-based guide can work as an eye-opener for decision-makers, particularly where it demonstrates how to add more perspectives to the decision.     

Ethics and public perception of climate change: Exploring the Christian voices in the US public debate

Climate change raises many questions with strong moral and ethical dimensions that are important to address in climate-policy formation and international negotiations. Particularly in the United States, the public discussion of these dimensions is strongly influenced by religious groups and leaders. Over the past few years, many religious groups have taken positions on climate change, highlighting its ethical dimensions. This paper aims to explore these ethical dimensions in the US public debate in relation to public support for climate policies. It analyzes in particular the Christian voices in the US public debate on climate change by typifying the various discourses. Three narratives emerge from this analysis: ‘conservational stewardship’ (conserving the ‘garden of God’ as it was created), ‘developmental stewardship’ (turning the wilderness into a garden as it should become) and ‘developmental preservation’ (God's creation is good and changing; progress and preservation should be combined). The different narratives address fundamental ethical questions, dealing with stewardship and social justice, and they provide proxies for public perception of climate change in the US. Policy strategies that pay careful attention to the effects of climate change and climate policy on the poor – in developing nations and the US itself – may find support among the US population. Religious framings of climate change resonate with the electorates of both progressive and conservative politicians and could serve as bridging devices for bipartisan climate-policy initiatives.