Electrical analogy for modelling thermal regime and moisture distribution in sandy soils

The soil mass is subjected to temperature variation due to several human activities (viz. tanks storing heated fluids, buried cables and pipelines, air-conditioning ducts, disposal of nuclear and thermal power plant wastes etc.), which result in heat-induced migration of the moisture in it. Though several studies have been conducted in the past to investigate the mechanism of heat migration through the soil mass, a methodology for ‘real-time measurement of the variations in temperature, flux and moving moisture front, in tandem, with respect to space' has rarely been attempted. In this context, extensive laboratory investigations were conducted to measure real-time flux and temperature variations in the sandy soils, and the validation of results has been done by employing an equivalent electrical circuit programme, LTspice. Subsequently, a mathematical model PHITMDS (i.e. Prediction of Heat-Induced Temperature and Moisture Distribution in Soil) has been developed and its utility and efficacy, for predicting the depth-wise temperature and heat-induced moisture migration, due to evaporation, in terms of position of moving moisture front in the sandy soil has been critically discussed and demonstrated.     

The behaviour of dissolved arsenic in the estuary of the River Beaulieu

The chemical forms and distribution of dissolved arsenic species in the estuary of the River Beaulieu (Hampshire, U.K.) are reported. ‘Inorganic arsenic (V)’ in both the marine and riverine estuary inputs are in true solution, passing through ultrafiltration membranes having a nominal molecular weight cut-off of 500 daltons. Extensive removal of dissolved ‘inorganic arsenic (V)’ is apparent from the distribution of arsenic in the estuary, with laboratory mixing experiments indicating that removal is favoured in the low salinity region. ‘Inorganic arsenic (III)’ and methylated arsenic species account for up to 41% and 70% of the dissolved arsenic, respectively, but are only found during the warmer months when water temperatures exceed ca. 12°C.     

Seasonal variability of biological arsenic methylation in the estuary of the River Beaulieu

The observation of a strong seasonal variation of arsenic species found in the estuaries of the Rivers Beaulieu, Test and Itchen in central southern England is presented. The implications of such observations regarding the environmental biomethylation and fate of arsenic in natural waters are also discussed.     

Predicting New Hampshire indoor radon concentrations from geologic information and other covariates

 Generalized geologic province information and data on house construction were used to predict indoor radon concentrations in New Hampshire (NH). A mixed-effects regression model was used to predict the geometric mean (GM) short-term radon concentrations in 259 NH towns. Bayesian methods were used to avoid over-fitting and to minimize the effects of small sample variation within towns. Data from a random survey of short-term radon measurements, individual residence building characteristics, along with geologic unit information, and average surface radium concentration by town, were variables used in the model. Predicted town GM short-term indoor radon concentrations for detached houses with usable basements range from 34 Bq/m³ (1 pCi/l) to 558 Bq/m³ (15 pCi/l), with uncertainties of about 30%. A geologic province consisting of glacial deposits and marine sediments was associated with significantly elevated radon levels, after adjustment for radium concentration and building type. Validation and interpretation of results are discussed. Received: 20 October 1997 · Accepted: 18 May 1998     

High-Resolution Records of the Holocene Paleoenvironmental Variation Reflected by Carbonate and Its Isotopic Compositions in Bosten Lake and Response to Glacial Activities

Abstract: The Early Holocene paleoclimate in Bosten Lake on the northern margin of the Tarim Basin, southern Xinjiang, is reconstructed through an analysis of a 953 cm long core (BSTC2000) taken from Bosten Lake. Multiple proxies of this core, including the mineral components of carbonate, carbonate content, stable isotopic compositions of carbonate, Ca/Sr, TOC and C/N and C/S of organic matter, are used to reconstruct the climatic change since 8500 a B.P. The chronology model is made by nine AMS 14C ages of leaves, seeds and organic matter contained in two parallel cores. The climate was cold and wet during 8500 to 8100 a B.P. Temperature increased from 8100 to 6400 a B.P., the climate was warm and humid, and the lake expanded. The lake level was highest during this stage. Then from 6400 to 5100 a B.P., the climate became cold and the lake level decreased slightly. During the late mid-Holocene, the climate was hot and dry from 5100 to 3100 a B.P., but there was a short cold period during 4400 to 3800 a B.P. At this temporal interval, a mass of ice and snow melting water supplied the lake at the early time and made the lake level rise. The second highest lake level stage occurred during 5200 to 3800 a B.P. The climate was cool and wet during 3100 to 2200 a B.P., when the lake expanded with decreasing evaporation. The lake had the last short-term high level during 3100 to 2800 a B.P. After this short high lake level period, the lake shrank because of the long-term lower temperature and reduced water supply. From 2200 to 1200 a B.P., the climate was hot and dry, and the lake shrank greatly. Although the temperature decreased somewhat from 1200 a B.P. to the present, the climate was warm and dry. The lake level began to rise a little again, but it did not reach the river bed altitude of the Konqi River, an outflow river of the Bosten Lake.     

Dissolved trace metal distributions in Port Jackson estuary (Sydney Harbour), Australia

Concentrations of dissolved metals (Cd, Cu, Ni, Mn and Zn) were determined for summer and winter, under low-flow conditions in Port Jackson, a microtidal, well-mixed estuary in south-east Australia. Mean concentrations of Cd (0.04+/-0.02 microg/l), Ni (0.86+/-0.40 microg/l), Mn (20.0+/-25 microg/l) and Zn (6.47+/-2.0 microg/l) were below water quality guidelines. Concentrations of Cu (1.68+/-0.37 microg/l), however, slightly exceeded recommended values. Dissolved Ni and Mn behaved mostly conservatively, whereas Cd, Cu and Zn showed mid-estuarine maxima. Peaks in Cd, Cu and Zn concentrations were located in the upper estuary, independent of the salinity and suspended particulate matter loading, and were consistent with anthropogenic inputs of metals in the estuary. Concentrations of dissolved Cu were highest in summer, whereas concentrations of Cd, Ni and Mn were significantly lower in summer than winter (P< or =0.05). The increase in temperature and biological activity during summer explained the seasonal variation. The sequence of log K(d) values (20-30 salinity) was Mn>Zn>Cu>Ni. These results give unique information concerning the contemporaneous distribution of dissolved trace metals in the Port Jackson estuary and they provide a data set against which the long-term contamination may be assessed.     

An evaluation of copper remobilization from mine tailings in sulfidic environments

A laboratory-based assessment of copper remobilization from Cu-rich mine tailings exposed to anoxic, sulfide rich waters was performed. The results from incubation experiments, conducted over a 20 day period, were compared to thermodynamic modelling calculations of copper speciation in sulfidic waters. The tailings materials were observed to react rapidly with added sulfide, consuming 159 μmol HS⁻ g⁻¹ (dry wt) within a 24 h period. The consumption of sulfide was attributed to a two stage process involving the reduction of Fe-hydroxy phases by sulfide followed by reaction with available Fe²⁺ and Cu²⁺ resulting in the formation Fe- and Cu-sulfide phases. During incubation experiments, the dissolved copper concentrations in the absence of sulfide were approximately 0.31 μmol l⁻¹, whereas in the presence of sulfide (0.5–5 mM) concentrations were typically 0.24 μmol l⁻¹. The experiments did not indicate enhanced solubility owing to the formation of soluble copper sulfide species. The predictions (based on the most recent thermodynamic data for aqueous Cu-sulfide and Cu-polysulfide species) did not accurately explain the laboratory observations. Model predictions were greatly influenced by the assumptions made about the oxidation state of copper under anoxic conditions and the solid sulfide phase controlling copper solubility. The study emphasizes the limitations of modelling copper speciation in sulfidic waters and the need for laboratory or field verification of predictions.     

An Analysis of Spatial and Temporal Dimension of Drought Vulnerability in Turkey Using the Standardized Precipitation Index

Drought has become a recurrent phenomenon in Turkey in the last few decades. Significant drought conditions were observed during years of late 1980s and the trend continued in the late 1990s. The countrys agricultural sector and water resources have been under severe constraints from the recurrent droughts. In this study, spatial and temporal dimensions of meteorological droughts in Turkey have been investigated from vulnerability concept. The Standardized Precipitation Index (SPI) method was used to detail geographical variations in the drought vulnerability based on frequency and severity of drought events at multiple time steps. Critical (threshold) rainfall values were derived for each station at multiple-time steps in varying drought categories to determine least amount of rainfall required to avoid from drought initiation. The study found that drought vulnerability portrays a very diverse but consistent picture with varying time steps. At regional scale, south-eastern and eastern Anatolia are characterized with moderate droughts at shorter time steps, while the occurrence of severe droughts at shorter time steps is observed at non-coastal parts of the country. A similar picture was observed with very severe droughts. The critical (threshold) values exhibited rising numbers during the growing season at 3-month step in the South-eastern Anatolia, which might have significant consequences considering presence of large irrigation projects under-development in the region. In general, rainfall amounts required for non-drought conditions decrease from the coastal parts toward the interiors with increasing time steps.     

Quartz latite rheoignimbrite flows of the Etendeka Formation,north-western Namibia

The Etendeka Formation of north-western Namibia consists of a sequence of interbedded quartz latites and tholeiitic basalts and forms part of the Karoo Igneous Province in southern Africa. The age of the Etendeka Formation is approximately 130–135 Ma. The quartz latites make up a significant proportion of the stratigraphic succession (<25% of the total stratigraphic thickness) and form as much as 60% of the outcrop area in the southern Etendeka. Apart from some systematic differences between pitchstones and devitrified quartz latite, largely explained by alteration processes, individual quartz latite units exhibit remarkably uniform compositions with no significant vertical or lateral variation. Geochemistry can be used as a primary criterion for the correlation of major quartz latite units over much of the southern Etendeka area enabling the reconstruction of the Etendeka Formation stratigraphy in this region. Individual quartz latite units occur as voluminous (400–2600 km³), widespread (up to 8800 km²), sheet-like deposits typically between 40 and 300 m thick. Each unit consists of basal, main and upper zones. The main zone generally constitutes over 70% of the thickness of the unit and typically consists of texturally featureless devitrified quartz latite. In contrast the basal and upper zones of the flow are characterised by flow banding, pitchstone lenses and breccia, with rare occurrences of pyroclastic textures. The quartz latites are sparsely porphyritic (<10% phenocrysts) with glassy or devitrified groundmass textures. The phenocrysts consist of plagioclase, pyroxene, titanomagnetite and rare ilmenite. Pyroxene geothermometry indicates high (1000–1100°C) temperatures of crystallisation which, coupled with the absence or primary hydrous phases, indicates that the quartz latites were relatively hot, H₂O-undersaturated magmas. The quartz latites display features common to both rhyolite lavas and ignimbrites and are clearly the products of an unusual eruption style. The local preservation of pyroclastic textures and the broad areal extent of these units lead to the conclusion that the quartz latites are high-temperature rheomorphic ignimbrites (i.e. rheoignimbrites). A combination of high eruption temperature and relatively low viscosity helps to explain the often completely welded and homogeneous textures observed in most quartz latite outcrops in the Etendeka area.