Stochastic modelling of groundwater flow and solute transport in aquifers

This paper presents an introductory overview of recently developed stochastic theories for tackling spatial variability problems in predicting groundwater flow and solute transport. Advantages and limitations of the theories are discussed. Lastly, strategies based on the stochastic approaches to predict solute transport in aquifers are recommended.     

Effect of spatial variation characteristics on contouring of design storm depth

The ordinary kriging method, a geostatistical interpolation technique, was applied for developing contour maps of design storm depth in northern Taiwan using intensity–duration–frequency (IDF) data. Results of variogram modelling on design storm depths indicate that the design storms can be categorized into two distinct storm types: (i) storms of short duration and high spatial variation and (ii) storms of long duration and less spatial variation. For storms of the first category, the influence range of rainfall depth decreases when the recurrence interval increases, owing to the increasing degree of their spatial independence. However, for storms of the second category, the influence range of rainfall depth does not change significantly and has an average of approximately 72 km. For very extreme events, such as events of short duration and long recurrence interval, we do not recommend usage of the established design storm contours, because most of the interstation distances exceed the influence ranges. Our study concludes that the influence range of the design storm depth is dependent on the design duration and recurrence interval and is a key factor in developing design storm contours. Copyright © 2003 John Wiley & Sons, Ltd.     

Low‐energy helium ion irradiation‐induced amorphization and chemical changes in olivine: Insights for silicate dust evolution in the interstellar medium

Abstract— We present the results of irradiation experiments aimed at understanding the structural and chemical evolution of silicate grains in the interstellar medium. A series of He+ irradiation experiments have been performed on ultra‐thin olivine, (Mg,Fe)₂SiO₄, samples having a high surface/volume (S/V) ratio, comparable to the expected S/V ratio of interstellar dust. The energies and fluences of the helium ions used in this study have been chosen to simulate the irradiation of interstellar dust grains in supernovae shock waves. The samples were mainly studied using analytical transmission electron microscopy. Our results show that olivine is amorphized by low‐energy ion irradiation. Changes in composition are also observed. In particular, irradiation leads to a decrease of the atomic ratios O/Si and Mg/Si as determined by x‐ray photoelectron spectroscopy and by x‐ray energy dispersive spectroscopy. This chemical evolution is due to the differential sputtering of atoms near the surfaces. We also observe a reduction process resulting in the formation of metallic iron. The use of very thin samples emphasizes the role of surface/volume ratio and thus the importance of the particle size in the irradiation‐induced effects. These results allow us to account qualitatively for the observed properties of interstellar grains in different environments, that is, at different stages of their evolution: chemical and structural evolution in the interstellar medium, from olivine to pyroxene‐type and from crystalline to amorphous silicates, porosity of cometary grains as well as the formation of metallic inclusions in silicates.     

Isotopic studies of leaf water. Part 1: A physically based two-dimensional model for pine needles

Understanding of isotopic variations in leaf water is important for reconstruction of paleoclimate and assessment of global biochemical processes. We report here a study of isotopic distributions within a single needle of two pine species, Pinus resinosa Ait and Pinus strobes L., with the objective of understanding how isotopic compositions of leaf water are controlled by environmental and physiological variables. A 2D model was developed to simulate along-leaf isotopic variations and bulk leaf water isotopic compositions. In addition to variables common to all leaf water isotopic models, this 2D model also takes into account the specific geometry and dimensions of pine needles and the isotopic transport in xylem and mesophyll. The model can successfully simulate oxygen isotopic variations along a single needle and averaged over a leaf (bulk leaf water). The simulations suggest that isotopic composition of the bulk leaf water does not always depend only upon the average transpiration rate, which in turn raises questions about using leaf water isotopic values to estimate transpiration rates. An unsuccessful attempt to simulate along-needle hydrogen isotopic variations suggests that certain unknown biological process(es) may not have been incorporated into our 2D model, and if so, it calls for a reevaluation of all other models for hydrogen isotopic simulations of leaf water since they too lack these processes.Existing leaf water isotopic models are reviewed in this work. In particular, we evaluate the most frequently used model, the stomatal boundary layer model (also referred to as the Craig-Gordon model). We point out that discrepancy between the boundary layer model and the measured bulk leaf water seems to depend upon relative humidity. Using our 2D model, we show that this humidity dependency is a result of an interplay between environmental and physiological conditions: if the transpiration rate of plant leaves decreases with increasing relative humidity, our 2D model can reproduce the pattern of isotopic discrepancy between boundary layer model predictions and observations, enabling us to understand better the reason behind this discrepancy.     

The presence of anomalous trace element levels in present day Jamaican soils and the geochemistry of Late-Miocene or Pliocene phosphorites

High levels of Cd and Zn in Jamaican soils observed in geochemical surveys are related to the presence of phosphorites of possible Late-Miocene or Pliocene age. The trace element and REE geochemistry of the phosphorites, together with SEM studies, indicate a guano origin for the phosphorites. No specific host minerals for Cd could be identified in the fossiliferous phosphorite which is characterized by uniquely high levels of Cd, Zn, Ag, Be, U and Y. However, in the soil Cd is present in lithiophorite and a complex history of pedological development is preserved in the aluminous–goethite present in the soil. The unique guano signature is preserved in the soil despite the fact that guanos themselves have either not been observed or have been destroyed by continuing karst and soil development. The phosphorite geochemical signature can be traced in the data of a 1988 island-wide soil geochemical survey, identifying areas where the Palaeo-environment that supported bird ‘rookeries’ existed in the Late-Miocene or Pliocene.     

Crustal Structures of the Northernmost South China Sea: Seismic Reflection and Gravity Modeling

The South China Sea (SCS) is a marginal sea off shore Southeast Asia. Based on magnetic study, oceanic crust has been suggested in the northernmost SCS. However, the crustal structure of the northernmost SCS was poorly known. To elaborate the crustal structures in the northernmost SCS and off southwest Taiwan, we have analyzed 20 multi-channel seismic profiles of the region. We have also performed gravity modeling to understand the Moho depth variation. The volcanic basement deepens southeastwards while the Moho depth shoals southeastwards. Except for the continental margin, the northernmost SCS can be divided into three tectonic regions: the disturbed and undisturbed oceanic crust (8–12 km thick) in the southwest, a trapped oceanic crust (8 km thick) between the Luzon-Ryukyu Transform Plate Boundary (LRTPB) and Formosa Canyon, and the area to the north of the Formosa Canyon which has the thickest sediments. Instead of faulting, the sediments across the LRTPB have only displayed differential subsidence offset of about 0.5–1 s in the northeast side, indicating that the LRTPB is no longer active. The gravity modeling has shown a relatively thin crust beneath the LRTPB, demonstrating the sheared zone character along the LRTPB. However, probably because of post-spreading volcanism, only the transtension-shearing phenomenon of volcanic basement in the northwest and southeast ends of the LRTPB can be observed. These two basement-fractured sites coincide with low gravity anomalies. Intensive erosion has prevailed over the whole channel of the Formosa Canyon.     

Code of Practice For Ocean Mining: An International Effort to Develop a Code For Environmental Management of Marine Mining

A code of practice for ocean mining has been developed by the International Marine Minerals Society. The code provides general guiding Principles for development of marine mineral resources and delineates Operating Guidelines for application, as appropriate, at specific mining sites. In total 11 operating guidelines are provided to serve as benchmarks for industry and targets for regulatory agencies and other stakeholders. They include the following commitments: •To sustainable development, •To environmentally responsible corporate ethics, •To the development of effective community partnership, •To implementation of environmental risk management, •To the integration of environmental management into all phases of development, •To the establishment of corporate environmental performance targets, •To timely environmental improvements and upgrading, •To responsible rehabilitation of operations sites and decommissioning of facilities, and •To accurate and timely, reporting and documentation, archiving, and performance review.     

Eastern and Western Poor Cod (Trisopterus minutus capelanus) Populations in the Mediterranean Sea: Evidence from Allozyme and Minisatellite Loci

Abstract. Nine allozyme and two minisatellite loci were used to investigate potential genetic differentiation among three samples of Mediterranean poor cod, Trisopterus minutus capelanus, from the Gulf of Lion, the Tuscan Archipelago and the Aegean Sea. Both types of markers showed consistent results, with F_ST values of 0.0262 and 0.0296 (P < 0.0015, after Bonferroni correction for multiple tests) for allozymes and minisatellites, respectively. Allele frequency heterogeneity tests between pairs of samples showed a clear separation between the two western Mediterranean samples (Gulf of Lion, Tuscan Archipelago) and the eastern one (Aegean Sea). The results indicate that at least two reproductively isolated populations of poor cod occur in the Mediterranean.     

Petroleum hydrocarbons in sediments of Southampton water estuary

The sediments of Southampton Water were analysed for petroleum hydrocarbons to determine the fate of petrochemical refinery waste in the estuary. Much of the petroleum hydrocarbons appears to be removed by adsorption onto estuarine sediments close to source. Surface sediment concentrations range from 3·1mg/g dry weight near a refinery to 0·5 mg/g dry weight at locations distant from the refinery.The absence of any change with depth in total hydrocarbon concentrations from some sediment cores and the presence of distinct ‘oil’ horizons in others suggests that mixing of sediments in the area is very random. Sedimentation rates in areas where a distinct oil horizon was observed ranged from 1 to 3cm a year.